TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine
- Autores
- Levy, Ivana Karina; Mizrahi, Martin Daniel; Ruano, Gustavo; Zampieri, Guillermo Enrique; Requejo, Felix Gregorio; Litter, Marta Irene
- Año de publicación
- 2012
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Heterogeneous photocatalytic reduction of As(V) and As(III) at different concentrations over TiO2 under UV light in deoxygenated aqueous suspensions is described. For the first time, As(0) was unambiguously identified together with arsine(AsH3) as reaction products. As(V) reduction requires the presence of an electron donor(methanol in the present case) and takes place through the hydroxymethyl radical formed from methanol oxidation by holes or hydroxyl radicals. On the contrary, As(III)reduction takes place through direct reduction by the TiO2-conduction band electrons. Detailed mechanisms for the photocatalytic processes are proposed. Although reduction to solid As(0) is convenient for purposes of As removal from water as a deposit on TiO2, attention must be paid to formation of AsH3, one of the most toxic forms of As, and strategies for AsH3 treatment should be considered.
Fil: Levy, Ivana Karina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Fil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Ruano, Gustavo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Zampieri, Guillermo Enrique. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina
Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina
Fil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina - Materia
-
photocatalytic
TiO2
arsenic - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/236777
Ver los metadatos del registro completo
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CONICET Digital (CONICET) |
spelling |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsineLevy, Ivana KarinaMizrahi, Martin DanielRuano, GustavoZampieri, Guillermo EnriqueRequejo, Felix GregorioLitter, Marta IrenephotocatalyticTiO2arsenichttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1Heterogeneous photocatalytic reduction of As(V) and As(III) at different concentrations over TiO2 under UV light in deoxygenated aqueous suspensions is described. For the first time, As(0) was unambiguously identified together with arsine(AsH3) as reaction products. As(V) reduction requires the presence of an electron donor(methanol in the present case) and takes place through the hydroxymethyl radical formed from methanol oxidation by holes or hydroxyl radicals. On the contrary, As(III)reduction takes place through direct reduction by the TiO2-conduction band electrons. Detailed mechanisms for the photocatalytic processes are proposed. Although reduction to solid As(0) is convenient for purposes of As removal from water as a deposit on TiO2, attention must be paid to formation of AsH3, one of the most toxic forms of As, and strategies for AsH3 treatment should be considered.Fil: Levy, Ivana Karina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Ruano, Gustavo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Zampieri, Guillermo Enrique. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; ArgentinaFil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaAmerican Chemical Society2012-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/236777Levy, Ivana Karina; Mizrahi, Martin Daniel; Ruano, Gustavo; Zampieri, Guillermo Enrique; Requejo, Felix Gregorio; et al.; TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine; American Chemical Society; Environmental Science & Technology; 46; 4; 1-2012; 2299-23080013-936XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/es202638cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:08:25Zoai:ri.conicet.gov.ar:11336/236777instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:08:25.317CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
title |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
spellingShingle |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine Levy, Ivana Karina photocatalytic TiO2 arsenic |
title_short |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
title_full |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
title_fullStr |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
title_full_unstemmed |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
title_sort |
TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine |
dc.creator.none.fl_str_mv |
Levy, Ivana Karina Mizrahi, Martin Daniel Ruano, Gustavo Zampieri, Guillermo Enrique Requejo, Felix Gregorio Litter, Marta Irene |
author |
Levy, Ivana Karina |
author_facet |
Levy, Ivana Karina Mizrahi, Martin Daniel Ruano, Gustavo Zampieri, Guillermo Enrique Requejo, Felix Gregorio Litter, Marta Irene |
author_role |
author |
author2 |
Mizrahi, Martin Daniel Ruano, Gustavo Zampieri, Guillermo Enrique Requejo, Felix Gregorio Litter, Marta Irene |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
photocatalytic TiO2 arsenic |
topic |
photocatalytic TiO2 arsenic |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Heterogeneous photocatalytic reduction of As(V) and As(III) at different concentrations over TiO2 under UV light in deoxygenated aqueous suspensions is described. For the first time, As(0) was unambiguously identified together with arsine(AsH3) as reaction products. As(V) reduction requires the presence of an electron donor(methanol in the present case) and takes place through the hydroxymethyl radical formed from methanol oxidation by holes or hydroxyl radicals. On the contrary, As(III)reduction takes place through direct reduction by the TiO2-conduction band electrons. Detailed mechanisms for the photocatalytic processes are proposed. Although reduction to solid As(0) is convenient for purposes of As removal from water as a deposit on TiO2, attention must be paid to formation of AsH3, one of the most toxic forms of As, and strategies for AsH3 treatment should be considered. Fil: Levy, Ivana Karina. Comisión Nacional de Energía Atómica; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina Fil: Mizrahi, Martin Daniel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Ruano, Gustavo. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina Fil: Zampieri, Guillermo Enrique. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Energía Nuclear. Instituto Balseiro; Argentina Fil: Requejo, Felix Gregorio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; Argentina Fil: Litter, Marta Irene. Comisión Nacional de Energía Atómica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina |
description |
Heterogeneous photocatalytic reduction of As(V) and As(III) at different concentrations over TiO2 under UV light in deoxygenated aqueous suspensions is described. For the first time, As(0) was unambiguously identified together with arsine(AsH3) as reaction products. As(V) reduction requires the presence of an electron donor(methanol in the present case) and takes place through the hydroxymethyl radical formed from methanol oxidation by holes or hydroxyl radicals. On the contrary, As(III)reduction takes place through direct reduction by the TiO2-conduction band electrons. Detailed mechanisms for the photocatalytic processes are proposed. Although reduction to solid As(0) is convenient for purposes of As removal from water as a deposit on TiO2, attention must be paid to formation of AsH3, one of the most toxic forms of As, and strategies for AsH3 treatment should be considered. |
publishDate |
2012 |
dc.date.none.fl_str_mv |
2012-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/236777 Levy, Ivana Karina; Mizrahi, Martin Daniel; Ruano, Gustavo; Zampieri, Guillermo Enrique; Requejo, Felix Gregorio; et al.; TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine; American Chemical Society; Environmental Science & Technology; 46; 4; 1-2012; 2299-2308 0013-936X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/236777 |
identifier_str_mv |
Levy, Ivana Karina; Mizrahi, Martin Daniel; Ruano, Gustavo; Zampieri, Guillermo Enrique; Requejo, Felix Gregorio; et al.; TiO 2-photocatalytic reduction of pentavalent and trivalent arsenic: Production of elemental arsenic and arsine; American Chemical Society; Environmental Science & Technology; 46; 4; 1-2012; 2299-2308 0013-936X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/es202638c |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842270043742666752 |
score |
13.13397 |