Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs

Autores
Fortunatti, Cecilia; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The polymerization that IUPAC terms reversible-deactivation radical polymerization is a controlled radical polymerization technique (CRP) that allows producing polymers with tailored properties without the stringent conditions typical in ionic polymerization. A theoretical analysis is presented of the influence of operating and design conditions on the product properties for the nitroxide-mediated copolymerization (NMP) of styrene and α-methyl styrene. Several reactor configurations are analyzed, with different feeding policies and temperature profiles. To this end a mathematical model is developed to predict copolymer average properties and the complete bivariate MWD. The results help establishing design parameters and optimal operating policies to obtain desired copolymer microstructures.
Fil: Fortunatti, Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Materia
Copolymerization
Modeling
Molecular Weight Distribution
Nitroxide Mediated Polymerization
Pgf
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/25965
Acceder
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spelling Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designsFortunatti, CeciliaSarmoria, ClaudiaBrandolin, AdrianaAsteasuain, MarianoCopolymerizationModelingMolecular Weight DistributionNitroxide Mediated PolymerizationPgfhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The polymerization that IUPAC terms reversible-deactivation radical polymerization is a controlled radical polymerization technique (CRP) that allows producing polymers with tailored properties without the stringent conditions typical in ionic polymerization. A theoretical analysis is presented of the influence of operating and design conditions on the product properties for the nitroxide-mediated copolymerization (NMP) of styrene and α-methyl styrene. Several reactor configurations are analyzed, with different feeding policies and temperature profiles. To this end a mathematical model is developed to predict copolymer average properties and the complete bivariate MWD. The results help establishing design parameters and optimal operating policies to obtain desired copolymer microstructures.Fil: Fortunatti, Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaFil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; ArgentinaWiley VCH Verlag2013-05-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/25965Fortunatti, Cecilia; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs; Wiley VCH Verlag; Macromolecular Reaction Engineering; 8; 4; 27-5-2013; 260-2811862-832X1862-8338CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mren.201200084/abstractinfo:eu-repo/semantics/altIdentifier/doi/10.1002/mren.201200084info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T09:51:21Zoai:ri.conicet.gov.ar:11336/25965instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 09:51:21.347CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
title Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
spellingShingle Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
Fortunatti, Cecilia
Copolymerization
Modeling
Molecular Weight Distribution
Nitroxide Mediated Polymerization
Pgf
title_short Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
title_full Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
title_fullStr Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
title_full_unstemmed Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
title_sort Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs
dc.creator.none.fl_str_mv Fortunatti, Cecilia
Sarmoria, Claudia
Brandolin, Adriana
Asteasuain, Mariano
author Fortunatti, Cecilia
author_facet Fortunatti, Cecilia
Sarmoria, Claudia
Brandolin, Adriana
Asteasuain, Mariano
author_role author
author2 Sarmoria, Claudia
Brandolin, Adriana
Asteasuain, Mariano
author2_role author
author
author
dc.subject.none.fl_str_mv Copolymerization
Modeling
Molecular Weight Distribution
Nitroxide Mediated Polymerization
Pgf
topic Copolymerization
Modeling
Molecular Weight Distribution
Nitroxide Mediated Polymerization
Pgf
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The polymerization that IUPAC terms reversible-deactivation radical polymerization is a controlled radical polymerization technique (CRP) that allows producing polymers with tailored properties without the stringent conditions typical in ionic polymerization. A theoretical analysis is presented of the influence of operating and design conditions on the product properties for the nitroxide-mediated copolymerization (NMP) of styrene and α-methyl styrene. Several reactor configurations are analyzed, with different feeding policies and temperature profiles. To this end a mathematical model is developed to predict copolymer average properties and the complete bivariate MWD. The results help establishing design parameters and optimal operating policies to obtain desired copolymer microstructures.
Fil: Fortunatti, Cecilia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Sarmoria, Claudia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Brandolin, Adriana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
Fil: Asteasuain, Mariano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina
description The polymerization that IUPAC terms reversible-deactivation radical polymerization is a controlled radical polymerization technique (CRP) that allows producing polymers with tailored properties without the stringent conditions typical in ionic polymerization. A theoretical analysis is presented of the influence of operating and design conditions on the product properties for the nitroxide-mediated copolymerization (NMP) of styrene and α-methyl styrene. Several reactor configurations are analyzed, with different feeding policies and temperature profiles. To this end a mathematical model is developed to predict copolymer average properties and the complete bivariate MWD. The results help establishing design parameters and optimal operating policies to obtain desired copolymer microstructures.
publishDate 2013
dc.date.none.fl_str_mv 2013-05-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/25965
Fortunatti, Cecilia; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs; Wiley VCH Verlag; Macromolecular Reaction Engineering; 8; 4; 27-5-2013; 260-281
1862-832X
1862-8338
CONICET Digital
CONICET
url http://hdl.handle.net/11336/25965
identifier_str_mv Fortunatti, Cecilia; Sarmoria, Claudia; Brandolin, Adriana; Asteasuain, Mariano; Theoretical analysis of nitroxide-mediated copolymerization of styrene and a-methyl-styrene under different operating policies and reactor designs; Wiley VCH Verlag; Macromolecular Reaction Engineering; 8; 4; 27-5-2013; 260-281
1862-832X
1862-8338
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/mren.201200084/abstract
info:eu-repo/semantics/altIdentifier/doi/10.1002/mren.201200084
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.084122

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