Green synthesis of dimethyl isosorbide
- Autores
- Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; Bevinakatti, Hanamanthsa S.; Sievert, Robert L.; Newman, Christoper P.
- Año de publicación
- 2010
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.
Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia
Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido
Fil: Sievert, Robert L.. Uniqema; Reino Unido
Fil: Newman, Christoper P.. Quest International; Reino Unido - Materia
-
Carbohydrates
Carbonates
Green Chemistry
Methylation
Renewable Resources - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/70344
Ver los metadatos del registro completo
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Green synthesis of dimethyl isosorbideTundo, PietroAricò, FabioGauthier, GuillaumeRossi, Laura IsabelRosamilia, Anthony E.Bevinakatti, Hanamanthsa S.Sievert, Robert L.Newman, Christoper P.CarbohydratesCarbonatesGreen ChemistryMethylationRenewable Resourceshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; ItaliaFil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; ItaliaFil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; ArgentinaFil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; ItaliaFil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino UnidoFil: Sievert, Robert L.. Uniqema; Reino UnidoFil: Newman, Christoper P.. Quest International; Reino UnidoWiley VCH Verlag2010-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70344Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-5701864-56311864-564XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/20401898info:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201000011info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:33:21Zoai:ri.conicet.gov.ar:11336/70344instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:33:21.899CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Green synthesis of dimethyl isosorbide |
title |
Green synthesis of dimethyl isosorbide |
spellingShingle |
Green synthesis of dimethyl isosorbide Tundo, Pietro Carbohydrates Carbonates Green Chemistry Methylation Renewable Resources |
title_short |
Green synthesis of dimethyl isosorbide |
title_full |
Green synthesis of dimethyl isosorbide |
title_fullStr |
Green synthesis of dimethyl isosorbide |
title_full_unstemmed |
Green synthesis of dimethyl isosorbide |
title_sort |
Green synthesis of dimethyl isosorbide |
dc.creator.none.fl_str_mv |
Tundo, Pietro Aricò, Fabio Gauthier, Guillaume Rossi, Laura Isabel Rosamilia, Anthony E. Bevinakatti, Hanamanthsa S. Sievert, Robert L. Newman, Christoper P. |
author |
Tundo, Pietro |
author_facet |
Tundo, Pietro Aricò, Fabio Gauthier, Guillaume Rossi, Laura Isabel Rosamilia, Anthony E. Bevinakatti, Hanamanthsa S. Sievert, Robert L. Newman, Christoper P. |
author_role |
author |
author2 |
Aricò, Fabio Gauthier, Guillaume Rossi, Laura Isabel Rosamilia, Anthony E. Bevinakatti, Hanamanthsa S. Sievert, Robert L. Newman, Christoper P. |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Carbohydrates Carbonates Green Chemistry Methylation Renewable Resources |
topic |
Carbohydrates Carbonates Green Chemistry Methylation Renewable Resources |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC. Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido Fil: Sievert, Robert L.. Uniqema; Reino Unido Fil: Newman, Christoper P.. Quest International; Reino Unido |
description |
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC. |
publishDate |
2010 |
dc.date.none.fl_str_mv |
2010-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/70344 Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-570 1864-5631 1864-564X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/70344 |
identifier_str_mv |
Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-570 1864-5631 1864-564X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/20401898 info:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201000011 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |