Green synthesis of dimethyl isosorbide

Autores
Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; Bevinakatti, Hanamanthsa S.; Sievert, Robert L.; Newman, Christoper P.
Año de publicación
2010
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.
Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia
Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido
Fil: Sievert, Robert L.. Uniqema; Reino Unido
Fil: Newman, Christoper P.. Quest International; Reino Unido
Materia
Carbohydrates
Carbonates
Green Chemistry
Methylation
Renewable Resources
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/70344
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Green synthesis of dimethyl isosorbideTundo, PietroAricò, FabioGauthier, GuillaumeRossi, Laura IsabelRosamilia, Anthony E.Bevinakatti, Hanamanthsa S.Sievert, Robert L.Newman, Christoper P.CarbohydratesCarbonatesGreen ChemistryMethylationRenewable Resourceshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; ItaliaFil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; ItaliaFil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; ArgentinaFil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; ItaliaFil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino UnidoFil: Sievert, Robert L.. Uniqema; Reino UnidoFil: Newman, Christoper P.. Quest International; Reino UnidoWiley VCH Verlag2010-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/70344Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-5701864-56311864-564XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/20401898info:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201000011info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:30:46Zoai:ri.conicet.gov.ar:11336/70344instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:30:46.397CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Green synthesis of dimethyl isosorbide
title Green synthesis of dimethyl isosorbide
spellingShingle Green synthesis of dimethyl isosorbide
Tundo, Pietro
Carbohydrates
Carbonates
Green Chemistry
Methylation
Renewable Resources
title_short Green synthesis of dimethyl isosorbide
title_full Green synthesis of dimethyl isosorbide
title_fullStr Green synthesis of dimethyl isosorbide
title_full_unstemmed Green synthesis of dimethyl isosorbide
title_sort Green synthesis of dimethyl isosorbide
dc.creator.none.fl_str_mv Tundo, Pietro
Aricò, Fabio
Gauthier, Guillaume
Rossi, Laura Isabel
Rosamilia, Anthony E.
Bevinakatti, Hanamanthsa S.
Sievert, Robert L.
Newman, Christoper P.
author Tundo, Pietro
author_facet Tundo, Pietro
Aricò, Fabio
Gauthier, Guillaume
Rossi, Laura Isabel
Rosamilia, Anthony E.
Bevinakatti, Hanamanthsa S.
Sievert, Robert L.
Newman, Christoper P.
author_role author
author2 Aricò, Fabio
Gauthier, Guillaume
Rossi, Laura Isabel
Rosamilia, Anthony E.
Bevinakatti, Hanamanthsa S.
Sievert, Robert L.
Newman, Christoper P.
author2_role author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Carbohydrates
Carbonates
Green Chemistry
Methylation
Renewable Resources
topic Carbohydrates
Carbonates
Green Chemistry
Methylation
Renewable Resources
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.
Fil: Tundo, Pietro. Universita' Ca' Foscari Di Venezia; Italia. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Aricò, Fabio. Interuniversity Consortium Chemistry for the Environment; Italia. Universita' Ca' Foscari Di Venezia; Italia
Fil: Gauthier, Guillaume. École Nationale Supérieure de Chimie de Paris; Argentina
Fil: Rossi, Laura Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Rosamilia, Anthony E.. Interuniversity Consortium Chemistry for the Environment; Italia
Fil: Bevinakatti, Hanamanthsa S.. Uniqema; Reino Unido
Fil: Sievert, Robert L.. Uniqema; Reino Unido
Fil: Newman, Christoper P.. Quest International; Reino Unido
description A green synthetic approach for dimethyl isosorbide (DMI) with dimethylcarbonate (DMC) in the presence of a base is reported. The easy methylation of isosorbide may be due to its unique structure (which enhances the nucleophilicity of the hydroxyl groups), and to the effect of the hydrogen bonding which increases the reactivity of the molecule towards DMC.
publishDate 2010
dc.date.none.fl_str_mv 2010-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/70344
Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-570
1864-5631
1864-564X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/70344
identifier_str_mv Tundo, Pietro; Aricò, Fabio; Gauthier, Guillaume; Rossi, Laura Isabel; Rosamilia, Anthony E.; et al.; Green synthesis of dimethyl isosorbide; Wiley VCH Verlag; Chemsuschem; 3; 5; 4-2010; 566-570
1864-5631
1864-564X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.ncbi.nlm.nih.gov/pubmed/20401898
info:eu-repo/semantics/altIdentifier/doi/10.1002/cssc.201000011
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846083445240889344
score 13.22299

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