Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina

Autores
Ramos, Laura Mabel; Berenstein, Giselle Anahí; Hughes, Enrique Alejandro; Zalts, Anita; Montserrat, Javier Marcelo
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Horticulture makes intensive use of soil and extensive use of polyethylene (PE) sheeting and pesticides, producing an environment where the dynamics between soil and plastics can affect pesticide fate. We have determined that the presence of plastic residues in the horticultural soil of small production units equals 10% of the soil area, being meso and macro-sections the predominant fragment sizes. All soil samples were taken from different plots located in Cuartel V, Moreno district, in the suburbs of Buenos Aires city, Argentina. Laboratory experiments were conducted to see the relations among pesticide, soil and PE film. Endosulfan recovery from LDPE films (25 μm and 100 μm) was studied, observing evidence that indicated migration to the inside of the plastic matrix. To further analyze the dynamics of pesticide migration to soil and atmosphere, experiments using chlorpyrifos, procymidone and trifluralin were performed in soil–plastic–atmosphere microenvironments, showing that up to 24 h significant amounts of pesticides moved away from the PE film. To determine whether PE residues could act as potential pesticide collector in soil, column elution experiments were done using chlorpyrifos, procymidone and trifluralin. Results showed an important pesticide accumulation in the mulch film (584 μg–2284 μg pesticide/g plastic) compared to soil (13 μg–32 μg pesticide/g soil). Finally, chemical and photochemical degradation of deltamethrin adsorbed in PE film was studied, finding a protective effect on hydrolysis but no protective effect on photodegradation. We believe that a deeper understanding of the dynamics among soil, plastic and pesticides in horticultural productive systems may contribute to alert for the implications of PE use for plastic sheeting.
Fil: Ramos, Laura Mabel. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Berenstein, Giselle Anahí. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Ingeniería Genética y Biología Molecular; Argentina
Materia
Polyethylene Film
Mulching
Greenhouses
Horticultural Soil
Pesticides
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/3942

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network_name_str CONICET Digital (CONICET)
spelling Polyethylene film incorporation into the horticultural soil of small periurban production units in ArgentinaRamos, Laura MabelBerenstein, Giselle AnahíHughes, Enrique AlejandroZalts, AnitaMontserrat, Javier MarceloPolyethylene FilmMulchingGreenhousesHorticultural SoilPesticideshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Horticulture makes intensive use of soil and extensive use of polyethylene (PE) sheeting and pesticides, producing an environment where the dynamics between soil and plastics can affect pesticide fate. We have determined that the presence of plastic residues in the horticultural soil of small production units equals 10% of the soil area, being meso and macro-sections the predominant fragment sizes. All soil samples were taken from different plots located in Cuartel V, Moreno district, in the suburbs of Buenos Aires city, Argentina. Laboratory experiments were conducted to see the relations among pesticide, soil and PE film. Endosulfan recovery from LDPE films (25 μm and 100 μm) was studied, observing evidence that indicated migration to the inside of the plastic matrix. To further analyze the dynamics of pesticide migration to soil and atmosphere, experiments using chlorpyrifos, procymidone and trifluralin were performed in soil–plastic–atmosphere microenvironments, showing that up to 24 h significant amounts of pesticides moved away from the PE film. To determine whether PE residues could act as potential pesticide collector in soil, column elution experiments were done using chlorpyrifos, procymidone and trifluralin. Results showed an important pesticide accumulation in the mulch film (584 μg–2284 μg pesticide/g plastic) compared to soil (13 μg–32 μg pesticide/g soil). Finally, chemical and photochemical degradation of deltamethrin adsorbed in PE film was studied, finding a protective effect on hydrolysis but no protective effect on photodegradation. We believe that a deeper understanding of the dynamics among soil, plastic and pesticides in horticultural productive systems may contribute to alert for the implications of PE use for plastic sheeting.Fil: Ramos, Laura Mabel. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; ArgentinaFil: Berenstein, Giselle Anahí. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; ArgentinaFil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; ArgentinaFil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; ArgentinaFil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Ingeniería Genética y Biología Molecular; ArgentinaElsevier2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/3942Ramos, Laura Mabel; Berenstein, Giselle Anahí; Hughes, Enrique Alejandro; Zalts, Anita; Montserrat, Javier Marcelo; Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina; Elsevier; Science of the Total Environment; 523; 4-2015; 74-810048-9697enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S004896971500426Xinfo:eu-repo/semantics/altIdentifier/issn/0048-9697info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2015.03.142info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:06:51Zoai:ri.conicet.gov.ar:11336/3942instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:06:51.798CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
title Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
spellingShingle Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
Ramos, Laura Mabel
Polyethylene Film
Mulching
Greenhouses
Horticultural Soil
Pesticides
title_short Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
title_full Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
title_fullStr Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
title_full_unstemmed Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
title_sort Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina
dc.creator.none.fl_str_mv Ramos, Laura Mabel
Berenstein, Giselle Anahí
Hughes, Enrique Alejandro
Zalts, Anita
Montserrat, Javier Marcelo
author Ramos, Laura Mabel
author_facet Ramos, Laura Mabel
Berenstein, Giselle Anahí
Hughes, Enrique Alejandro
Zalts, Anita
Montserrat, Javier Marcelo
author_role author
author2 Berenstein, Giselle Anahí
Hughes, Enrique Alejandro
Zalts, Anita
Montserrat, Javier Marcelo
author2_role author
author
author
author
dc.subject.none.fl_str_mv Polyethylene Film
Mulching
Greenhouses
Horticultural Soil
Pesticides
topic Polyethylene Film
Mulching
Greenhouses
Horticultural Soil
Pesticides
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Horticulture makes intensive use of soil and extensive use of polyethylene (PE) sheeting and pesticides, producing an environment where the dynamics between soil and plastics can affect pesticide fate. We have determined that the presence of plastic residues in the horticultural soil of small production units equals 10% of the soil area, being meso and macro-sections the predominant fragment sizes. All soil samples were taken from different plots located in Cuartel V, Moreno district, in the suburbs of Buenos Aires city, Argentina. Laboratory experiments were conducted to see the relations among pesticide, soil and PE film. Endosulfan recovery from LDPE films (25 μm and 100 μm) was studied, observing evidence that indicated migration to the inside of the plastic matrix. To further analyze the dynamics of pesticide migration to soil and atmosphere, experiments using chlorpyrifos, procymidone and trifluralin were performed in soil–plastic–atmosphere microenvironments, showing that up to 24 h significant amounts of pesticides moved away from the PE film. To determine whether PE residues could act as potential pesticide collector in soil, column elution experiments were done using chlorpyrifos, procymidone and trifluralin. Results showed an important pesticide accumulation in the mulch film (584 μg–2284 μg pesticide/g plastic) compared to soil (13 μg–32 μg pesticide/g soil). Finally, chemical and photochemical degradation of deltamethrin adsorbed in PE film was studied, finding a protective effect on hydrolysis but no protective effect on photodegradation. We believe that a deeper understanding of the dynamics among soil, plastic and pesticides in horticultural productive systems may contribute to alert for the implications of PE use for plastic sheeting.
Fil: Ramos, Laura Mabel. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Berenstein, Giselle Anahí. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Hughes, Enrique Alejandro. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Zalts, Anita. Universidad Nacional de General Sarmiento. Instituto de Ciencias. Area de Quimica; Argentina
Fil: Montserrat, Javier Marcelo. Consejo Nacional de Investigaciones Científicas y Técnicas. Instituto de Investigaciones en Ingeniería Genética y Biología Molecular; Argentina
description Horticulture makes intensive use of soil and extensive use of polyethylene (PE) sheeting and pesticides, producing an environment where the dynamics between soil and plastics can affect pesticide fate. We have determined that the presence of plastic residues in the horticultural soil of small production units equals 10% of the soil area, being meso and macro-sections the predominant fragment sizes. All soil samples were taken from different plots located in Cuartel V, Moreno district, in the suburbs of Buenos Aires city, Argentina. Laboratory experiments were conducted to see the relations among pesticide, soil and PE film. Endosulfan recovery from LDPE films (25 μm and 100 μm) was studied, observing evidence that indicated migration to the inside of the plastic matrix. To further analyze the dynamics of pesticide migration to soil and atmosphere, experiments using chlorpyrifos, procymidone and trifluralin were performed in soil–plastic–atmosphere microenvironments, showing that up to 24 h significant amounts of pesticides moved away from the PE film. To determine whether PE residues could act as potential pesticide collector in soil, column elution experiments were done using chlorpyrifos, procymidone and trifluralin. Results showed an important pesticide accumulation in the mulch film (584 μg–2284 μg pesticide/g plastic) compared to soil (13 μg–32 μg pesticide/g soil). Finally, chemical and photochemical degradation of deltamethrin adsorbed in PE film was studied, finding a protective effect on hydrolysis but no protective effect on photodegradation. We believe that a deeper understanding of the dynamics among soil, plastic and pesticides in horticultural productive systems may contribute to alert for the implications of PE use for plastic sheeting.
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/3942
Ramos, Laura Mabel; Berenstein, Giselle Anahí; Hughes, Enrique Alejandro; Zalts, Anita; Montserrat, Javier Marcelo; Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina; Elsevier; Science of the Total Environment; 523; 4-2015; 74-81
0048-9697
url http://hdl.handle.net/11336/3942
identifier_str_mv Ramos, Laura Mabel; Berenstein, Giselle Anahí; Hughes, Enrique Alejandro; Zalts, Anita; Montserrat, Javier Marcelo; Polyethylene film incorporation into the horticultural soil of small periurban production units in Argentina; Elsevier; Science of the Total Environment; 523; 4-2015; 74-81
0048-9697
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S004896971500426X
info:eu-repo/semantics/altIdentifier/issn/0048-9697
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.scitotenv.2015.03.142
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/msword
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
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instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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