Polyethylene Film Surface Modification via Benzoic Acid Grafting
- Autores
- Grafia, Ana Luisa; Barbosa, Silvia Elena
- Año de publicación
- 2024
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A polyethylene (PE) film surface modification method is proposed via benzoic acid (BA)alkylation grafting to improve the surface affinity to polar substances. The procedure involves sequentially spraying AlCl3 and BA onto the heat-softened PE surface. The occurrence of the alkylation reaction was evaluated through comparative chemical, morphological, and thermal analyses. It was demonstrated that the grafting reaction of BA onto the PE film surface took place, limited to the surface layer, while preserving the bulk properties of PE. The reaction resulted in the formation of aluminum benzoate complexes, which improved the surface affinity to polar compounds. The impact of grafting on the surface properties of PE was further assessed by comparing the behavior of PE films treated with BA and untreated PE films when painted with watercolors. The PE film grafted with BA exhibited increased affinity towards watercolors, providing strong evidence of a change in surface polarity from hydrophobic to hydrophilic. These findings indicate that the proposed methodology effectively renders the PE surface paintable, even with non-toxic water-based inks, making it suitable for applications such as packaging.
Fil: Grafia, Ana Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina - Materia
-
POLYETHYLENE SURFACE MODIFICATION
GRAFTING
ALUMINUM BENZOATE COMPLEXES
HIDROPHOBIC TO HYDDROPHILIC - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/237696
Ver los metadatos del registro completo
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3498 |
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CONICET Digital (CONICET) |
spelling |
Polyethylene Film Surface Modification via Benzoic Acid GraftingGrafia, Ana LuisaBarbosa, Silvia ElenaPOLYETHYLENE SURFACE MODIFICATIONGRAFTINGALUMINUM BENZOATE COMPLEXESHIDROPHOBIC TO HYDDROPHILIChttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2A polyethylene (PE) film surface modification method is proposed via benzoic acid (BA)alkylation grafting to improve the surface affinity to polar substances. The procedure involves sequentially spraying AlCl3 and BA onto the heat-softened PE surface. The occurrence of the alkylation reaction was evaluated through comparative chemical, morphological, and thermal analyses. It was demonstrated that the grafting reaction of BA onto the PE film surface took place, limited to the surface layer, while preserving the bulk properties of PE. The reaction resulted in the formation of aluminum benzoate complexes, which improved the surface affinity to polar compounds. The impact of grafting on the surface properties of PE was further assessed by comparing the behavior of PE films treated with BA and untreated PE films when painted with watercolors. The PE film grafted with BA exhibited increased affinity towards watercolors, providing strong evidence of a change in surface polarity from hydrophobic to hydrophilic. These findings indicate that the proposed methodology effectively renders the PE surface paintable, even with non-toxic water-based inks, making it suitable for applications such as packaging.Fil: Grafia, Ana Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaMDPI2024-05-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/237696Grafia, Ana Luisa; Barbosa, Silvia Elena; Polyethylene Film Surface Modification via Benzoic Acid Grafting; MDPI; Polymers; 16; 9; 5-5-2024; 1291-13072073-4360CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/16/9/1291info:eu-repo/semantics/altIdentifier/doi/10.3390/polym16091291info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:23:41Zoai:ri.conicet.gov.ar:11336/237696instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:23:41.884CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
title |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
spellingShingle |
Polyethylene Film Surface Modification via Benzoic Acid Grafting Grafia, Ana Luisa POLYETHYLENE SURFACE MODIFICATION GRAFTING ALUMINUM BENZOATE COMPLEXES HIDROPHOBIC TO HYDDROPHILIC |
title_short |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
title_full |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
title_fullStr |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
title_full_unstemmed |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
title_sort |
Polyethylene Film Surface Modification via Benzoic Acid Grafting |
dc.creator.none.fl_str_mv |
Grafia, Ana Luisa Barbosa, Silvia Elena |
author |
Grafia, Ana Luisa |
author_facet |
Grafia, Ana Luisa Barbosa, Silvia Elena |
author_role |
author |
author2 |
Barbosa, Silvia Elena |
author2_role |
author |
dc.subject.none.fl_str_mv |
POLYETHYLENE SURFACE MODIFICATION GRAFTING ALUMINUM BENZOATE COMPLEXES HIDROPHOBIC TO HYDDROPHILIC |
topic |
POLYETHYLENE SURFACE MODIFICATION GRAFTING ALUMINUM BENZOATE COMPLEXES HIDROPHOBIC TO HYDDROPHILIC |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
A polyethylene (PE) film surface modification method is proposed via benzoic acid (BA)alkylation grafting to improve the surface affinity to polar substances. The procedure involves sequentially spraying AlCl3 and BA onto the heat-softened PE surface. The occurrence of the alkylation reaction was evaluated through comparative chemical, morphological, and thermal analyses. It was demonstrated that the grafting reaction of BA onto the PE film surface took place, limited to the surface layer, while preserving the bulk properties of PE. The reaction resulted in the formation of aluminum benzoate complexes, which improved the surface affinity to polar compounds. The impact of grafting on the surface properties of PE was further assessed by comparing the behavior of PE films treated with BA and untreated PE films when painted with watercolors. The PE film grafted with BA exhibited increased affinity towards watercolors, providing strong evidence of a change in surface polarity from hydrophobic to hydrophilic. These findings indicate that the proposed methodology effectively renders the PE surface paintable, even with non-toxic water-based inks, making it suitable for applications such as packaging. Fil: Grafia, Ana Luisa. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina Fil: Barbosa, Silvia Elena. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina |
description |
A polyethylene (PE) film surface modification method is proposed via benzoic acid (BA)alkylation grafting to improve the surface affinity to polar substances. The procedure involves sequentially spraying AlCl3 and BA onto the heat-softened PE surface. The occurrence of the alkylation reaction was evaluated through comparative chemical, morphological, and thermal analyses. It was demonstrated that the grafting reaction of BA onto the PE film surface took place, limited to the surface layer, while preserving the bulk properties of PE. The reaction resulted in the formation of aluminum benzoate complexes, which improved the surface affinity to polar compounds. The impact of grafting on the surface properties of PE was further assessed by comparing the behavior of PE films treated with BA and untreated PE films when painted with watercolors. The PE film grafted with BA exhibited increased affinity towards watercolors, providing strong evidence of a change in surface polarity from hydrophobic to hydrophilic. These findings indicate that the proposed methodology effectively renders the PE surface paintable, even with non-toxic water-based inks, making it suitable for applications such as packaging. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-05-05 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/237696 Grafia, Ana Luisa; Barbosa, Silvia Elena; Polyethylene Film Surface Modification via Benzoic Acid Grafting; MDPI; Polymers; 16; 9; 5-5-2024; 1291-1307 2073-4360 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/237696 |
identifier_str_mv |
Grafia, Ana Luisa; Barbosa, Silvia Elena; Polyethylene Film Surface Modification via Benzoic Acid Grafting; MDPI; Polymers; 16; 9; 5-5-2024; 1291-1307 2073-4360 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2073-4360/16/9/1291 info:eu-repo/semantics/altIdentifier/doi/10.3390/polym16091291 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
MDPI |
publisher.none.fl_str_mv |
MDPI |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614232371363840 |
score |
13.070432 |