Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin

Autores
Vicerich, Maria Ana; Oportus, Marcelo; Benitez, Viviana Monica; Reyes, Patricio; Pieck, Carlos Luis
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the Na addition on Pt-Ir/Al2O3 on the reaction of selective ring opening of decalin and methyl cyclopentane was studied. The catalysts were evaluated by means of TPR, pyridine TPD, TEM, FTIR-CO and by the reaction tests of cyclohexane dehydrogenation, hydrogenolysis of cyclopentane, selective ring opening of decalin and methyl cyclopentane. It was found that Na strongly decreases the acidity and influences the metal properties of Pt-Ir/Al2O3 catalysts. The interaction between Pt and Ir is increased by the presence of Na, with larger metal crystals being obtained on the support modified by Na. As a consequence, the catalytic properties are also modified and the CP/CH ratio (parameter of demanding/not demanding reaction) is increased with sodium concentration. In the case of MCP reaction, Na strongly decreases the aromatic and n-C6 formation and favors the selective reaction mechanism, thus favoring the formation of 2MP and 3MP. For the decalin reaction, it was found that the yield to the dehydrogenated product of the catalysts supported on Al2O3-Na is lower than that of the free Na-alumina supported catalyst, whereas the opposite occurs with the yield to C1 due to the higher hydrogenolytic and lower dehydrogenation activity of the catalysts with Na. The yield to ring contraction (RC) products is higheron the catalyst without Na due to the higher acidity which favors the ring contraction reaction and the lower metallic activity; thus, the transformation of the RC product to ring opening products is decreased.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Oportus, Marcelo. Universidad de Concepción; Chile
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Reyes, Patricio. Universidad de Concepción; Chile
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Selective Ring Opening
Pt-Ir/Al2o3 Catalysts
Na Influence
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31731
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/31731
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalinVicerich, Maria AnaOportus, MarceloBenitez, Viviana MonicaReyes, PatricioPieck, Carlos LuisSelective Ring OpeningPt-Ir/Al2o3 CatalystsNa Influencehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the Na addition on Pt-Ir/Al2O3 on the reaction of selective ring opening of decalin and methyl cyclopentane was studied. The catalysts were evaluated by means of TPR, pyridine TPD, TEM, FTIR-CO and by the reaction tests of cyclohexane dehydrogenation, hydrogenolysis of cyclopentane, selective ring opening of decalin and methyl cyclopentane. It was found that Na strongly decreases the acidity and influences the metal properties of Pt-Ir/Al2O3 catalysts. The interaction between Pt and Ir is increased by the presence of Na, with larger metal crystals being obtained on the support modified by Na. As a consequence, the catalytic properties are also modified and the CP/CH ratio (parameter of demanding/not demanding reaction) is increased with sodium concentration. In the case of MCP reaction, Na strongly decreases the aromatic and n-C6 formation and favors the selective reaction mechanism, thus favoring the formation of 2MP and 3MP. For the decalin reaction, it was found that the yield to the dehydrogenated product of the catalysts supported on Al2O3-Na is lower than that of the free Na-alumina supported catalyst, whereas the opposite occurs with the yield to C1 due to the higher hydrogenolytic and lower dehydrogenation activity of the catalysts with Na. The yield to ring contraction (RC) products is higheron the catalyst without Na due to the higher acidity which favors the ring contraction reaction and the lower metallic activity; thus, the transformation of the RC product to ring opening products is decreased.Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Oportus, Marcelo. Universidad de Concepción; ChileFil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Reyes, Patricio. Universidad de Concepción; ChileFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaElsevier2014-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31731Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin; Elsevier; Applied Catalysis A: General; 480; 4-2014; 42-490926-860XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2014.04.036info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X14002907info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:39:31Zoai:ri.conicet.gov.ar:11336/31731instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:39:31.591CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
title Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
spellingShingle Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
Vicerich, Maria Ana
Selective Ring Opening
Pt-Ir/Al2o3 Catalysts
Na Influence
title_short Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
title_full Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
title_fullStr Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
title_full_unstemmed Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
title_sort Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin
dc.creator.none.fl_str_mv Vicerich, Maria Ana
Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author Vicerich, Maria Ana
author_facet Vicerich, Maria Ana
Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author_role author
author2 Oportus, Marcelo
Benitez, Viviana Monica
Reyes, Patricio
Pieck, Carlos Luis
author2_role author
author
author
author
dc.subject.none.fl_str_mv Selective Ring Opening
Pt-Ir/Al2o3 Catalysts
Na Influence
topic Selective Ring Opening
Pt-Ir/Al2o3 Catalysts
Na Influence
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the Na addition on Pt-Ir/Al2O3 on the reaction of selective ring opening of decalin and methyl cyclopentane was studied. The catalysts were evaluated by means of TPR, pyridine TPD, TEM, FTIR-CO and by the reaction tests of cyclohexane dehydrogenation, hydrogenolysis of cyclopentane, selective ring opening of decalin and methyl cyclopentane. It was found that Na strongly decreases the acidity and influences the metal properties of Pt-Ir/Al2O3 catalysts. The interaction between Pt and Ir is increased by the presence of Na, with larger metal crystals being obtained on the support modified by Na. As a consequence, the catalytic properties are also modified and the CP/CH ratio (parameter of demanding/not demanding reaction) is increased with sodium concentration. In the case of MCP reaction, Na strongly decreases the aromatic and n-C6 formation and favors the selective reaction mechanism, thus favoring the formation of 2MP and 3MP. For the decalin reaction, it was found that the yield to the dehydrogenated product of the catalysts supported on Al2O3-Na is lower than that of the free Na-alumina supported catalyst, whereas the opposite occurs with the yield to C1 due to the higher hydrogenolytic and lower dehydrogenation activity of the catalysts with Na. The yield to ring contraction (RC) products is higheron the catalyst without Na due to the higher acidity which favors the ring contraction reaction and the lower metallic activity; thus, the transformation of the RC product to ring opening products is decreased.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Oportus, Marcelo. Universidad de Concepción; Chile
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Reyes, Patricio. Universidad de Concepción; Chile
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The influence of the Na addition on Pt-Ir/Al2O3 on the reaction of selective ring opening of decalin and methyl cyclopentane was studied. The catalysts were evaluated by means of TPR, pyridine TPD, TEM, FTIR-CO and by the reaction tests of cyclohexane dehydrogenation, hydrogenolysis of cyclopentane, selective ring opening of decalin and methyl cyclopentane. It was found that Na strongly decreases the acidity and influences the metal properties of Pt-Ir/Al2O3 catalysts. The interaction between Pt and Ir is increased by the presence of Na, with larger metal crystals being obtained on the support modified by Na. As a consequence, the catalytic properties are also modified and the CP/CH ratio (parameter of demanding/not demanding reaction) is increased with sodium concentration. In the case of MCP reaction, Na strongly decreases the aromatic and n-C6 formation and favors the selective reaction mechanism, thus favoring the formation of 2MP and 3MP. For the decalin reaction, it was found that the yield to the dehydrogenated product of the catalysts supported on Al2O3-Na is lower than that of the free Na-alumina supported catalyst, whereas the opposite occurs with the yield to C1 due to the higher hydrogenolytic and lower dehydrogenation activity of the catalysts with Na. The yield to ring contraction (RC) products is higheron the catalyst without Na due to the higher acidity which favors the ring contraction reaction and the lower metallic activity; thus, the transformation of the RC product to ring opening products is decreased.
publishDate 2014
dc.date.none.fl_str_mv 2014-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31731
Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin; Elsevier; Applied Catalysis A: General; 480; 4-2014; 42-49
0926-860X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31731
identifier_str_mv Pieck, Carlos Luis; Reyes, Patricio; Benitez, Viviana Monica; Oportus, Marcelo; Vicerich, Maria Ana; Influence of Na content on the catalytic properties of Pt-Ir/Al2O3 catalysts for selective ring opening of decalin; Elsevier; Applied Catalysis A: General; 480; 4-2014; 42-49
0926-860X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apcata.2014.04.036
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0926860X14002907
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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