Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions

Autores
Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis
Año de publicación
2014
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Materia
Pt-Ir
Bifunctional Catalysts
Ring Opening
Decalin
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/31892
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening ReactionsVicerich, Maria AnaBenitez, Viviana MonicaSánchez, María AmparoPieck, Carlos LuisPt-IrBifunctional CatalystsRing OpeningDecalinhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSpringer2014-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/zipapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31892Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-9181011-372X1572-879XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1459-2info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10562-014-1459-2info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:20:42Zoai:ri.conicet.gov.ar:11336/31892instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:20:42.905CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
title Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
spellingShingle Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
Vicerich, Maria Ana
Pt-Ir
Bifunctional Catalysts
Ring Opening
Decalin
title_short Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
title_full Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
title_fullStr Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
title_full_unstemmed Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
title_sort Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
dc.creator.none.fl_str_mv Vicerich, Maria Ana
Benitez, Viviana Monica
Sánchez, María Amparo
Pieck, Carlos Luis
author Vicerich, Maria Ana
author_facet Vicerich, Maria Ana
Benitez, Viviana Monica
Sánchez, María Amparo
Pieck, Carlos Luis
author_role author
author2 Benitez, Viviana Monica
Sánchez, María Amparo
Pieck, Carlos Luis
author2_role author
author
author
dc.subject.none.fl_str_mv Pt-Ir
Bifunctional Catalysts
Ring Opening
Decalin
topic Pt-Ir
Bifunctional Catalysts
Ring Opening
Decalin
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
description The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.
publishDate 2014
dc.date.none.fl_str_mv 2014-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/31892
Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-918
1011-372X
1572-879X
CONICET Digital
CONICET
url http://hdl.handle.net/11336/31892
identifier_str_mv Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-918
1011-372X
1572-879X
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1459-2
info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10562-014-1459-2
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/zip
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.229304

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