Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions
- Autores
- Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.
Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina
Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina - Materia
-
Pt-Ir
Bifunctional Catalysts
Ring Opening
Decalin - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/31892
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Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening ReactionsVicerich, Maria AnaBenitez, Viviana MonicaSánchez, María AmparoPieck, Carlos LuisPt-IrBifunctional CatalystsRing OpeningDecalinhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening.Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaFil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; ArgentinaSpringer2014-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/zipapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/31892Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-9181011-372X1572-879XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1459-2info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10562-014-1459-2info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:47:17Zoai:ri.conicet.gov.ar:11336/31892instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:47:17.815CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
title |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
spellingShingle |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions Vicerich, Maria Ana Pt-Ir Bifunctional Catalysts Ring Opening Decalin |
title_short |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
title_full |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
title_fullStr |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
title_full_unstemmed |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
title_sort |
Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions |
dc.creator.none.fl_str_mv |
Vicerich, Maria Ana Benitez, Viviana Monica Sánchez, María Amparo Pieck, Carlos Luis |
author |
Vicerich, Maria Ana |
author_facet |
Vicerich, Maria Ana Benitez, Viviana Monica Sánchez, María Amparo Pieck, Carlos Luis |
author_role |
author |
author2 |
Benitez, Viviana Monica Sánchez, María Amparo Pieck, Carlos Luis |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Pt-Ir Bifunctional Catalysts Ring Opening Decalin |
topic |
Pt-Ir Bifunctional Catalysts Ring Opening Decalin |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening. Fil: Vicerich, Maria Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Benitez, Viviana Monica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Sánchez, María Amparo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina Fil: Pieck, Carlos Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica ; Argentina |
description |
The influence of the supports (Al2O3, TiO2 and SiO2) on the activity and selectivity of Pt-Ir catalysts for the ring opening of decalin was studied. It was found that the properties of the supports strongly influence the distribution, size and Pt-Ir interaction of the metal particles. They therefore also influence the catalytic activity for reactions like dehydrogenation and hydrogenolysis, but also specifically the activity for ring opening reactions of naphthenes. Via their acid sites the supports influence ring opening reactions although the effect is not very marked on conversion because the acidity differences are not very significant among them. The results show that the highest decalin conversion for three different supports, alumina, silica and titania, is obtained with the catalysts of highest metal loading. The best selectivity to ring opening products is obtained with Pt-Ir(1.0)/Al2O3 catalyst. Moreover this catalyst shows the highest performance for MCP ring opening. |
publishDate |
2014 |
dc.date.none.fl_str_mv |
2014-12 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/31892 Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-918 1011-372X 1572-879X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/31892 |
identifier_str_mv |
Vicerich, Maria Ana; Benitez, Viviana Monica; Sánchez, María Amparo; Pieck, Carlos Luis; Influence of Support Material on the Activity and Selectivity of Pt–Ir Catalysts for Ring Opening Reactions; Springer; Catalysis Letters; 145; 3; 12-2014; 910-918 1011-372X 1572-879X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s10562-014-1459-2 info:eu-repo/semantics/altIdentifier/url/https://link.springer.com/article/10.1007%2Fs10562-014-1459-2 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/zip application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Springer |
publisher.none.fl_str_mv |
Springer |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.070432 |