Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance

Autores
Podio, Natalia Soledad; Baroni, María Verónica; Badini, Raul G.; Inga, Marcela; Ostera, Hector Adolfo; Cagnoni, Mariana Celina; Gautier, Eduardo Amilcar; Peral Garcia, Pilar; Hoogewerff, Jurian; Wunderlin, Daniel Alberto
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this study was to investigate if elemental and isotopic signatures of Argentinean wheat can be used to develop a reliable fingerprint to assess its geographical provenance. For this pilot study we used wheat cultivated at three different regions (Buenos Aires, Córdoba, and Entre Ríos), together with matching soil and water. Elemental composition was determined by ICP-MS. δ13C and δ15N were measured by isotopic ratio mass spectrometry, while 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. Wheat samples from three sampling sites were differentiated by the combination of 11 key variables (K/Rb, Ca/Sr, Ba, 87Sr/86Sr, Co, Mo, Zn, Mn, Eu, δ13C, and Na), demonstrating differences among the three studied regions. The application of generalized Procrustes analysis showed 99.2% consensus between cultivation soil, irrigation water, and wheat samples, in addition to clear differences between studied areas. Furthermore, canonical correlation analysis showed significant correlation between the elemental and isotopic profiles of wheat and those corresponding to both soil and water (r2 = 0.97, p < 0.001 and r2 = 0.96, p < 0.001, respectively). To our knowledge, this is the first report demonstrating the correspondence between soil, water, and wheat samples using different statistical methods, showing that wheat elemental and isotopic compositions are mainly related to soil and irrigation water characteristics of the site of growth.
Fil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Badini, Raul G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; Argentina
Fil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; Argentina
Fil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Gautier, Eduardo Amilcar. Comisión Nacional de Energía Atómica; Argentina
Fil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria "Ing. Fernando Noel Dulout". Universidad Nacional de La Plata. Facultad de Ciencias Veterinarias. Instituto de Genética Veterinaria; Argentina
Fil: Hoogewerff, Jurian. University Of Otago; Nueva Zelanda
Fil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Materia
Wheat
Multielement Composition
Isotopes
Geographical Origin
Food Authenticity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24005
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate ProvenancePodio, Natalia SoledadBaroni, María VerónicaBadini, Raul G.Inga, MarcelaOstera, Hector AdolfoCagnoni, Mariana CelinaGautier, Eduardo AmilcarPeral Garcia, PilarHoogewerff, JurianWunderlin, Daniel AlbertoWheatMultielement CompositionIsotopesGeographical OriginFood Authenticityhttps://purl.org/becyt/ford/4.3https://purl.org/becyt/ford/4The aim of this study was to investigate if elemental and isotopic signatures of Argentinean wheat can be used to develop a reliable fingerprint to assess its geographical provenance. For this pilot study we used wheat cultivated at three different regions (Buenos Aires, Córdoba, and Entre Ríos), together with matching soil and water. Elemental composition was determined by ICP-MS. δ13C and δ15N were measured by isotopic ratio mass spectrometry, while 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. Wheat samples from three sampling sites were differentiated by the combination of 11 key variables (K/Rb, Ca/Sr, Ba, 87Sr/86Sr, Co, Mo, Zn, Mn, Eu, δ13C, and Na), demonstrating differences among the three studied regions. The application of generalized Procrustes analysis showed 99.2% consensus between cultivation soil, irrigation water, and wheat samples, in addition to clear differences between studied areas. Furthermore, canonical correlation analysis showed significant correlation between the elemental and isotopic profiles of wheat and those corresponding to both soil and water (r2 = 0.97, p < 0.001 and r2 = 0.96, p < 0.001, respectively). To our knowledge, this is the first report demonstrating the correspondence between soil, water, and wheat samples using different statistical methods, showing that wheat elemental and isotopic compositions are mainly related to soil and irrigation water characteristics of the site of growth.Fil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaFil: Badini, Raul G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; ArgentinaFil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; ArgentinaFil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; ArgentinaFil: Gautier, Eduardo Amilcar. Comisión Nacional de Energía Atómica; ArgentinaFil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria "Ing. Fernando Noel Dulout". Universidad Nacional de La Plata. Facultad de Ciencias Veterinarias. Instituto de Genética Veterinaria; ArgentinaFil: Hoogewerff, Jurian. University Of Otago; Nueva ZelandaFil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; ArgentinaAmerican Chemical Society2013-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24005Podio, Natalia Soledad; Baroni, María Verónica; Badini, Raul G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance; American Chemical Society; Journal of Agricultural and Food Chemistry; 61; 3-2013; 3763-37730021-8561CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/jf305258rinfo:eu-repo/semantics/altIdentifier/doi/10.1021/jf305258rinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:10:30Zoai:ri.conicet.gov.ar:11336/24005instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:10:30.469CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
title Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
spellingShingle Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
Podio, Natalia Soledad
Wheat
Multielement Composition
Isotopes
Geographical Origin
Food Authenticity
title_short Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
title_full Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
title_fullStr Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
title_full_unstemmed Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
title_sort Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance
dc.creator.none.fl_str_mv Podio, Natalia Soledad
Baroni, María Verónica
Badini, Raul G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author Podio, Natalia Soledad
author_facet Podio, Natalia Soledad
Baroni, María Verónica
Badini, Raul G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author_role author
author2 Baroni, María Verónica
Badini, Raul G.
Inga, Marcela
Ostera, Hector Adolfo
Cagnoni, Mariana Celina
Gautier, Eduardo Amilcar
Peral Garcia, Pilar
Hoogewerff, Jurian
Wunderlin, Daniel Alberto
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Wheat
Multielement Composition
Isotopes
Geographical Origin
Food Authenticity
topic Wheat
Multielement Composition
Isotopes
Geographical Origin
Food Authenticity
purl_subject.fl_str_mv https://purl.org/becyt/ford/4.3
https://purl.org/becyt/ford/4
dc.description.none.fl_txt_mv The aim of this study was to investigate if elemental and isotopic signatures of Argentinean wheat can be used to develop a reliable fingerprint to assess its geographical provenance. For this pilot study we used wheat cultivated at three different regions (Buenos Aires, Córdoba, and Entre Ríos), together with matching soil and water. Elemental composition was determined by ICP-MS. δ13C and δ15N were measured by isotopic ratio mass spectrometry, while 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. Wheat samples from three sampling sites were differentiated by the combination of 11 key variables (K/Rb, Ca/Sr, Ba, 87Sr/86Sr, Co, Mo, Zn, Mn, Eu, δ13C, and Na), demonstrating differences among the three studied regions. The application of generalized Procrustes analysis showed 99.2% consensus between cultivation soil, irrigation water, and wheat samples, in addition to clear differences between studied areas. Furthermore, canonical correlation analysis showed significant correlation between the elemental and isotopic profiles of wheat and those corresponding to both soil and water (r2 = 0.97, p < 0.001 and r2 = 0.96, p < 0.001, respectively). To our knowledge, this is the first report demonstrating the correspondence between soil, water, and wheat samples using different statistical methods, showing that wheat elemental and isotopic compositions are mainly related to soil and irrigation water characteristics of the site of growth.
Fil: Podio, Natalia Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Baroni, María Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
Fil: Badini, Raul G.. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; Argentina
Fil: Inga, Marcela. Provincia de Córdoba. Ministerio de Ciencia y Técnica. Centro de Excelencia En Productos y Procesos de Córdoba; Argentina
Fil: Ostera, Hector Adolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Cagnoni, Mariana Celina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Geocronología y Geología Isotopica. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Geocronología y Geología Isotópica; Argentina
Fil: Gautier, Eduardo Amilcar. Comisión Nacional de Energía Atómica; Argentina
Fil: Peral Garcia, Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico CONICET- La Plata. Instituto de Genética Veterinaria "Ing. Fernando Noel Dulout". Universidad Nacional de La Plata. Facultad de Ciencias Veterinarias. Instituto de Genética Veterinaria; Argentina
Fil: Hoogewerff, Jurian. University Of Otago; Nueva Zelanda
Fil: Wunderlin, Daniel Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Ciencia y Tecnología de Alimentos Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Ciencia y Tecnología de Alimentos Córdoba; Argentina
description The aim of this study was to investigate if elemental and isotopic signatures of Argentinean wheat can be used to develop a reliable fingerprint to assess its geographical provenance. For this pilot study we used wheat cultivated at three different regions (Buenos Aires, Córdoba, and Entre Ríos), together with matching soil and water. Elemental composition was determined by ICP-MS. δ13C and δ15N were measured by isotopic ratio mass spectrometry, while 87Sr/86Sr ratio was determined using thermal ionization mass spectrometry. Wheat samples from three sampling sites were differentiated by the combination of 11 key variables (K/Rb, Ca/Sr, Ba, 87Sr/86Sr, Co, Mo, Zn, Mn, Eu, δ13C, and Na), demonstrating differences among the three studied regions. The application of generalized Procrustes analysis showed 99.2% consensus between cultivation soil, irrigation water, and wheat samples, in addition to clear differences between studied areas. Furthermore, canonical correlation analysis showed significant correlation between the elemental and isotopic profiles of wheat and those corresponding to both soil and water (r2 = 0.97, p < 0.001 and r2 = 0.96, p < 0.001, respectively). To our knowledge, this is the first report demonstrating the correspondence between soil, water, and wheat samples using different statistical methods, showing that wheat elemental and isotopic compositions are mainly related to soil and irrigation water characteristics of the site of growth.
publishDate 2013
dc.date.none.fl_str_mv 2013-03
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24005
Podio, Natalia Soledad; Baroni, María Verónica; Badini, Raul G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance; American Chemical Society; Journal of Agricultural and Food Chemistry; 61; 3-2013; 3763-3773
0021-8561
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24005
identifier_str_mv Podio, Natalia Soledad; Baroni, María Verónica; Badini, Raul G.; Inga, Marcela; Ostera, Hector Adolfo; et al.; Elemental and Isotopic Fingerprint of Argentinean Wheat. Matching Soil, Water, and Crop Composition to Differentiate Provenance; American Chemical Society; Journal of Agricultural and Food Chemistry; 61; 3-2013; 3763-3773
0021-8561
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
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info:eu-repo/semantics/altIdentifier/doi/10.1021/jf305258r
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
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dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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