Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions

Autores
Acosta, Delicia Ester; Ramírez, Norma; Erdamnn, Eleonora; Gonzo, Elio Emilio; Destefanis, Hugo Alberto
Año de publicación
2008
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nickel borides doped with elements of first transition series (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% (w/w) respect to Ni, and prepared with the same method as NiB, were used in the glucose and the nitrobenzene hydrogenation reactions. The amorphous catalysts were prepared by chemical reduction of nickel and metallic (Cr, Mn, Fe, Co, Cu, and Zn) salts with borane-tetrahydrofurane (BH3-THF) complex in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. The results show that bimetallic borides follow a pattern related to the nature of the dopants metal. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopants metal. SEM studies show the same spongy-morphology in all cases. The logarithm of the ratio between bimetallic boride and nickel borides specific rates, for nitrobenzene hydrogenation, follow a linear relation with respect to the same relation for glucose hydrogenation. These results demonstrate that the dopants effect on the free activation energy is the same for both reaction systems. This effect could be related with electronic modifications introduced by the dopants metal on nickel boride.
Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Ramírez, Norma. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Erdamnn, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Materia
CATALYST
GLUCOSE
NICKEL BORIDES
NITROBENZENE HYDROGENATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/129352
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/129352
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactionsAcosta, Delicia EsterRamírez, NormaErdamnn, EleonoraGonzo, Elio EmilioDestefanis, Hugo AlbertoCATALYSTGLUCOSENICKEL BORIDESNITROBENZENE HYDROGENATIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Nickel borides doped with elements of first transition series (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% (w/w) respect to Ni, and prepared with the same method as NiB, were used in the glucose and the nitrobenzene hydrogenation reactions. The amorphous catalysts were prepared by chemical reduction of nickel and metallic (Cr, Mn, Fe, Co, Cu, and Zn) salts with borane-tetrahydrofurane (BH3-THF) complex in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. The results show that bimetallic borides follow a pattern related to the nature of the dopants metal. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopants metal. SEM studies show the same spongy-morphology in all cases. The logarithm of the ratio between bimetallic boride and nickel borides specific rates, for nitrobenzene hydrogenation, follow a linear relation with respect to the same relation for glucose hydrogenation. These results demonstrate that the dopants effect on the free activation energy is the same for both reaction systems. This effect could be related with electronic modifications introduced by the dopants metal on nickel boride.Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Ramírez, Norma. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Erdamnn, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaElsevier Science2008-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/129352Acosta, Delicia Ester; Ramírez, Norma; Erdamnn, Eleonora; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 49-550920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.125info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0920586107009649info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:33:03Zoai:ri.conicet.gov.ar:11336/129352instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:33:04.125CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
title Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
spellingShingle Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
Acosta, Delicia Ester
CATALYST
GLUCOSE
NICKEL BORIDES
NITROBENZENE HYDROGENATION
title_short Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
title_full Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
title_fullStr Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
title_full_unstemmed Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
title_sort Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions
dc.creator.none.fl_str_mv Acosta, Delicia Ester
Ramírez, Norma
Erdamnn, Eleonora
Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author Acosta, Delicia Ester
author_facet Acosta, Delicia Ester
Ramírez, Norma
Erdamnn, Eleonora
Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author_role author
author2 Ramírez, Norma
Erdamnn, Eleonora
Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author2_role author
author
author
author
dc.subject.none.fl_str_mv CATALYST
GLUCOSE
NICKEL BORIDES
NITROBENZENE HYDROGENATION
topic CATALYST
GLUCOSE
NICKEL BORIDES
NITROBENZENE HYDROGENATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Nickel borides doped with elements of first transition series (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% (w/w) respect to Ni, and prepared with the same method as NiB, were used in the glucose and the nitrobenzene hydrogenation reactions. The amorphous catalysts were prepared by chemical reduction of nickel and metallic (Cr, Mn, Fe, Co, Cu, and Zn) salts with borane-tetrahydrofurane (BH3-THF) complex in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. The results show that bimetallic borides follow a pattern related to the nature of the dopants metal. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopants metal. SEM studies show the same spongy-morphology in all cases. The logarithm of the ratio between bimetallic boride and nickel borides specific rates, for nitrobenzene hydrogenation, follow a linear relation with respect to the same relation for glucose hydrogenation. These results demonstrate that the dopants effect on the free activation energy is the same for both reaction systems. This effect could be related with electronic modifications introduced by the dopants metal on nickel boride.
Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Ramírez, Norma. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Erdamnn, Eleonora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
description Nickel borides doped with elements of first transition series (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% (w/w) respect to Ni, and prepared with the same method as NiB, were used in the glucose and the nitrobenzene hydrogenation reactions. The amorphous catalysts were prepared by chemical reduction of nickel and metallic (Cr, Mn, Fe, Co, Cu, and Zn) salts with borane-tetrahydrofurane (BH3-THF) complex in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. The results show that bimetallic borides follow a pattern related to the nature of the dopants metal. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopants metal. SEM studies show the same spongy-morphology in all cases. The logarithm of the ratio between bimetallic boride and nickel borides specific rates, for nitrobenzene hydrogenation, follow a linear relation with respect to the same relation for glucose hydrogenation. These results demonstrate that the dopants effect on the free activation energy is the same for both reaction systems. This effect could be related with electronic modifications introduced by the dopants metal on nickel boride.
publishDate 2008
dc.date.none.fl_str_mv 2008-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/129352
Acosta, Delicia Ester; Ramírez, Norma; Erdamnn, Eleonora; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 49-55
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/129352
identifier_str_mv Acosta, Delicia Ester; Ramírez, Norma; Erdamnn, Eleonora; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Transition metals as dopants on nickel borides: Their catalytic activity effect on hydrogenation reactions; Elsevier Science; Catalysis Today; 133-135; 1-4; 4-2008; 49-55
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2007.12.125
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0920586107009649
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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