Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Partic...

Autores
Acosta, Delicia Ester; Gonzo, Elio Emilio; Destefanis, Hugo Alberto
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Nickel borides doped with transition metal (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% w/w respect to Ni were prepared by chemical reduction of nickel and metallic salts in methanol solution with borane-tetrahydrofurane (BH3-THF) complex obtained in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. Thermal treatment in N2 shows Ni˚, Ni2 Band NiO phases. Spongy-morphology was evident by SEM studies in all cases. XPS and TEM show that doped and non-doped nickel boride was present as Ni˚ in metallic state as principal phase and nickel alloying with boron was observed in minor quantities. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopant metal.
Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Materia
NiB
DOPED NiB
BORANE-TETRAHYDROFURANE REDUCTION
CATALYST
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/61300
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride ParticlesAcosta, Delicia EsterGonzo, Elio EmilioDestefanis, Hugo AlbertoNiBDOPED NiBBORANE-TETRAHYDROFURANE REDUCTIONCATALYSThttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Nickel borides doped with transition metal (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% w/w respect to Ni were prepared by chemical reduction of nickel and metallic salts in methanol solution with borane-tetrahydrofurane (BH3-THF) complex obtained in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. Thermal treatment in N2 shows Ni˚, Ni2 Band NiO phases. Spongy-morphology was evident by SEM studies in all cases. XPS and TEM show that doped and non-doped nickel boride was present as Ni˚ in metallic state as principal phase and nickel alloying with boron was observed in minor quantities. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopant metal.Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaFil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; ArgentinaScientific Research Publishing2016-01-13info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/61300Acosta, Delicia Ester; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles; Scientific Research Publishing; Modern Research in Catalysis; 5; 1; 13-1-2016; 1-12; 627032168-4480CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.4236/mrc.2016.51003info:eu-repo/semantics/altIdentifier/url/http://file.scirp.org/Html/3-2530130_62703.htminfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:43:39Zoai:ri.conicet.gov.ar:11336/61300instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:43:39.485CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
title Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
spellingShingle Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
Acosta, Delicia Ester
NiB
DOPED NiB
BORANE-TETRAHYDROFURANE REDUCTION
CATALYST
title_short Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
title_full Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
title_fullStr Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
title_full_unstemmed Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
title_sort Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles
dc.creator.none.fl_str_mv Acosta, Delicia Ester
Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author Acosta, Delicia Ester
author_facet Acosta, Delicia Ester
Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author_role author
author2 Gonzo, Elio Emilio
Destefanis, Hugo Alberto
author2_role author
author
dc.subject.none.fl_str_mv NiB
DOPED NiB
BORANE-TETRAHYDROFURANE REDUCTION
CATALYST
topic NiB
DOPED NiB
BORANE-TETRAHYDROFURANE REDUCTION
CATALYST
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Nickel borides doped with transition metal (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% w/w respect to Ni were prepared by chemical reduction of nickel and metallic salts in methanol solution with borane-tetrahydrofurane (BH3-THF) complex obtained in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. Thermal treatment in N2 shows Ni˚, Ni2 Band NiO phases. Spongy-morphology was evident by SEM studies in all cases. XPS and TEM show that doped and non-doped nickel boride was present as Ni˚ in metallic state as principal phase and nickel alloying with boron was observed in minor quantities. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopant metal.
Fil: Acosta, Delicia Ester. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Gonzo, Elio Emilio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
Fil: Destefanis, Hugo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Salta. Instituto de Investigaciones para la Industria Química. Universidad Nacional de Salta. Facultad de Ingeniería. Instituto de Investigaciones para la Industria Química; Argentina
description Nickel borides doped with transition metal (Cr, Mn, Fe, Co, Cu, and Zn) MNiB, 4% w/w respect to Ni were prepared by chemical reduction of nickel and metallic salts in methanol solution with borane-tetrahydrofurane (BH3-THF) complex obtained in aprotic solvent (THF anhydrous). Different techniques were used to characterize these materials. The MNiB amorphous structure was verified by XRD. Thermal treatment in N2 shows Ni˚, Ni2 Band NiO phases. Spongy-morphology was evident by SEM studies in all cases. XPS and TEM show that doped and non-doped nickel boride was present as Ni˚ in metallic state as principal phase and nickel alloying with boron was observed in minor quantities. The oxidation stability, magnetic susceptibility and catalytic effect are correlated with parameters of each dopant metal.
publishDate 2016
dc.date.none.fl_str_mv 2016-01-13
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/61300
Acosta, Delicia Ester; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles; Scientific Research Publishing; Modern Research in Catalysis; 5; 1; 13-1-2016; 1-12; 62703
2168-4480
CONICET Digital
CONICET
url http://hdl.handle.net/11336/61300
identifier_str_mv Acosta, Delicia Ester; Gonzo, Elio Emilio; Destefanis, Hugo Alberto; Borane-Tetrahydrofurane Complex Reduction of Nickel and First Transition Metals in Tetrahydrofurane Media: Controllable Chemistry Leading to Nanoscale Metal and Metal Boride Particles; Scientific Research Publishing; Modern Research in Catalysis; 5; 1; 13-1-2016; 1-12; 62703
2168-4480
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.4236/mrc.2016.51003
info:eu-repo/semantics/altIdentifier/url/http://file.scirp.org/Html/3-2530130_62703.htm
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Scientific Research Publishing
publisher.none.fl_str_mv Scientific Research Publishing
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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