Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs)
- Autores
- Teruel, Mariano Andres; Achad, Mariana; Blanco, Maria Belen
- Año de publicación
- 2009
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The kinetics of the reactions of Cl atoms with three unsaturated carbonyl compounds at 298 K and atmospheric pressure were investigated for the first time using the GC-FID technique. Rate coefficients (in cm3 molecule-1 s-1) of k1(Cl + CH2{double bond, long}CHC(O)CH2CH3) = (2.91 ± 1.10) × 10-10, k2(Cl + CH2{double bond, long}CHOC(O)CH2CH3) = (2.06 ± 0.36) × 10-10 and k3(Cl + CH2{double bond, long}CHC(O)OCH2CH3) = (2.53 ± 0.46) × 10-10 were obtained using the relative rate method with different references. Structure activity relationships (SARs) were developed for the reactions of Cl with a wide range of unsaturated compounds. On the basis of our kinetic measurements, tropospheric lifetimes of the studied unsaturated compounds are estimated.
Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina
Fil: Achad, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina
Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina - Materia
-
Unsaturated Carbonyls
Rate Constants
Cl Atoms - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/72571
Ver los metadatos del registro completo
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Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs)Teruel, Mariano AndresAchad, MarianaBlanco, Maria BelenUnsaturated CarbonylsRate ConstantsCl Atomshttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1The kinetics of the reactions of Cl atoms with three unsaturated carbonyl compounds at 298 K and atmospheric pressure were investigated for the first time using the GC-FID technique. Rate coefficients (in cm3 molecule-1 s-1) of k1(Cl + CH2{double bond, long}CHC(O)CH2CH3) = (2.91 ± 1.10) × 10-10, k2(Cl + CH2{double bond, long}CHOC(O)CH2CH3) = (2.06 ± 0.36) × 10-10 and k3(Cl + CH2{double bond, long}CHC(O)OCH2CH3) = (2.53 ± 0.46) × 10-10 were obtained using the relative rate method with different references. Structure activity relationships (SARs) were developed for the reactions of Cl with a wide range of unsaturated compounds. On the basis of our kinetic measurements, tropospheric lifetimes of the studied unsaturated compounds are estimated.Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; ArgentinaFil: Achad, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; ArgentinaFil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; ArgentinaElsevier Science2009-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/72571Teruel, Mariano Andres; Achad, Mariana; Blanco, Maria Belen; Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs); Elsevier Science; Chemical Physics Letters; 479; 1-3; 9-2009; 25-290009-2614CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2009.07.103info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261409009592info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:54:48Zoai:ri.conicet.gov.ar:11336/72571instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:54:49.225CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
title |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
spellingShingle |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) Teruel, Mariano Andres Unsaturated Carbonyls Rate Constants Cl Atoms |
title_short |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
title_full |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
title_fullStr |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
title_full_unstemmed |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
title_sort |
Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs) |
dc.creator.none.fl_str_mv |
Teruel, Mariano Andres Achad, Mariana Blanco, Maria Belen |
author |
Teruel, Mariano Andres |
author_facet |
Teruel, Mariano Andres Achad, Mariana Blanco, Maria Belen |
author_role |
author |
author2 |
Achad, Mariana Blanco, Maria Belen |
author2_role |
author author |
dc.subject.none.fl_str_mv |
Unsaturated Carbonyls Rate Constants Cl Atoms |
topic |
Unsaturated Carbonyls Rate Constants Cl Atoms |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
The kinetics of the reactions of Cl atoms with three unsaturated carbonyl compounds at 298 K and atmospheric pressure were investigated for the first time using the GC-FID technique. Rate coefficients (in cm3 molecule-1 s-1) of k1(Cl + CH2{double bond, long}CHC(O)CH2CH3) = (2.91 ± 1.10) × 10-10, k2(Cl + CH2{double bond, long}CHOC(O)CH2CH3) = (2.06 ± 0.36) × 10-10 and k3(Cl + CH2{double bond, long}CHC(O)OCH2CH3) = (2.53 ± 0.46) × 10-10 were obtained using the relative rate method with different references. Structure activity relationships (SARs) were developed for the reactions of Cl with a wide range of unsaturated compounds. On the basis of our kinetic measurements, tropospheric lifetimes of the studied unsaturated compounds are estimated. Fil: Teruel, Mariano Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina Fil: Achad, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina Fil: Blanco, Maria Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Departamento de Fisicoquímica; Argentina |
description |
The kinetics of the reactions of Cl atoms with three unsaturated carbonyl compounds at 298 K and atmospheric pressure were investigated for the first time using the GC-FID technique. Rate coefficients (in cm3 molecule-1 s-1) of k1(Cl + CH2{double bond, long}CHC(O)CH2CH3) = (2.91 ± 1.10) × 10-10, k2(Cl + CH2{double bond, long}CHOC(O)CH2CH3) = (2.06 ± 0.36) × 10-10 and k3(Cl + CH2{double bond, long}CHC(O)OCH2CH3) = (2.53 ± 0.46) × 10-10 were obtained using the relative rate method with different references. Structure activity relationships (SARs) were developed for the reactions of Cl with a wide range of unsaturated compounds. On the basis of our kinetic measurements, tropospheric lifetimes of the studied unsaturated compounds are estimated. |
publishDate |
2009 |
dc.date.none.fl_str_mv |
2009-09 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/72571 Teruel, Mariano Andres; Achad, Mariana; Blanco, Maria Belen; Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs); Elsevier Science; Chemical Physics Letters; 479; 1-3; 9-2009; 25-29 0009-2614 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/72571 |
identifier_str_mv |
Teruel, Mariano Andres; Achad, Mariana; Blanco, Maria Belen; Kinetic study of the reactions of Cl atoms with α,β-unsaturated carbonyl compounds at atmospheric pressure and structure activity relations (SARs); Elsevier Science; Chemical Physics Letters; 479; 1-3; 9-2009; 25-29 0009-2614 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cplett.2009.07.103 info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/pii/S0009261409009592 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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13.13397 |