Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives
- Autores
- Vega Baudrit, José; Navarro Bañón, Virtudes; Vazquez, Patricia Graciela; Martín Martínez, José Miguel
- Año de publicación
- 2006
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Three nanosilicas with different silanol contents were prepared by treatment of hydrophilic fumed silica with dimethyldichlorosilane. This treatment reduced the silanol content and produced the particle agglomeration of the nanosilicas. Thermoplastic polyurethane (TPU) adhesives containing nanosilicas were prepared and characterized by FTIR spectroscopy, differential scanning calorimetry (DSC), plate–plate rheology, dynamic mechanical thermal analysis (DMTA), transmission electron microscopy (TEM) and stress–strain testing. Adhesive strength was obtained from T-peel tests of PVC/polyurethane adhesive joints. The addition of hydrophilic nanosilicas favoured the degree of phase separation between the hard (i.e. isocyanate+chain extender) and soft (i.e. polyol) segments in the TPUs; the higher the silanol content on the surface of silica, the higher the degree of phase separation, and the crystallinity of the polyurethane (due to the soft segments) was also increased. Hydrogen bonds between the ester carbonyl groups in the TPU and the silanol groups on the silica surface were created and more favoured by increasing the silanol content. The tensile strength increased and the elongation at break of the polyurethane decreased by increasing the silanol content of the nanosilica. Addition of nanosilica increased the immediate adhesion of the polyurethane adhesives to PVC, irrespective of the silanol content on the nanosilica. The higher the mechanical and the rheological properties of the polyurethanes containing nanosilicas with different silanol content, the higher the final adhesive strength.
Fil: Vega Baudrit, José. Universidad de Costa Rica; Costa Rica
Fil: Navarro Bañón, Virtudes. Universidad de Alicante; España
Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Martín Martínez, José Miguel. Universidad de Alicante; España - Materia
-
A. POLYURETHANE
C. INFRARED SPECTRA
C. RHEOLOGY
D. MECHANICAL PROPERTIES OF ADHESIVES - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/16946
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Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesivesVega Baudrit, JoséNavarro Bañón, VirtudesVazquez, Patricia GracielaMartín Martínez, José MiguelA. POLYURETHANEC. INFRARED SPECTRAC. RHEOLOGYD. MECHANICAL PROPERTIES OF ADHESIVEShttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Three nanosilicas with different silanol contents were prepared by treatment of hydrophilic fumed silica with dimethyldichlorosilane. This treatment reduced the silanol content and produced the particle agglomeration of the nanosilicas. Thermoplastic polyurethane (TPU) adhesives containing nanosilicas were prepared and characterized by FTIR spectroscopy, differential scanning calorimetry (DSC), plate–plate rheology, dynamic mechanical thermal analysis (DMTA), transmission electron microscopy (TEM) and stress–strain testing. Adhesive strength was obtained from T-peel tests of PVC/polyurethane adhesive joints. The addition of hydrophilic nanosilicas favoured the degree of phase separation between the hard (i.e. isocyanate+chain extender) and soft (i.e. polyol) segments in the TPUs; the higher the silanol content on the surface of silica, the higher the degree of phase separation, and the crystallinity of the polyurethane (due to the soft segments) was also increased. Hydrogen bonds between the ester carbonyl groups in the TPU and the silanol groups on the silica surface were created and more favoured by increasing the silanol content. The tensile strength increased and the elongation at break of the polyurethane decreased by increasing the silanol content of the nanosilica. Addition of nanosilica increased the immediate adhesion of the polyurethane adhesives to PVC, irrespective of the silanol content on the nanosilica. The higher the mechanical and the rheological properties of the polyurethanes containing nanosilicas with different silanol content, the higher the final adhesive strength.Fil: Vega Baudrit, José. Universidad de Costa Rica; Costa RicaFil: Navarro Bañón, Virtudes. Universidad de Alicante; EspañaFil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Martín Martínez, José Miguel. Universidad de Alicante; EspañaElsevier2006-08-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/16946Vega Baudrit, José; Navarro Bañón, Virtudes; Vazquez, Patricia Graciela; Martín Martínez, José Miguel; Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives; Elsevier; International Journal of Adhesion and Adhesives; 26; 5; 15-8-2006; 378-3870143-7496enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0143749605000904info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2005.06.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:13:09Zoai:ri.conicet.gov.ar:11336/16946instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:13:10.043CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
title |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
spellingShingle |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives Vega Baudrit, José A. POLYURETHANE C. INFRARED SPECTRA C. RHEOLOGY D. MECHANICAL PROPERTIES OF ADHESIVES |
title_short |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
title_full |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
title_fullStr |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
title_full_unstemmed |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
title_sort |
Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives |
dc.creator.none.fl_str_mv |
Vega Baudrit, José Navarro Bañón, Virtudes Vazquez, Patricia Graciela Martín Martínez, José Miguel |
author |
Vega Baudrit, José |
author_facet |
Vega Baudrit, José Navarro Bañón, Virtudes Vazquez, Patricia Graciela Martín Martínez, José Miguel |
author_role |
author |
author2 |
Navarro Bañón, Virtudes Vazquez, Patricia Graciela Martín Martínez, José Miguel |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
A. POLYURETHANE C. INFRARED SPECTRA C. RHEOLOGY D. MECHANICAL PROPERTIES OF ADHESIVES |
topic |
A. POLYURETHANE C. INFRARED SPECTRA C. RHEOLOGY D. MECHANICAL PROPERTIES OF ADHESIVES |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Three nanosilicas with different silanol contents were prepared by treatment of hydrophilic fumed silica with dimethyldichlorosilane. This treatment reduced the silanol content and produced the particle agglomeration of the nanosilicas. Thermoplastic polyurethane (TPU) adhesives containing nanosilicas were prepared and characterized by FTIR spectroscopy, differential scanning calorimetry (DSC), plate–plate rheology, dynamic mechanical thermal analysis (DMTA), transmission electron microscopy (TEM) and stress–strain testing. Adhesive strength was obtained from T-peel tests of PVC/polyurethane adhesive joints. The addition of hydrophilic nanosilicas favoured the degree of phase separation between the hard (i.e. isocyanate+chain extender) and soft (i.e. polyol) segments in the TPUs; the higher the silanol content on the surface of silica, the higher the degree of phase separation, and the crystallinity of the polyurethane (due to the soft segments) was also increased. Hydrogen bonds between the ester carbonyl groups in the TPU and the silanol groups on the silica surface were created and more favoured by increasing the silanol content. The tensile strength increased and the elongation at break of the polyurethane decreased by increasing the silanol content of the nanosilica. Addition of nanosilica increased the immediate adhesion of the polyurethane adhesives to PVC, irrespective of the silanol content on the nanosilica. The higher the mechanical and the rheological properties of the polyurethanes containing nanosilicas with different silanol content, the higher the final adhesive strength. Fil: Vega Baudrit, José. Universidad de Costa Rica; Costa Rica Fil: Navarro Bañón, Virtudes. Universidad de Alicante; España Fil: Vazquez, Patricia Graciela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina Fil: Martín Martínez, José Miguel. Universidad de Alicante; España |
description |
Three nanosilicas with different silanol contents were prepared by treatment of hydrophilic fumed silica with dimethyldichlorosilane. This treatment reduced the silanol content and produced the particle agglomeration of the nanosilicas. Thermoplastic polyurethane (TPU) adhesives containing nanosilicas were prepared and characterized by FTIR spectroscopy, differential scanning calorimetry (DSC), plate–plate rheology, dynamic mechanical thermal analysis (DMTA), transmission electron microscopy (TEM) and stress–strain testing. Adhesive strength was obtained from T-peel tests of PVC/polyurethane adhesive joints. The addition of hydrophilic nanosilicas favoured the degree of phase separation between the hard (i.e. isocyanate+chain extender) and soft (i.e. polyol) segments in the TPUs; the higher the silanol content on the surface of silica, the higher the degree of phase separation, and the crystallinity of the polyurethane (due to the soft segments) was also increased. Hydrogen bonds between the ester carbonyl groups in the TPU and the silanol groups on the silica surface were created and more favoured by increasing the silanol content. The tensile strength increased and the elongation at break of the polyurethane decreased by increasing the silanol content of the nanosilica. Addition of nanosilica increased the immediate adhesion of the polyurethane adhesives to PVC, irrespective of the silanol content on the nanosilica. The higher the mechanical and the rheological properties of the polyurethanes containing nanosilicas with different silanol content, the higher the final adhesive strength. |
publishDate |
2006 |
dc.date.none.fl_str_mv |
2006-08-15 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/16946 Vega Baudrit, José; Navarro Bañón, Virtudes; Vazquez, Patricia Graciela; Martín Martínez, José Miguel; Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives; Elsevier; International Journal of Adhesion and Adhesives; 26; 5; 15-8-2006; 378-387 0143-7496 |
url |
http://hdl.handle.net/11336/16946 |
identifier_str_mv |
Vega Baudrit, José; Navarro Bañón, Virtudes; Vazquez, Patricia Graciela; Martín Martínez, José Miguel; Addition of nanosilicas with different silanol content to thermoplastic polyurethane adhesives; Elsevier; International Journal of Adhesion and Adhesives; 26; 5; 15-8-2006; 378-387 0143-7496 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0143749605000904 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ijadhadh.2005.06.004 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1844614045595860992 |
score |
13.070432 |