New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules
- Autores
- Calderón, Matías F.; Zelaya, Maria Eugenia; Benitez, Guillermo Alfredo; Schilardi, Patricia Laura; Hernández Creus, Alberto; González Orive, Alejandro; Salvarezza, Roberto Carlos; Ibañez, Francisco Javier
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Here we explore the synthesis of alkanethiolcoated Ni NPs following the one-phase reaction method by Brust et al.1 The reduction of NiCl2 with NaBH4 in the presence of dodecanethiol (C12SH) yields a complex product that is difficult to identify as illustrated in the figure of merit. We synthesized Ni(II) dodecanethiolate (C12S) (without the addition of NaBH4) for comparison and performed an exhaustive characterization with TEM, HR-TEM, AFM, MFM, XPS, XRD, UV−vis, magnetism, and FT-IR. It is found that the organic coating is not quite a well-organized self-assembled monolayer (SAM) surrounding the Ni cluster as previously reported.2,3 XPS and XRD data show slight differences between both syntheses; however, Ni(II) thiolate appears to be more stable than reduced Ni when exposed to ambient air, indicating the propensity of metallic Ni to oxidize. It has been shown that irradiating with TEM electrons over various metal thiolates leads to nanoparticle formation.4 We irradiated over Ni(II) thiolate and observed no evidence of NP formation whereas irradiating a reduced Ni sample exhibited an ∼3.0 nm nanoparticle diameter. Magnetism studies showed a difference between both samples, indicating ferromagnetic character for the reduced Ni sample. According to our results, the product of the synthesis is comprised of ultrasmall metallic clusters embedded in some form of Ni(II) C12S. In this work, we open a discussion of the chemical nature of the core and the shell in the synthesis of Ni NPs protected with organomercaptan molecules.
Fil: Calderón, Matías F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina
Fil: Zelaya, Maria Eugenia. Comision Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Fisica (cab); Argentina
Fil: Benitez, Guillermo Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina
Fil: Schilardi, Patricia Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina
Fil: Hernández Creus, Alberto. Universidad de La Laguna; España
Fil: González Orive, Alejandro. Universidad de La Laguna; España
Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina
Fil: Ibañez, Francisco Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina - Materia
-
Ni Nanoparticles
Xps
Tem
Afm - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/1274
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oai:ri.conicet.gov.ar:11336/1274 |
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New findings for the composition and structure of Ni nanoparticles protected with organomercaptan moleculesCalderón, Matías F.Zelaya, Maria EugeniaBenitez, Guillermo AlfredoSchilardi, Patricia LauraHernández Creus, AlbertoGonzález Orive, AlejandroSalvarezza, Roberto CarlosIbañez, Francisco JavierNi NanoparticlesXpsTemAfmhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Here we explore the synthesis of alkanethiolcoated Ni NPs following the one-phase reaction method by Brust et al.1 The reduction of NiCl2 with NaBH4 in the presence of dodecanethiol (C12SH) yields a complex product that is difficult to identify as illustrated in the figure of merit. We synthesized Ni(II) dodecanethiolate (C12S) (without the addition of NaBH4) for comparison and performed an exhaustive characterization with TEM, HR-TEM, AFM, MFM, XPS, XRD, UV−vis, magnetism, and FT-IR. It is found that the organic coating is not quite a well-organized self-assembled monolayer (SAM) surrounding the Ni cluster as previously reported.2,3 XPS and XRD data show slight differences between both syntheses; however, Ni(II) thiolate appears to be more stable than reduced Ni when exposed to ambient air, indicating the propensity of metallic Ni to oxidize. It has been shown that irradiating with TEM electrons over various metal thiolates leads to nanoparticle formation.4 We irradiated over Ni(II) thiolate and observed no evidence of NP formation whereas irradiating a reduced Ni sample exhibited an ∼3.0 nm nanoparticle diameter. Magnetism studies showed a difference between both samples, indicating ferromagnetic character for the reduced Ni sample. According to our results, the product of the synthesis is comprised of ultrasmall metallic clusters embedded in some form of Ni(II) C12S. In this work, we open a discussion of the chemical nature of the core and the shell in the synthesis of Ni NPs protected with organomercaptan molecules.Fil: Calderón, Matías F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; ArgentinaFil: Zelaya, Maria Eugenia. Comision Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Fisica (cab); ArgentinaFil: Benitez, Guillermo Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; ArgentinaFil: Schilardi, Patricia Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; ArgentinaFil: Hernández Creus, Alberto. Universidad de La Laguna; EspañaFil: González Orive, Alejandro. Universidad de La Laguna; EspañaFil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; ArgentinaFil: Ibañez, Francisco Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; ArgentinaAmerican Chemical Society2013-03-21info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/1274Calderón, Matías F.; Zelaya, Maria Eugenia; Benitez, Guillermo Alfredo; Schilardi, Patricia Laura; Hernández Creus, Alberto; et al.; New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules; American Chemical Society; Langmuir; 29; 15; 21-3-2013; 4670-46780743-7463enginfo:eu-repo/semantics/altIdentifier/doi/10.1021/la304993cinfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/la304993cinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:39:19Zoai:ri.conicet.gov.ar:11336/1274instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:39:20.203CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
title |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
spellingShingle |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules Calderón, Matías F. Ni Nanoparticles Xps Tem Afm |
title_short |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
title_full |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
title_fullStr |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
title_full_unstemmed |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
title_sort |
New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules |
dc.creator.none.fl_str_mv |
Calderón, Matías F. Zelaya, Maria Eugenia Benitez, Guillermo Alfredo Schilardi, Patricia Laura Hernández Creus, Alberto González Orive, Alejandro Salvarezza, Roberto Carlos Ibañez, Francisco Javier |
author |
Calderón, Matías F. |
author_facet |
Calderón, Matías F. Zelaya, Maria Eugenia Benitez, Guillermo Alfredo Schilardi, Patricia Laura Hernández Creus, Alberto González Orive, Alejandro Salvarezza, Roberto Carlos Ibañez, Francisco Javier |
author_role |
author |
author2 |
Zelaya, Maria Eugenia Benitez, Guillermo Alfredo Schilardi, Patricia Laura Hernández Creus, Alberto González Orive, Alejandro Salvarezza, Roberto Carlos Ibañez, Francisco Javier |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Ni Nanoparticles Xps Tem Afm |
topic |
Ni Nanoparticles Xps Tem Afm |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Here we explore the synthesis of alkanethiolcoated Ni NPs following the one-phase reaction method by Brust et al.1 The reduction of NiCl2 with NaBH4 in the presence of dodecanethiol (C12SH) yields a complex product that is difficult to identify as illustrated in the figure of merit. We synthesized Ni(II) dodecanethiolate (C12S) (without the addition of NaBH4) for comparison and performed an exhaustive characterization with TEM, HR-TEM, AFM, MFM, XPS, XRD, UV−vis, magnetism, and FT-IR. It is found that the organic coating is not quite a well-organized self-assembled monolayer (SAM) surrounding the Ni cluster as previously reported.2,3 XPS and XRD data show slight differences between both syntheses; however, Ni(II) thiolate appears to be more stable than reduced Ni when exposed to ambient air, indicating the propensity of metallic Ni to oxidize. It has been shown that irradiating with TEM electrons over various metal thiolates leads to nanoparticle formation.4 We irradiated over Ni(II) thiolate and observed no evidence of NP formation whereas irradiating a reduced Ni sample exhibited an ∼3.0 nm nanoparticle diameter. Magnetism studies showed a difference between both samples, indicating ferromagnetic character for the reduced Ni sample. According to our results, the product of the synthesis is comprised of ultrasmall metallic clusters embedded in some form of Ni(II) C12S. In this work, we open a discussion of the chemical nature of the core and the shell in the synthesis of Ni NPs protected with organomercaptan molecules. Fil: Calderón, Matías F.. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina Fil: Zelaya, Maria Eugenia. Comision Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Fisica (cab); Argentina Fil: Benitez, Guillermo Alfredo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina Fil: Schilardi, Patricia Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina Fil: Hernández Creus, Alberto. Universidad de La Laguna; España Fil: González Orive, Alejandro. Universidad de La Laguna; España Fil: Salvarezza, Roberto Carlos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina Fil: Ibañez, Francisco Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico - CONICET- La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicaciones; Argentina |
description |
Here we explore the synthesis of alkanethiolcoated Ni NPs following the one-phase reaction method by Brust et al.1 The reduction of NiCl2 with NaBH4 in the presence of dodecanethiol (C12SH) yields a complex product that is difficult to identify as illustrated in the figure of merit. We synthesized Ni(II) dodecanethiolate (C12S) (without the addition of NaBH4) for comparison and performed an exhaustive characterization with TEM, HR-TEM, AFM, MFM, XPS, XRD, UV−vis, magnetism, and FT-IR. It is found that the organic coating is not quite a well-organized self-assembled monolayer (SAM) surrounding the Ni cluster as previously reported.2,3 XPS and XRD data show slight differences between both syntheses; however, Ni(II) thiolate appears to be more stable than reduced Ni when exposed to ambient air, indicating the propensity of metallic Ni to oxidize. It has been shown that irradiating with TEM electrons over various metal thiolates leads to nanoparticle formation.4 We irradiated over Ni(II) thiolate and observed no evidence of NP formation whereas irradiating a reduced Ni sample exhibited an ∼3.0 nm nanoparticle diameter. Magnetism studies showed a difference between both samples, indicating ferromagnetic character for the reduced Ni sample. According to our results, the product of the synthesis is comprised of ultrasmall metallic clusters embedded in some form of Ni(II) C12S. In this work, we open a discussion of the chemical nature of the core and the shell in the synthesis of Ni NPs protected with organomercaptan molecules. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-03-21 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/1274 Calderón, Matías F.; Zelaya, Maria Eugenia; Benitez, Guillermo Alfredo; Schilardi, Patricia Laura; Hernández Creus, Alberto; et al.; New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules; American Chemical Society; Langmuir; 29; 15; 21-3-2013; 4670-4678 0743-7463 |
url |
http://hdl.handle.net/11336/1274 |
identifier_str_mv |
Calderón, Matías F.; Zelaya, Maria Eugenia; Benitez, Guillermo Alfredo; Schilardi, Patricia Laura; Hernández Creus, Alberto; et al.; New findings for the composition and structure of Ni nanoparticles protected with organomercaptan molecules; American Chemical Society; Langmuir; 29; 15; 21-3-2013; 4670-4678 0743-7463 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1021/la304993c info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/la304993c |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
American Chemical Society |
publisher.none.fl_str_mv |
American Chemical Society |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613244415639552 |
score |
13.070432 |