Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media

Autores
Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto
Año de publicación
2021
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Advances in visible light-photocatalyzed preparative synthetic organic transformations in water or aqueous media are studied. Both the convenience of visible light photocatalytic strategies to achieve synthetic organic transformations and the employment of water or aqueous mixtures make this approach a very resourceful methodology. Mechanistic aspects for such photocatalyzed processes are discussed. The effects of water in the stereoselectivity of some reactions and considerations regarding the improved enantioselectivity in chiral catalytic photoredox reactions are manifested with the use of water. The use of water as a result of a protocol improvement or environmentally friendlier methodology as compared to the same reaction performed in organic solvents are also considered. All these combined effects of water as a reaction medium or its very presence in photocatalytic reactions have an ultimate goal which is to diminish the environmental impact of synthetic and photocatalytic processes. This perspective highlights the progress and state of the art organic transformations realized by photocatalytic techniques in water or aqueous systems as well as water as a reactant. In this regard, aromatic substitution reactions, radical additions to carbon-carbon double bonds, photooxidation reactions, decarboxylation processes, and miscellaneous reactions are presented.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Materia
DECARBOXYLATIVE REACTIONS
DIASTEREOSELECTIVE PHOTOCATALYSIS
ENANTIOSELECTIVE PHOTOCATALYSIS
PHOTOCATALYSIS IN WATER
PHOTOCATALYZED ARYLATIONS
PHOTOCATALYZED ATRA
PHOTOCATALYZED CYCLIZATIONS
PHOTOCATALYZED DEOXYGENATIONS
PHOTOCATALYZED PHOTOOXIDATIONS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/148309
Acceder
id CONICETDig_a74ee54877e4176a7de9d764a9203ba8
oai_identifier_str oai:ri.conicet.gov.ar:11336/148309
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous MediaBarata Vallejo, SebastianYerien, Damián EmilioPostigo, Jose AlbertoDECARBOXYLATIVE REACTIONSDIASTEREOSELECTIVE PHOTOCATALYSISENANTIOSELECTIVE PHOTOCATALYSISPHOTOCATALYSIS IN WATERPHOTOCATALYZED ARYLATIONSPHOTOCATALYZED ATRAPHOTOCATALYZED CYCLIZATIONSPHOTOCATALYZED DEOXYGENATIONSPHOTOCATALYZED PHOTOOXIDATIONShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Advances in visible light-photocatalyzed preparative synthetic organic transformations in water or aqueous media are studied. Both the convenience of visible light photocatalytic strategies to achieve synthetic organic transformations and the employment of water or aqueous mixtures make this approach a very resourceful methodology. Mechanistic aspects for such photocatalyzed processes are discussed. The effects of water in the stereoselectivity of some reactions and considerations regarding the improved enantioselectivity in chiral catalytic photoredox reactions are manifested with the use of water. The use of water as a result of a protocol improvement or environmentally friendlier methodology as compared to the same reaction performed in organic solvents are also considered. All these combined effects of water as a reaction medium or its very presence in photocatalytic reactions have an ultimate goal which is to diminish the environmental impact of synthetic and photocatalytic processes. This perspective highlights the progress and state of the art organic transformations realized by photocatalytic techniques in water or aqueous systems as well as water as a reactant. In this regard, aromatic substitution reactions, radical additions to carbon-carbon double bonds, photooxidation reactions, decarboxylation processes, and miscellaneous reactions are presented.Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaAmerican Chemical Society2021-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/148309Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media; American Chemical Society; ACS Sustainable Chemistry and Engineering; 9; 30; 7-2021; 10016-100472168-0485CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.1c03384info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acssuschemeng.1c03384info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:45:54Zoai:ri.conicet.gov.ar:11336/148309instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:45:54.916CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
title Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
spellingShingle Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
Barata Vallejo, Sebastian
DECARBOXYLATIVE REACTIONS
DIASTEREOSELECTIVE PHOTOCATALYSIS
ENANTIOSELECTIVE PHOTOCATALYSIS
PHOTOCATALYSIS IN WATER
PHOTOCATALYZED ARYLATIONS
PHOTOCATALYZED ATRA
PHOTOCATALYZED CYCLIZATIONS
PHOTOCATALYZED DEOXYGENATIONS
PHOTOCATALYZED PHOTOOXIDATIONS
title_short Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
title_full Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
title_fullStr Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
title_full_unstemmed Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
title_sort Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media
dc.creator.none.fl_str_mv Barata Vallejo, Sebastian
Yerien, Damián Emilio
Postigo, Jose Alberto
author Barata Vallejo, Sebastian
author_facet Barata Vallejo, Sebastian
Yerien, Damián Emilio
Postigo, Jose Alberto
author_role author
author2 Yerien, Damián Emilio
Postigo, Jose Alberto
author2_role author
author
dc.subject.none.fl_str_mv DECARBOXYLATIVE REACTIONS
DIASTEREOSELECTIVE PHOTOCATALYSIS
ENANTIOSELECTIVE PHOTOCATALYSIS
PHOTOCATALYSIS IN WATER
PHOTOCATALYZED ARYLATIONS
PHOTOCATALYZED ATRA
PHOTOCATALYZED CYCLIZATIONS
PHOTOCATALYZED DEOXYGENATIONS
PHOTOCATALYZED PHOTOOXIDATIONS
topic DECARBOXYLATIVE REACTIONS
DIASTEREOSELECTIVE PHOTOCATALYSIS
ENANTIOSELECTIVE PHOTOCATALYSIS
PHOTOCATALYSIS IN WATER
PHOTOCATALYZED ARYLATIONS
PHOTOCATALYZED ATRA
PHOTOCATALYZED CYCLIZATIONS
PHOTOCATALYZED DEOXYGENATIONS
PHOTOCATALYZED PHOTOOXIDATIONS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Advances in visible light-photocatalyzed preparative synthetic organic transformations in water or aqueous media are studied. Both the convenience of visible light photocatalytic strategies to achieve synthetic organic transformations and the employment of water or aqueous mixtures make this approach a very resourceful methodology. Mechanistic aspects for such photocatalyzed processes are discussed. The effects of water in the stereoselectivity of some reactions and considerations regarding the improved enantioselectivity in chiral catalytic photoredox reactions are manifested with the use of water. The use of water as a result of a protocol improvement or environmentally friendlier methodology as compared to the same reaction performed in organic solvents are also considered. All these combined effects of water as a reaction medium or its very presence in photocatalytic reactions have an ultimate goal which is to diminish the environmental impact of synthetic and photocatalytic processes. This perspective highlights the progress and state of the art organic transformations realized by photocatalytic techniques in water or aqueous systems as well as water as a reactant. In this regard, aromatic substitution reactions, radical additions to carbon-carbon double bonds, photooxidation reactions, decarboxylation processes, and miscellaneous reactions are presented.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Yerien, Damián Emilio. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
description Advances in visible light-photocatalyzed preparative synthetic organic transformations in water or aqueous media are studied. Both the convenience of visible light photocatalytic strategies to achieve synthetic organic transformations and the employment of water or aqueous mixtures make this approach a very resourceful methodology. Mechanistic aspects for such photocatalyzed processes are discussed. The effects of water in the stereoselectivity of some reactions and considerations regarding the improved enantioselectivity in chiral catalytic photoredox reactions are manifested with the use of water. The use of water as a result of a protocol improvement or environmentally friendlier methodology as compared to the same reaction performed in organic solvents are also considered. All these combined effects of water as a reaction medium or its very presence in photocatalytic reactions have an ultimate goal which is to diminish the environmental impact of synthetic and photocatalytic processes. This perspective highlights the progress and state of the art organic transformations realized by photocatalytic techniques in water or aqueous systems as well as water as a reactant. In this regard, aromatic substitution reactions, radical additions to carbon-carbon double bonds, photooxidation reactions, decarboxylation processes, and miscellaneous reactions are presented.
publishDate 2021
dc.date.none.fl_str_mv 2021-07
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/148309
Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media; American Chemical Society; ACS Sustainable Chemistry and Engineering; 9; 30; 7-2021; 10016-10047
2168-0485
CONICET Digital
CONICET
url http://hdl.handle.net/11336/148309
identifier_str_mv Barata Vallejo, Sebastian; Yerien, Damián Emilio; Postigo, Jose Alberto; Advances in Photocatalytic Organic Synthetic Transformations in Water and Aqueous Media; American Chemical Society; ACS Sustainable Chemistry and Engineering; 9; 30; 7-2021; 10016-10047
2168-0485
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acssuschemeng.1c03384
info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acssuschemeng.1c03384
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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