New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds
- Autores
- Barata Vallejo, Sebastian; Postigo, Jose Alberto
- Año de publicación
- 2020
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Visible-light-photocatalyzed methods employed insynthetic transformations present attractive properties such asenvironmentally friendly, safety, availability and excellent functionalgroup tolerance. In this venue, research on the visible-lightphotocatalytic incorporation of the trifluoromethyl CF3 moiety intoorganic substrates, in particular, has contributed to a clear evolutionof the very field of photocatalysis. Outer-sphere electron transfersbetween photocatalysts and trifluoromethyl sources supply CF3radicals efficiently in clean and controlled ways, capable of effectingnumerous synthetic transformations and functionalization on organicsubstrates and compounds with pharmacological activity instraightforward manners. Although this particular area is constantlyevolving and reviewed, the last five years have experienced anoutburst of seminal and significant photocatalytic trifluoromethylationexamples that are leading the way and opening new syntheticavenues. Recent review articles on Ru- and Ir- based photocatalytictrifluoromethylation reactions have borne witness of this evolution.Although this account will show the new Ru- and Ir-basedphotocatalytic trifluoromethylations, Sections 2 and 3 will alsoillustrate other photocatalytic systems, such as organic dyes, organicsemiconductors and newly-developed all-organic photocatalysts. All the known and reviewed strategies for photocatalytictrifluoromethylation reactions of olefins and (hetero)aromaticcompounds will not be discussed but will be summarized in twoFigures (Figures 4 and 5), and new examples (2015-present) will bepresented and discussed.
Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina
Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina - Materia
-
TRIFLUOROMETHYLATION
PHOTOCATALYSIS
ALL-ORGANIC SEMICONDUCTORS - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/109053
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New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic CompoundsBarata Vallejo, SebastianPostigo, Jose AlbertoTRIFLUOROMETHYLATIONPHOTOCATALYSISALL-ORGANIC SEMICONDUCTORShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Visible-light-photocatalyzed methods employed insynthetic transformations present attractive properties such asenvironmentally friendly, safety, availability and excellent functionalgroup tolerance. In this venue, research on the visible-lightphotocatalytic incorporation of the trifluoromethyl CF3 moiety intoorganic substrates, in particular, has contributed to a clear evolutionof the very field of photocatalysis. Outer-sphere electron transfersbetween photocatalysts and trifluoromethyl sources supply CF3radicals efficiently in clean and controlled ways, capable of effectingnumerous synthetic transformations and functionalization on organicsubstrates and compounds with pharmacological activity instraightforward manners. Although this particular area is constantlyevolving and reviewed, the last five years have experienced anoutburst of seminal and significant photocatalytic trifluoromethylationexamples that are leading the way and opening new syntheticavenues. Recent review articles on Ru- and Ir- based photocatalytictrifluoromethylation reactions have borne witness of this evolution.Although this account will show the new Ru- and Ir-basedphotocatalytic trifluoromethylations, Sections 2 and 3 will alsoillustrate other photocatalytic systems, such as organic dyes, organicsemiconductors and newly-developed all-organic photocatalysts. All the known and reviewed strategies for photocatalytictrifluoromethylation reactions of olefins and (hetero)aromaticcompounds will not be discussed but will be summarized in twoFigures (Figures 4 and 5), and new examples (2015-present) will bepresented and discussed.Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; ArgentinaFil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; ArgentinaWiley VCH Verlag2020-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/109053Barata Vallejo, Sebastian; Postigo, Jose Alberto; New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds; Wiley VCH Verlag; Chemistry- A European Journal; 26; 24; 4-2020; 1-100947-6539CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202000856info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.202000856info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:46:25Zoai:ri.conicet.gov.ar:11336/109053instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:46:26.155CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
title |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
spellingShingle |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds Barata Vallejo, Sebastian TRIFLUOROMETHYLATION PHOTOCATALYSIS ALL-ORGANIC SEMICONDUCTORS |
title_short |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
title_full |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
title_fullStr |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
title_full_unstemmed |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
title_sort |
New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds |
dc.creator.none.fl_str_mv |
Barata Vallejo, Sebastian Postigo, Jose Alberto |
author |
Barata Vallejo, Sebastian |
author_facet |
Barata Vallejo, Sebastian Postigo, Jose Alberto |
author_role |
author |
author2 |
Postigo, Jose Alberto |
author2_role |
author |
dc.subject.none.fl_str_mv |
TRIFLUOROMETHYLATION PHOTOCATALYSIS ALL-ORGANIC SEMICONDUCTORS |
topic |
TRIFLUOROMETHYLATION PHOTOCATALYSIS ALL-ORGANIC SEMICONDUCTORS |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Visible-light-photocatalyzed methods employed insynthetic transformations present attractive properties such asenvironmentally friendly, safety, availability and excellent functionalgroup tolerance. In this venue, research on the visible-lightphotocatalytic incorporation of the trifluoromethyl CF3 moiety intoorganic substrates, in particular, has contributed to a clear evolutionof the very field of photocatalysis. Outer-sphere electron transfersbetween photocatalysts and trifluoromethyl sources supply CF3radicals efficiently in clean and controlled ways, capable of effectingnumerous synthetic transformations and functionalization on organicsubstrates and compounds with pharmacological activity instraightforward manners. Although this particular area is constantlyevolving and reviewed, the last five years have experienced anoutburst of seminal and significant photocatalytic trifluoromethylationexamples that are leading the way and opening new syntheticavenues. Recent review articles on Ru- and Ir- based photocatalytictrifluoromethylation reactions have borne witness of this evolution.Although this account will show the new Ru- and Ir-basedphotocatalytic trifluoromethylations, Sections 2 and 3 will alsoillustrate other photocatalytic systems, such as organic dyes, organicsemiconductors and newly-developed all-organic photocatalysts. All the known and reviewed strategies for photocatalytictrifluoromethylation reactions of olefins and (hetero)aromaticcompounds will not be discussed but will be summarized in twoFigures (Figures 4 and 5), and new examples (2015-present) will bepresented and discussed. Fil: Barata Vallejo, Sebastian. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina Fil: Postigo, Jose Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina |
description |
Visible-light-photocatalyzed methods employed insynthetic transformations present attractive properties such asenvironmentally friendly, safety, availability and excellent functionalgroup tolerance. In this venue, research on the visible-lightphotocatalytic incorporation of the trifluoromethyl CF3 moiety intoorganic substrates, in particular, has contributed to a clear evolutionof the very field of photocatalysis. Outer-sphere electron transfersbetween photocatalysts and trifluoromethyl sources supply CF3radicals efficiently in clean and controlled ways, capable of effectingnumerous synthetic transformations and functionalization on organicsubstrates and compounds with pharmacological activity instraightforward manners. Although this particular area is constantlyevolving and reviewed, the last five years have experienced anoutburst of seminal and significant photocatalytic trifluoromethylationexamples that are leading the way and opening new syntheticavenues. Recent review articles on Ru- and Ir- based photocatalytictrifluoromethylation reactions have borne witness of this evolution.Although this account will show the new Ru- and Ir-basedphotocatalytic trifluoromethylations, Sections 2 and 3 will alsoillustrate other photocatalytic systems, such as organic dyes, organicsemiconductors and newly-developed all-organic photocatalysts. All the known and reviewed strategies for photocatalytictrifluoromethylation reactions of olefins and (hetero)aromaticcompounds will not be discussed but will be summarized in twoFigures (Figures 4 and 5), and new examples (2015-present) will bepresented and discussed. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/109053 Barata Vallejo, Sebastian; Postigo, Jose Alberto; New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds; Wiley VCH Verlag; Chemistry- A European Journal; 26; 24; 4-2020; 1-10 0947-6539 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/109053 |
identifier_str_mv |
Barata Vallejo, Sebastian; Postigo, Jose Alberto; New Visible Light-triggered Photocatalytic Trifluoromethylation Reactions of Carbon‐carbon Multiple Bonds and (Hetero)aromatic Compounds; Wiley VCH Verlag; Chemistry- A European Journal; 26; 24; 4-2020; 1-10 0947-6539 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/chem.202000856 info:eu-repo/semantics/altIdentifier/doi/10.1002/chem.202000856 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Wiley VCH Verlag |
publisher.none.fl_str_mv |
Wiley VCH Verlag |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613450147299328 |
score |
13.070432 |