Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors
- Autores
- Rossi, Ezequiel; Salahshoor, Zahra; Ho, Khanh Van; Lin, Chung Ho; Errea, María Inés; Fidalgo, Maria M.
- Año de publicación
- 2021
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A photonic sensor based on inversed opal molecular imprinted polymer (MIP) film to detect the presence of chlorantraniliprole (CHL) residue in tomatoes was developed. Acrylic acid was polymerized in the presence of CHL inside the structure of a colloidal crystal, followed by etching of the colloids and CHL elution. Colloidal crystals and MIP films were characterized by scanning electron microscopy and FT-IR, confirming the inner structure and chemical structure of the material. MIP films supported on polymethylmethacrylate (PMMA) slides were incubated in aqueous solutions of the pesticide and in blended tomato samples. The MIP sensor displayed shifts of the peak wavelength of the reflection spectra in the visible range when incubated in CHL concentrations between 0.5 and 10 μg L−1, while almost no peak displacement was observed for non-imprinted (NIP) films. Whole tomatoes were blended into a liquid and spiked with CHL; the sensor was able to detect CHL residues down to 0.5 μg kg−1, significantly below the tolerance level established by the US Environmental Protection Agency of 1.4 mg kg−1. Stable values were reached after about 30-min incubation in test samples. Control samples (unspiked processed tomatoes) produced peak shifts both in MIP and NIP films; however, this matrix effect did not affect the detection of CHL in the spiked samples. These promising results support the application of photonic MIP sensors as an economical and field-deployable screening tool for the detection of CHL in crops.
Fil: Rossi, Ezequiel. Instituto Tecnológico de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina
Fil: Salahshoor, Zahra. University of Missouri; Estados Unidos
Fil: Ho, Khanh Van. University of Missouri; Estados Unidos
Fil: Lin, Chung Ho. University of Missouri; Estados Unidos
Fil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; Argentina
Fil: Fidalgo, Maria M.. University of Missouri; Estados Unidos - Materia
-
CHLORANTRANILIPROLE
COLLOIDAL CRYSTAL
MOLECULARLY IMPRINTED POLYMER
PESTICIDE DETECTION
PHOTONIC SENSOR - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/177185
Ver los metadatos del registro completo
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oai:ri.conicet.gov.ar:11336/177185 |
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network_name_str |
CONICET Digital (CONICET) |
spelling |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensorsRossi, EzequielSalahshoor, ZahraHo, Khanh VanLin, Chung HoErrea, María InésFidalgo, Maria M.CHLORANTRANILIPROLECOLLOIDAL CRYSTALMOLECULARLY IMPRINTED POLYMERPESTICIDE DETECTIONPHOTONIC SENSORhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2A photonic sensor based on inversed opal molecular imprinted polymer (MIP) film to detect the presence of chlorantraniliprole (CHL) residue in tomatoes was developed. Acrylic acid was polymerized in the presence of CHL inside the structure of a colloidal crystal, followed by etching of the colloids and CHL elution. Colloidal crystals and MIP films were characterized by scanning electron microscopy and FT-IR, confirming the inner structure and chemical structure of the material. MIP films supported on polymethylmethacrylate (PMMA) slides were incubated in aqueous solutions of the pesticide and in blended tomato samples. The MIP sensor displayed shifts of the peak wavelength of the reflection spectra in the visible range when incubated in CHL concentrations between 0.5 and 10 μg L−1, while almost no peak displacement was observed for non-imprinted (NIP) films. Whole tomatoes were blended into a liquid and spiked with CHL; the sensor was able to detect CHL residues down to 0.5 μg kg−1, significantly below the tolerance level established by the US Environmental Protection Agency of 1.4 mg kg−1. Stable values were reached after about 30-min incubation in test samples. Control samples (unspiked processed tomatoes) produced peak shifts both in MIP and NIP films; however, this matrix effect did not affect the detection of CHL in the spiked samples. These promising results support the application of photonic MIP sensors as an economical and field-deployable screening tool for the detection of CHL in crops.Fil: Rossi, Ezequiel. Instituto Tecnológico de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; ArgentinaFil: Salahshoor, Zahra. University of Missouri; Estados UnidosFil: Ho, Khanh Van. University of Missouri; Estados UnidosFil: Lin, Chung Ho. University of Missouri; Estados UnidosFil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; ArgentinaFil: Fidalgo, Maria M.. University of Missouri; Estados UnidosSpringer Wien2021-03info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/vnd.openxmlformats-officedocument.wordprocessingml.documentapplication/pdfhttp://hdl.handle.net/11336/177185Rossi, Ezequiel; Salahshoor, Zahra; Ho, Khanh Van; Lin, Chung Ho; Errea, María Inés; et al.; Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors; Springer Wien; Mikrochimica Acta; 188; 3; 3-2021; 1-70026-3672CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s00604-021-04731-2info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:30Zoai:ri.conicet.gov.ar:11336/177185instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:31.027CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
title |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
spellingShingle |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors Rossi, Ezequiel CHLORANTRANILIPROLE COLLOIDAL CRYSTAL MOLECULARLY IMPRINTED POLYMER PESTICIDE DETECTION PHOTONIC SENSOR |
title_short |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
title_full |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
title_fullStr |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
title_full_unstemmed |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
title_sort |
Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors |
dc.creator.none.fl_str_mv |
Rossi, Ezequiel Salahshoor, Zahra Ho, Khanh Van Lin, Chung Ho Errea, María Inés Fidalgo, Maria M. |
author |
Rossi, Ezequiel |
author_facet |
Rossi, Ezequiel Salahshoor, Zahra Ho, Khanh Van Lin, Chung Ho Errea, María Inés Fidalgo, Maria M. |
author_role |
author |
author2 |
Salahshoor, Zahra Ho, Khanh Van Lin, Chung Ho Errea, María Inés Fidalgo, Maria M. |
author2_role |
author author author author author |
dc.subject.none.fl_str_mv |
CHLORANTRANILIPROLE COLLOIDAL CRYSTAL MOLECULARLY IMPRINTED POLYMER PESTICIDE DETECTION PHOTONIC SENSOR |
topic |
CHLORANTRANILIPROLE COLLOIDAL CRYSTAL MOLECULARLY IMPRINTED POLYMER PESTICIDE DETECTION PHOTONIC SENSOR |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
A photonic sensor based on inversed opal molecular imprinted polymer (MIP) film to detect the presence of chlorantraniliprole (CHL) residue in tomatoes was developed. Acrylic acid was polymerized in the presence of CHL inside the structure of a colloidal crystal, followed by etching of the colloids and CHL elution. Colloidal crystals and MIP films were characterized by scanning electron microscopy and FT-IR, confirming the inner structure and chemical structure of the material. MIP films supported on polymethylmethacrylate (PMMA) slides were incubated in aqueous solutions of the pesticide and in blended tomato samples. The MIP sensor displayed shifts of the peak wavelength of the reflection spectra in the visible range when incubated in CHL concentrations between 0.5 and 10 μg L−1, while almost no peak displacement was observed for non-imprinted (NIP) films. Whole tomatoes were blended into a liquid and spiked with CHL; the sensor was able to detect CHL residues down to 0.5 μg kg−1, significantly below the tolerance level established by the US Environmental Protection Agency of 1.4 mg kg−1. Stable values were reached after about 30-min incubation in test samples. Control samples (unspiked processed tomatoes) produced peak shifts both in MIP and NIP films; however, this matrix effect did not affect the detection of CHL in the spiked samples. These promising results support the application of photonic MIP sensors as an economical and field-deployable screening tool for the detection of CHL in crops. Fil: Rossi, Ezequiel. Instituto Tecnológico de Buenos Aires; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay. Instituto de Tecnología en Polímeros y Nanotecnología. Universidad de Buenos Aires. Facultad de Ingeniería. Instituto de Tecnología en Polímeros y Nanotecnología; Argentina Fil: Salahshoor, Zahra. University of Missouri; Estados Unidos Fil: Ho, Khanh Van. University of Missouri; Estados Unidos Fil: Lin, Chung Ho. University of Missouri; Estados Unidos Fil: Errea, María Inés. Instituto Tecnológico de Buenos Aires; Argentina Fil: Fidalgo, Maria M.. University of Missouri; Estados Unidos |
description |
A photonic sensor based on inversed opal molecular imprinted polymer (MIP) film to detect the presence of chlorantraniliprole (CHL) residue in tomatoes was developed. Acrylic acid was polymerized in the presence of CHL inside the structure of a colloidal crystal, followed by etching of the colloids and CHL elution. Colloidal crystals and MIP films were characterized by scanning electron microscopy and FT-IR, confirming the inner structure and chemical structure of the material. MIP films supported on polymethylmethacrylate (PMMA) slides were incubated in aqueous solutions of the pesticide and in blended tomato samples. The MIP sensor displayed shifts of the peak wavelength of the reflection spectra in the visible range when incubated in CHL concentrations between 0.5 and 10 μg L−1, while almost no peak displacement was observed for non-imprinted (NIP) films. Whole tomatoes were blended into a liquid and spiked with CHL; the sensor was able to detect CHL residues down to 0.5 μg kg−1, significantly below the tolerance level established by the US Environmental Protection Agency of 1.4 mg kg−1. Stable values were reached after about 30-min incubation in test samples. Control samples (unspiked processed tomatoes) produced peak shifts both in MIP and NIP films; however, this matrix effect did not affect the detection of CHL in the spiked samples. These promising results support the application of photonic MIP sensors as an economical and field-deployable screening tool for the detection of CHL in crops. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-03 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/177185 Rossi, Ezequiel; Salahshoor, Zahra; Ho, Khanh Van; Lin, Chung Ho; Errea, María Inés; et al.; Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors; Springer Wien; Mikrochimica Acta; 188; 3; 3-2021; 1-7 0026-3672 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/177185 |
identifier_str_mv |
Rossi, Ezequiel; Salahshoor, Zahra; Ho, Khanh Van; Lin, Chung Ho; Errea, María Inés; et al.; Detection of chlorantraniliprole residues in tomato using field-deployable MIP photonic sensors; Springer Wien; Mikrochimica Acta; 188; 3; 3-2021; 1-7 0026-3672 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1007/s00604-021-04731-2 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/vnd.openxmlformats-officedocument.wordprocessingml.document application/pdf |
dc.publisher.none.fl_str_mv |
Springer Wien |
publisher.none.fl_str_mv |
Springer Wien |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613697075412992 |
score |
13.070432 |