The crystal structure of cyanotrichite

Autores
Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason
Año de publicación
2015
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].
Fil: Mills, Stuart J.. Museum Victoria; Australia
Fil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; Australia
Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Price, Jason. Australian Synchrotron; Australia
Materia
CYANOTRICHITE
CAMEROLITE
CARBONATECYANOTRICHITE
SYNCHROTRON
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/44114
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/44114
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling The crystal structure of cyanotrichiteMills, Stuart J.Christy, Andrew. G.Colombo, FernandoPrice, JasonCYANOTRICHITECAMEROLITECARBONATECYANOTRICHITESYNCHROTRONhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].Fil: Mills, Stuart J.. Museum Victoria; AustraliaFil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; AustraliaFil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Price, Jason. Australian Synchrotron; AustraliaMineralogical Soc2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44114Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-3350026-461X1471-8022CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2015.079.2.10info:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/mineralogical-magazine/article/crystal-structure-of-cyanotrichite/1BDF108C6B33B288AF1A391AE3B78845info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:15:56Zoai:ri.conicet.gov.ar:11336/44114instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:15:57.271CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv The crystal structure of cyanotrichite
title The crystal structure of cyanotrichite
spellingShingle The crystal structure of cyanotrichite
Mills, Stuart J.
CYANOTRICHITE
CAMEROLITE
CARBONATECYANOTRICHITE
SYNCHROTRON
title_short The crystal structure of cyanotrichite
title_full The crystal structure of cyanotrichite
title_fullStr The crystal structure of cyanotrichite
title_full_unstemmed The crystal structure of cyanotrichite
title_sort The crystal structure of cyanotrichite
dc.creator.none.fl_str_mv Mills, Stuart J.
Christy, Andrew. G.
Colombo, Fernando
Price, Jason
author Mills, Stuart J.
author_facet Mills, Stuart J.
Christy, Andrew. G.
Colombo, Fernando
Price, Jason
author_role author
author2 Christy, Andrew. G.
Colombo, Fernando
Price, Jason
author2_role author
author
author
dc.subject.none.fl_str_mv CYANOTRICHITE
CAMEROLITE
CARBONATECYANOTRICHITE
SYNCHROTRON
topic CYANOTRICHITE
CAMEROLITE
CARBONATECYANOTRICHITE
SYNCHROTRON
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.5
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].
Fil: Mills, Stuart J.. Museum Victoria; Australia
Fil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; Australia
Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Price, Jason. Australian Synchrotron; Australia
description We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].
publishDate 2015
dc.date.none.fl_str_mv 2015-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/44114
Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-335
0026-461X
1471-8022
CONICET Digital
CONICET
url http://hdl.handle.net/11336/44114
identifier_str_mv Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-335
0026-461X
1471-8022
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2015.079.2.10
info:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/mineralogical-magazine/article/crystal-structure-of-cyanotrichite/1BDF108C6B33B288AF1A391AE3B78845
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Mineralogical Soc
publisher.none.fl_str_mv Mineralogical Soc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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