The crystal structure of cyanotrichite
- Autores
- Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason
- Año de publicación
- 2015
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].
Fil: Mills, Stuart J.. Museum Victoria; Australia
Fil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; Australia
Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina
Fil: Price, Jason. Australian Synchrotron; Australia - Materia
-
CYANOTRICHITE
CAMEROLITE
CARBONATECYANOTRICHITE
SYNCHROTRON - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/44114
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oai:ri.conicet.gov.ar:11336/44114 |
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network_name_str |
CONICET Digital (CONICET) |
spelling |
The crystal structure of cyanotrichiteMills, Stuart J.Christy, Andrew. G.Colombo, FernandoPrice, JasonCYANOTRICHITECAMEROLITECARBONATECYANOTRICHITESYNCHROTRONhttps://purl.org/becyt/ford/1.5https://purl.org/becyt/ford/1We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-].Fil: Mills, Stuart J.. Museum Victoria; AustraliaFil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; AustraliaFil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; ArgentinaFil: Price, Jason. Australian Synchrotron; AustraliaMineralogical Soc2015-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/44114Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-3350026-461X1471-8022CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2015.079.2.10info:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/mineralogical-magazine/article/crystal-structure-of-cyanotrichite/1BDF108C6B33B288AF1A391AE3B78845info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:43:11Zoai:ri.conicet.gov.ar:11336/44114instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:43:11.621CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
The crystal structure of cyanotrichite |
title |
The crystal structure of cyanotrichite |
spellingShingle |
The crystal structure of cyanotrichite Mills, Stuart J. CYANOTRICHITE CAMEROLITE CARBONATECYANOTRICHITE SYNCHROTRON |
title_short |
The crystal structure of cyanotrichite |
title_full |
The crystal structure of cyanotrichite |
title_fullStr |
The crystal structure of cyanotrichite |
title_full_unstemmed |
The crystal structure of cyanotrichite |
title_sort |
The crystal structure of cyanotrichite |
dc.creator.none.fl_str_mv |
Mills, Stuart J. Christy, Andrew. G. Colombo, Fernando Price, Jason |
author |
Mills, Stuart J. |
author_facet |
Mills, Stuart J. Christy, Andrew. G. Colombo, Fernando Price, Jason |
author_role |
author |
author2 |
Christy, Andrew. G. Colombo, Fernando Price, Jason |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
CYANOTRICHITE CAMEROLITE CARBONATECYANOTRICHITE SYNCHROTRON |
topic |
CYANOTRICHITE CAMEROLITE CARBONATECYANOTRICHITE SYNCHROTRON |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.5 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-]. Fil: Mills, Stuart J.. Museum Victoria; Australia Fil: Christy, Andrew. G.. Centre For Advanced Microscopy And Department Of Applie; Australia Fil: Colombo, Fernando. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Centro de Investigaciones en Ciencias de la Tierra. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas Físicas y Naturales. Centro de Investigaciones en Ciencias de la Tierra; Argentina Fil: Price, Jason. Australian Synchrotron; Australia |
description |
We report the single-crystal average structure of cyanotrichite, Cu4Al2[SO4](OH)12(H2O)2, from the Maid of Sunshine mine, Arizona, USA. Cyanotrichite crystallizes in space group C2/m, with the unit-cell parameters a = 12.625(3), b = 2.8950(6), c = 10.153(2) Å and β = 92.17(3)o. All non-hydrogen atoms were located and refined to R 1 = 0.0394 for all 584 observed reflections [F o > 4σF o] and 0.0424 for all 622 unique reflections. The cyanotrichite structure consists of a principal building unit of a three-wide [Cu2Al(OH)6] ribbon of edge-sharing Cu and Al polyhedra || b, similar to that found for camerolaite. The ribbons lie in layers || (001) and between these layers, while SO4 tetrahedra and H2O molecules form rods running || b. A hydrogen-bonding scheme is also proposed. A sample of cyanotrichite from the Cap Garonne mine, Le Pradet, France, showed a 4b superstructure with the following unit cell: space group P2/m, a = 12.611(2) Å, b = 11.584(16) = 4 × 2.896(4) Å, c = 10.190(1) Å and β = 92.29(6)o. The supercell could not be refined in detail, but nevertheless imposes constraints on the local structure in that while the space-group symmetry prevents full order of SO4 and H2O in the 4b supercell, it requires that the sequence of species along any given rod is [-SO4-SO4-(H2O)2-(H2O)2-] rather than [-SO4-(H2O)2-SO4-(H2O)2-]. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/44114 Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-335 0026-461X 1471-8022 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/44114 |
identifier_str_mv |
Mills, Stuart J.; Christy, Andrew. G.; Colombo, Fernando; Price, Jason; The crystal structure of cyanotrichite; Mineralogical Soc; Mineralogical Magazine; 79; 2; 4-2015; 321-335 0026-461X 1471-8022 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1180/minmag.2015.079.2.10 info:eu-repo/semantics/altIdentifier/url/https://www.cambridge.org/core/journals/mineralogical-magazine/article/crystal-structure-of-cyanotrichite/1BDF108C6B33B288AF1A391AE3B78845 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Mineralogical Soc |
publisher.none.fl_str_mv |
Mineralogical Soc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614466680913920 |
score |
13.070432 |