Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode

Autores
Dager Caballero, Paola Katherine; Mogni, Liliana Verónica; Zampieri, Guillermo Enrique; Caneiro, Alberto
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Sr2MgMo0.9Ni0.1O6-d (SMMNi) double perovskite was synthesized by the combustion-solution method followed by annealing in air at 1100 ºC during 12 hours. Sr2MgMoO6-d (SMMO) compound was also tested for comparison. X-Ray Diffraction (XRD) patterns indicate that SMMO and SMMNi powders display triclinic symmetry. Termogravimetric studies show that Mo-substitution by Ni in SMMO decreases the oxygen content in air condition. Meanwhile, after calcination in diluted-H2 both compounds present oxygen non-stoichiometric change Dd » 0.06. EIS measurements on symmetrical SMMO/GDC/SMMO and SMMNi/GDC/SMMNi cells were performed in order to study the influence of time and environment conditions (H2-content) on the anode polarization resistance (Rpa).
Fil: Dager Caballero, Paola Katherine. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Zampieri, Guillermo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
Materia
Sr2mgmoo6
Sofc Anode
High Temperature Properties
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/58219
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anodeDager Caballero, Paola KatherineMogni, Liliana VerónicaZampieri, Guillermo EnriqueCaneiro, AlbertoSr2mgmoo6Sofc AnodeHigh Temperature Propertieshttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Sr2MgMo0.9Ni0.1O6-d (SMMNi) double perovskite was synthesized by the combustion-solution method followed by annealing in air at 1100 ºC during 12 hours. Sr2MgMoO6-d (SMMO) compound was also tested for comparison. X-Ray Diffraction (XRD) patterns indicate that SMMO and SMMNi powders display triclinic symmetry. Termogravimetric studies show that Mo-substitution by Ni in SMMO decreases the oxygen content in air condition. Meanwhile, after calcination in diluted-H2 both compounds present oxygen non-stoichiometric change Dd » 0.06. EIS measurements on symmetrical SMMO/GDC/SMMO and SMMNi/GDC/SMMNi cells were performed in order to study the influence of time and environment conditions (H2-content) on the anode polarization resistance (Rpa).Fil: Dager Caballero, Paola Katherine. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Zampieri, Guillermo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; ArgentinaFil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaElectrochemical Society2017-05info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/58219Dager Caballero, Paola Katherine; Mogni, Liliana Verónica; Zampieri, Guillermo Enrique; Caneiro, Alberto; Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode; Electrochemical Society; ECS Transactions; 78; 1; 5-2017; 1367-13741938-5862CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1149/07801.1367ecstinfo:eu-repo/semantics/altIdentifier/url/http://ecst.ecsdl.org/content/78/1/1367info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-11-05T09:44:03Zoai:ri.conicet.gov.ar:11336/58219instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-11-05 09:44:03.777CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
title Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
spellingShingle Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
Dager Caballero, Paola Katherine
Sr2mgmoo6
Sofc Anode
High Temperature Properties
title_short Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
title_full Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
title_fullStr Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
title_full_unstemmed Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
title_sort Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode
dc.creator.none.fl_str_mv Dager Caballero, Paola Katherine
Mogni, Liliana Verónica
Zampieri, Guillermo Enrique
Caneiro, Alberto
author Dager Caballero, Paola Katherine
author_facet Dager Caballero, Paola Katherine
Mogni, Liliana Verónica
Zampieri, Guillermo Enrique
Caneiro, Alberto
author_role author
author2 Mogni, Liliana Verónica
Zampieri, Guillermo Enrique
Caneiro, Alberto
author2_role author
author
author
dc.subject.none.fl_str_mv Sr2mgmoo6
Sofc Anode
High Temperature Properties
topic Sr2mgmoo6
Sofc Anode
High Temperature Properties
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Sr2MgMo0.9Ni0.1O6-d (SMMNi) double perovskite was synthesized by the combustion-solution method followed by annealing in air at 1100 ºC during 12 hours. Sr2MgMoO6-d (SMMO) compound was also tested for comparison. X-Ray Diffraction (XRD) patterns indicate that SMMO and SMMNi powders display triclinic symmetry. Termogravimetric studies show that Mo-substitution by Ni in SMMO decreases the oxygen content in air condition. Meanwhile, after calcination in diluted-H2 both compounds present oxygen non-stoichiometric change Dd » 0.06. EIS measurements on symmetrical SMMO/GDC/SMMO and SMMNi/GDC/SMMNi cells were performed in order to study the influence of time and environment conditions (H2-content) on the anode polarization resistance (Rpa).
Fil: Dager Caballero, Paola Katherine. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Mogni, Liliana Verónica. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Zampieri, Guillermo Enrique. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina
Fil: Caneiro, Alberto. Comisión Nacional de Energía Atómica. Centro Atómico Bariloche; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina
description Sr2MgMo0.9Ni0.1O6-d (SMMNi) double perovskite was synthesized by the combustion-solution method followed by annealing in air at 1100 ºC during 12 hours. Sr2MgMoO6-d (SMMO) compound was also tested for comparison. X-Ray Diffraction (XRD) patterns indicate that SMMO and SMMNi powders display triclinic symmetry. Termogravimetric studies show that Mo-substitution by Ni in SMMO decreases the oxygen content in air condition. Meanwhile, after calcination in diluted-H2 both compounds present oxygen non-stoichiometric change Dd » 0.06. EIS measurements on symmetrical SMMO/GDC/SMMO and SMMNi/GDC/SMMNi cells were performed in order to study the influence of time and environment conditions (H2-content) on the anode polarization resistance (Rpa).
publishDate 2017
dc.date.none.fl_str_mv 2017-05
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/58219
Dager Caballero, Paola Katherine; Mogni, Liliana Verónica; Zampieri, Guillermo Enrique; Caneiro, Alberto; Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode; Electrochemical Society; ECS Transactions; 78; 1; 5-2017; 1367-1374
1938-5862
CONICET Digital
CONICET
url http://hdl.handle.net/11336/58219
identifier_str_mv Dager Caballero, Paola Katherine; Mogni, Liliana Verónica; Zampieri, Guillermo Enrique; Caneiro, Alberto; Study of Sr2MgMo0.9Ni0.1O6-δ as SOFC anode; Electrochemical Society; ECS Transactions; 78; 1; 5-2017; 1367-1374
1938-5862
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1149/07801.1367ecst
info:eu-repo/semantics/altIdentifier/url/http://ecst.ecsdl.org/content/78/1/1367
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Electrochemical Society
publisher.none.fl_str_mv Electrochemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.087074

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