Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis

Autores
Insausti, Matías; Romano, Carlos; Pistonesi, Marcelo Fabian; Fernández Band, Beatriz Susana
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
An analytical method was developed to determine four quality parameters (Biodiesel percentage, Cetane Number, Heat of Combustion Gross and Color) in biodiesel/diesel blends through a simple synchronous fluo- rescence spectrum of the samples. For this purpose, chemometrics models based on fluorescence spectra and PetroSpect data obtained from mixtures of biodiesel/diesel were built. A variable selection by the successive projections algorithm (SPA) was used in order to obtain simple multiple linear regression (MLR) models based on a small subset of wave- lengths. The SPA-MLR results were compared with a partial least squares (PLS) full spectrum regression. The best values found for the root mean square error of prediction using external validation were 0.37% (w/w) for the biodiesel in diesel, 0.5 for cetane number, 0.013 MJ/kg for heat of combustion and 0.1 for color.
Fil: Insausti, Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Romano, Carlos. Petrobras Argentina S.a; Argentina
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Materia
Biodiesel /Diesel Blends
Synchronous Fluorescence
Gross Heat of Combustion
Cetane Number
Spa-Mlr
Pls
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5418
Acceder
id CONICETDig_a1ad922fea3407e2991982805d6164da
oai_identifier_str oai:ri.conicet.gov.ar:11336/5418
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysisInsausti, MatíasRomano, CarlosPistonesi, Marcelo FabianFernández Band, Beatriz SusanaBiodiesel /Diesel BlendsSynchronous FluorescenceGross Heat of CombustionCetane NumberSpa-MlrPlshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1An analytical method was developed to determine four quality parameters (Biodiesel percentage, Cetane Number, Heat of Combustion Gross and Color) in biodiesel/diesel blends through a simple synchronous fluo- rescence spectrum of the samples. For this purpose, chemometrics models based on fluorescence spectra and PetroSpect data obtained from mixtures of biodiesel/diesel were built. A variable selection by the successive projections algorithm (SPA) was used in order to obtain simple multiple linear regression (MLR) models based on a small subset of wave- lengths. The SPA-MLR results were compared with a partial least squares (PLS) full spectrum regression. The best values found for the root mean square error of prediction using external validation were 0.37% (w/w) for the biodiesel in diesel, 0.5 for cetane number, 0.013 MJ/kg for heat of combustion and 0.1 for color.Fil: Insausti, Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaFil: Romano, Carlos. Petrobras Argentina S.a; ArgentinaFil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaFil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaElsevier2013-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5418Insausti, Matías; Romano, Carlos; Pistonesi, Marcelo Fabian; Fernández Band, Beatriz Susana; Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis; Elsevier; Microchemical Journal; 108; 12-2013; 32-370026-265Xenginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12003098info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.12.007info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:57Zoai:ri.conicet.gov.ar:11336/5418instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:58.125CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
title Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
spellingShingle Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
Insausti, Matías
Biodiesel /Diesel Blends
Synchronous Fluorescence
Gross Heat of Combustion
Cetane Number
Spa-Mlr
Pls
title_short Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
title_full Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
title_fullStr Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
title_full_unstemmed Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
title_sort Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis
dc.creator.none.fl_str_mv Insausti, Matías
Romano, Carlos
Pistonesi, Marcelo Fabian
Fernández Band, Beatriz Susana
author Insausti, Matías
author_facet Insausti, Matías
Romano, Carlos
Pistonesi, Marcelo Fabian
Fernández Band, Beatriz Susana
author_role author
author2 Romano, Carlos
Pistonesi, Marcelo Fabian
Fernández Band, Beatriz Susana
author2_role author
author
author
dc.subject.none.fl_str_mv Biodiesel /Diesel Blends
Synchronous Fluorescence
Gross Heat of Combustion
Cetane Number
Spa-Mlr
Pls
topic Biodiesel /Diesel Blends
Synchronous Fluorescence
Gross Heat of Combustion
Cetane Number
Spa-Mlr
Pls
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv An analytical method was developed to determine four quality parameters (Biodiesel percentage, Cetane Number, Heat of Combustion Gross and Color) in biodiesel/diesel blends through a simple synchronous fluo- rescence spectrum of the samples. For this purpose, chemometrics models based on fluorescence spectra and PetroSpect data obtained from mixtures of biodiesel/diesel were built. A variable selection by the successive projections algorithm (SPA) was used in order to obtain simple multiple linear regression (MLR) models based on a small subset of wave- lengths. The SPA-MLR results were compared with a partial least squares (PLS) full spectrum regression. The best values found for the root mean square error of prediction using external validation were 0.37% (w/w) for the biodiesel in diesel, 0.5 for cetane number, 0.013 MJ/kg for heat of combustion and 0.1 for color.
Fil: Insausti, Matías. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Romano, Carlos. Petrobras Argentina S.a; Argentina
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
description An analytical method was developed to determine four quality parameters (Biodiesel percentage, Cetane Number, Heat of Combustion Gross and Color) in biodiesel/diesel blends through a simple synchronous fluo- rescence spectrum of the samples. For this purpose, chemometrics models based on fluorescence spectra and PetroSpect data obtained from mixtures of biodiesel/diesel were built. A variable selection by the successive projections algorithm (SPA) was used in order to obtain simple multiple linear regression (MLR) models based on a small subset of wave- lengths. The SPA-MLR results were compared with a partial least squares (PLS) full spectrum regression. The best values found for the root mean square error of prediction using external validation were 0.37% (w/w) for the biodiesel in diesel, 0.5 for cetane number, 0.013 MJ/kg for heat of combustion and 0.1 for color.
publishDate 2013
dc.date.none.fl_str_mv 2013-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5418
Insausti, Matías; Romano, Carlos; Pistonesi, Marcelo Fabian; Fernández Band, Beatriz Susana; Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis; Elsevier; Microchemical Journal; 108; 12-2013; 32-37
0026-265X
url http://hdl.handle.net/11336/5418
identifier_str_mv Insausti, Matías; Romano, Carlos; Pistonesi, Marcelo Fabian; Fernández Band, Beatriz Susana; Simultaneous determination of quality parameters in biodiesel/diesel blends using synchronous fluorescence and multivariate analysis; Elsevier; Microchemical Journal; 108; 12-2013; 32-37
0026-265X
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0026265X12003098
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2012.12.007
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842269191152861184
score 13.13397

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