Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythio...

Autores
Soulé, Ezequiel Rodolfo; Jaffrennou, B.; Méchin, F.; Pascault, J. P.; Borrajo Fernandez, Julio; Williams, Roberto Juan Jose
Año de publicación
2006
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Poly(methyl methacrylate) and random copolymers of methyl methacrylate (MMA) and N,N-dimethylacrylamide (DMA) containing 7.5, 15, or 20 wt % DMA were dissolved in a stoichiometric mixture of m-xylylene diisocyanate and 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol, precursors of a polythiourethane network. Phase separation, which took place during polymerizations at 60, 90, and 120 °C, exhibited a lower critical solution temperature behavior. The cloud-point conversions, which were determined by the iodometric titration of free thiol groups of samples chilled in ice at the cloud point, increased with the weight fraction of DMA in the random copolymer. This could be used to control the cloud-point conversion and determine the characteristic size of the dispersed domains. A thermodynamic analysis was performed with the Flory-Huggins equation, taking into account the polydispersities of both the thermoplastic and thermoset polymers and using an interaction parameter depending on the temperature and on the three binary interaction energies. A reasonable fitting of the experimental curves was obtained with negative values for the interaction energies of the MMA-thermoset and DMA-thermoset pairs and with a positive value for the MMA-DMA pair.
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Jaffrennou, B.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Méchin, F.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Pascault, J. P.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
Blends
Miscibility
Phase Separation
Thermodynamics
Thermosets
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/76149
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/76149
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane networkSoulé, Ezequiel RodolfoJaffrennou, B.Méchin, F.Pascault, J. P.Borrajo Fernandez, JulioWilliams, Roberto Juan JoseBlendsMiscibilityPhase SeparationThermodynamicsThermosetshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1https://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Poly(methyl methacrylate) and random copolymers of methyl methacrylate (MMA) and N,N-dimethylacrylamide (DMA) containing 7.5, 15, or 20 wt % DMA were dissolved in a stoichiometric mixture of m-xylylene diisocyanate and 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol, precursors of a polythiourethane network. Phase separation, which took place during polymerizations at 60, 90, and 120 °C, exhibited a lower critical solution temperature behavior. The cloud-point conversions, which were determined by the iodometric titration of free thiol groups of samples chilled in ice at the cloud point, increased with the weight fraction of DMA in the random copolymer. This could be used to control the cloud-point conversion and determine the characteristic size of the dispersed domains. A thermodynamic analysis was performed with the Flory-Huggins equation, taking into account the polydispersities of both the thermoplastic and thermoset polymers and using an interaction parameter depending on the temperature and on the three binary interaction energies. A reasonable fitting of the experimental curves was obtained with negative values for the interaction energies of the MMA-thermoset and DMA-thermoset pairs and with a positive value for the MMA-DMA pair.Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Jaffrennou, B.. Institut National des Sciences Appliqués de Lyon; FranciaFil: Méchin, F.. Institut National des Sciences Appliqués de Lyon; FranciaFil: Pascault, J. P.. Institut National des Sciences Appliqués de Lyon; FranciaFil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2006-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/76149Soulé, Ezequiel Rodolfo; Jaffrennou, B.; Méchin, F.; Pascault, J. P.; Borrajo Fernandez, Julio; et al.; Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 44; 19; 10-2006; 2821-28270887-6266CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/polb.20948info:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20948info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:53:19Zoai:ri.conicet.gov.ar:11336/76149instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:53:20.208CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
title Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
spellingShingle Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
Soulé, Ezequiel Rodolfo
Blends
Miscibility
Phase Separation
Thermodynamics
Thermosets
title_short Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
title_full Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
title_fullStr Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
title_full_unstemmed Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
title_sort Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network
dc.creator.none.fl_str_mv Soulé, Ezequiel Rodolfo
Jaffrennou, B.
Méchin, F.
Pascault, J. P.
Borrajo Fernandez, Julio
Williams, Roberto Juan Jose
author Soulé, Ezequiel Rodolfo
author_facet Soulé, Ezequiel Rodolfo
Jaffrennou, B.
Méchin, F.
Pascault, J. P.
Borrajo Fernandez, Julio
Williams, Roberto Juan Jose
author_role author
author2 Jaffrennou, B.
Méchin, F.
Pascault, J. P.
Borrajo Fernandez, Julio
Williams, Roberto Juan Jose
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Blends
Miscibility
Phase Separation
Thermodynamics
Thermosets
topic Blends
Miscibility
Phase Separation
Thermodynamics
Thermosets
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Poly(methyl methacrylate) and random copolymers of methyl methacrylate (MMA) and N,N-dimethylacrylamide (DMA) containing 7.5, 15, or 20 wt % DMA were dissolved in a stoichiometric mixture of m-xylylene diisocyanate and 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol, precursors of a polythiourethane network. Phase separation, which took place during polymerizations at 60, 90, and 120 °C, exhibited a lower critical solution temperature behavior. The cloud-point conversions, which were determined by the iodometric titration of free thiol groups of samples chilled in ice at the cloud point, increased with the weight fraction of DMA in the random copolymer. This could be used to control the cloud-point conversion and determine the characteristic size of the dispersed domains. A thermodynamic analysis was performed with the Flory-Huggins equation, taking into account the polydispersities of both the thermoplastic and thermoset polymers and using an interaction parameter depending on the temperature and on the three binary interaction energies. A reasonable fitting of the experimental curves was obtained with negative values for the interaction energies of the MMA-thermoset and DMA-thermoset pairs and with a positive value for the MMA-DMA pair.
Fil: Soulé, Ezequiel Rodolfo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Jaffrennou, B.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Méchin, F.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Pascault, J. P.. Institut National des Sciences Appliqués de Lyon; Francia
Fil: Borrajo Fernandez, Julio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description Poly(methyl methacrylate) and random copolymers of methyl methacrylate (MMA) and N,N-dimethylacrylamide (DMA) containing 7.5, 15, or 20 wt % DMA were dissolved in a stoichiometric mixture of m-xylylene diisocyanate and 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol, precursors of a polythiourethane network. Phase separation, which took place during polymerizations at 60, 90, and 120 °C, exhibited a lower critical solution temperature behavior. The cloud-point conversions, which were determined by the iodometric titration of free thiol groups of samples chilled in ice at the cloud point, increased with the weight fraction of DMA in the random copolymer. This could be used to control the cloud-point conversion and determine the characteristic size of the dispersed domains. A thermodynamic analysis was performed with the Flory-Huggins equation, taking into account the polydispersities of both the thermoplastic and thermoset polymers and using an interaction parameter depending on the temperature and on the three binary interaction energies. A reasonable fitting of the experimental curves was obtained with negative values for the interaction energies of the MMA-thermoset and DMA-thermoset pairs and with a positive value for the MMA-DMA pair.
publishDate 2006
dc.date.none.fl_str_mv 2006-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/76149
Soulé, Ezequiel Rodolfo; Jaffrennou, B.; Méchin, F.; Pascault, J. P.; Borrajo Fernandez, Julio; et al.; Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 44; 19; 10-2006; 2821-2827
0887-6266
CONICET Digital
CONICET
url http://hdl.handle.net/11336/76149
identifier_str_mv Soulé, Ezequiel Rodolfo; Jaffrennou, B.; Méchin, F.; Pascault, J. P.; Borrajo Fernandez, Julio; et al.; Thermodynamic analysis of the reaction-induced phase separation of solutions of random copolymers of methyl methacrylate and N, N-dimethylacrylamide in the precursors of a polythiourethane network; John Wiley & Sons Inc; Journal of Polymer Science Part B: Polymer Physics; 44; 19; 10-2006; 2821-2827
0887-6266
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/full/10.1002/polb.20948
info:eu-repo/semantics/altIdentifier/doi/10.1002/polb.20948
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Inc
publisher.none.fl_str_mv John Wiley & Sons Inc
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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