Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs

Autores
Bernini, Maria Celeste; Snejko, Natalia; Gutierrez Puebla, Enrique; Brusau, Elena Virginia; Narda, Griselda Edith; Monge, M. Ángeles
Año de publicación
2011
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Two new holmium-succinate frameworks have been synthesized by hydrolysis in situ of the succinylsalicylic acid under different hydrothermal conditions. Compound 1, [Ho2(C4H4O4) 3(H2O)2]•0.33(C7H 6O3), Pī space group, has a novel structure composed by 1D-SBUs consisting of [HoO9] chains of polyhedra linked by the succinate ligands giving a 3D framework. Compound 2, [Ho2(C 4H4O4)3(H2O) 2], also belonging to the Pī space group, has a denser structure. The role of the in-situ-generated salicylic acid on formation of both structures is studied by means of a synthesis design methodology. A topological study of the new holmium succinate compounds in comparison with the previously reported 3D holmium-succinate framework is performed here.
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España
Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España
Fil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Monge, M. Ángeles. Instituto de Ciencia de Materiales de Madrid; España
Materia
MOFs
HOLMIUM
STRUCTURE DIRECTING AGENT
TEMPLATE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/148398
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFsBernini, Maria CelesteSnejko, NataliaGutierrez Puebla, EnriqueBrusau, Elena VirginiaNarda, Griselda EdithMonge, M. ÁngelesMOFsHOLMIUMSTRUCTURE DIRECTING AGENTTEMPLATEhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Two new holmium-succinate frameworks have been synthesized by hydrolysis in situ of the succinylsalicylic acid under different hydrothermal conditions. Compound 1, [Ho2(C4H4O4) 3(H2O)2]•0.33(C7H 6O3), Pī space group, has a novel structure composed by 1D-SBUs consisting of [HoO9] chains of polyhedra linked by the succinate ligands giving a 3D framework. Compound 2, [Ho2(C 4H4O4)3(H2O) 2], also belonging to the Pī space group, has a denser structure. The role of the in-situ-generated salicylic acid on formation of both structures is studied by means of a synthesis design methodology. A topological study of the new holmium succinate compounds in comparison with the previously reported 3D holmium-succinate framework is performed here.Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; EspañaFil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; ArgentinaFil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Monge, M. Ángeles. Instituto de Ciencia de Materiales de Madrid; EspañaAmerican Chemical Society2011-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/148398Bernini, Maria Celeste; Snejko, Natalia; Gutierrez Puebla, Enrique; Brusau, Elena Virginia; Narda, Griselda Edith; et al.; Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs; American Chemical Society; Inorganic Chemistry; 50; 13; 6-2011; 5958-59680020-1669CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ic102472uinfo:eu-repo/semantics/altIdentifier/doi/10.1021/ic102472uinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:08:34Zoai:ri.conicet.gov.ar:11336/148398instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:08:34.347CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
title Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
spellingShingle Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
Bernini, Maria Celeste
MOFs
HOLMIUM
STRUCTURE DIRECTING AGENT
TEMPLATE
title_short Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
title_full Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
title_fullStr Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
title_full_unstemmed Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
title_sort Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs
dc.creator.none.fl_str_mv Bernini, Maria Celeste
Snejko, Natalia
Gutierrez Puebla, Enrique
Brusau, Elena Virginia
Narda, Griselda Edith
Monge, M. Ángeles
author Bernini, Maria Celeste
author_facet Bernini, Maria Celeste
Snejko, Natalia
Gutierrez Puebla, Enrique
Brusau, Elena Virginia
Narda, Griselda Edith
Monge, M. Ángeles
author_role author
author2 Snejko, Natalia
Gutierrez Puebla, Enrique
Brusau, Elena Virginia
Narda, Griselda Edith
Monge, M. Ángeles
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv MOFs
HOLMIUM
STRUCTURE DIRECTING AGENT
TEMPLATE
topic MOFs
HOLMIUM
STRUCTURE DIRECTING AGENT
TEMPLATE
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Two new holmium-succinate frameworks have been synthesized by hydrolysis in situ of the succinylsalicylic acid under different hydrothermal conditions. Compound 1, [Ho2(C4H4O4) 3(H2O)2]•0.33(C7H 6O3), Pī space group, has a novel structure composed by 1D-SBUs consisting of [HoO9] chains of polyhedra linked by the succinate ligands giving a 3D framework. Compound 2, [Ho2(C 4H4O4)3(H2O) 2], also belonging to the Pī space group, has a denser structure. The role of the in-situ-generated salicylic acid on formation of both structures is studied by means of a synthesis design methodology. A topological study of the new holmium succinate compounds in comparison with the previously reported 3D holmium-succinate framework is performed here.
Fil: Bernini, Maria Celeste. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Snejko, Natalia. Instituto de Ciencia de Materiales de Madrid; España
Fil: Gutierrez Puebla, Enrique. Instituto de Ciencia de Materiales de Madrid; España
Fil: Brusau, Elena Virginia. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia; Argentina
Fil: Narda, Griselda Edith. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Monge, M. Ángeles. Instituto de Ciencia de Materiales de Madrid; España
description Two new holmium-succinate frameworks have been synthesized by hydrolysis in situ of the succinylsalicylic acid under different hydrothermal conditions. Compound 1, [Ho2(C4H4O4) 3(H2O)2]•0.33(C7H 6O3), Pī space group, has a novel structure composed by 1D-SBUs consisting of [HoO9] chains of polyhedra linked by the succinate ligands giving a 3D framework. Compound 2, [Ho2(C 4H4O4)3(H2O) 2], also belonging to the Pī space group, has a denser structure. The role of the in-situ-generated salicylic acid on formation of both structures is studied by means of a synthesis design methodology. A topological study of the new holmium succinate compounds in comparison with the previously reported 3D holmium-succinate framework is performed here.
publishDate 2011
dc.date.none.fl_str_mv 2011-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/148398
Bernini, Maria Celeste; Snejko, Natalia; Gutierrez Puebla, Enrique; Brusau, Elena Virginia; Narda, Griselda Edith; et al.; Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs; American Chemical Society; Inorganic Chemistry; 50; 13; 6-2011; 5958-5968
0020-1669
CONICET Digital
CONICET
url http://hdl.handle.net/11336/148398
identifier_str_mv Bernini, Maria Celeste; Snejko, Natalia; Gutierrez Puebla, Enrique; Brusau, Elena Virginia; Narda, Griselda Edith; et al.; Structure-directing and template roles of aromatic molecules in the self-assembly formation process of 3D holmium-succinate MOFs; American Chemical Society; Inorganic Chemistry; 50; 13; 6-2011; 5958-5968
0020-1669
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/ic102472u
info:eu-repo/semantics/altIdentifier/doi/10.1021/ic102472u
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.13397

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