Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology

Autores
Abrile, Mariana Guadalupe; Fiasconaro, Maria Laura; Lovato, Maria Eugenia
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work reports the degradation of Reactive Blue 19 (RB19) dye using ozone and ozone/UV. The effects of operational parameters such as pH, ozone concentration and UV radiation were examined. A two factor with three levels factorial design was carried out and the interaction between variables was studied. Response surface methodology was applied in order to optimize ozone concentration, pH and UV radiation in terms of the half life time required for discoloration and/or mineralization of the solution. Equations of color and TOC half-life time with respect to operational conditions were determined. Contour plots and a desirability function were used to find the local points of optimization. Optimized reaction conditions were established as pH 8.26, UV radiation of 40 W and ozone concentration of 50 g Nm−3. A specific experiment was carried out under the optimal conditions where RB19 half life time was 1.59 min and TOC half life time was 30.98 min, confirming the agreement between model and experimental results. The obtained results confirm ozonation as a promising alternative for treatment of wastewater with a high content of recalcitrant reactive dyes.
Fil: Abrile, Mariana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Fiasconaro, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Lovato, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
ANTHRAQUINONE DYE
OZONE
REACTION MODELING
RESPONSE SURFACE METHODOLOGY
UV RADIATION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/137542

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spelling Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodologyAbrile, Mariana GuadalupeFiasconaro, Maria LauraLovato, Maria EugeniaANTHRAQUINONE DYEOZONEREACTION MODELINGRESPONSE SURFACE METHODOLOGYUV RADIATIONhttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2This work reports the degradation of Reactive Blue 19 (RB19) dye using ozone and ozone/UV. The effects of operational parameters such as pH, ozone concentration and UV radiation were examined. A two factor with three levels factorial design was carried out and the interaction between variables was studied. Response surface methodology was applied in order to optimize ozone concentration, pH and UV radiation in terms of the half life time required for discoloration and/or mineralization of the solution. Equations of color and TOC half-life time with respect to operational conditions were determined. Contour plots and a desirability function were used to find the local points of optimization. Optimized reaction conditions were established as pH 8.26, UV radiation of 40 W and ozone concentration of 50 g Nm−3. A specific experiment was carried out under the optimal conditions where RB19 half life time was 1.59 min and TOC half life time was 30.98 min, confirming the agreement between model and experimental results. The obtained results confirm ozonation as a promising alternative for treatment of wastewater with a high content of recalcitrant reactive dyes.Fil: Abrile, Mariana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Fiasconaro, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Lovato, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaSpringer2020-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/137542Abrile, Mariana Guadalupe; Fiasconaro, Maria Laura; Lovato, Maria Eugenia; Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology; Springer; SN Applied Sciences; 2; 5; 4-2020; 1-152523-3963CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s42452-020-2824-yinfo:eu-repo/semantics/altIdentifier/doi/10.1007/s42452-020-2824-yinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:52:42Zoai:ri.conicet.gov.ar:11336/137542instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:52:42.425CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
title Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
spellingShingle Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
Abrile, Mariana Guadalupe
ANTHRAQUINONE DYE
OZONE
REACTION MODELING
RESPONSE SURFACE METHODOLOGY
UV RADIATION
title_short Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
title_full Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
title_fullStr Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
title_full_unstemmed Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
title_sort Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology
dc.creator.none.fl_str_mv Abrile, Mariana Guadalupe
Fiasconaro, Maria Laura
Lovato, Maria Eugenia
author Abrile, Mariana Guadalupe
author_facet Abrile, Mariana Guadalupe
Fiasconaro, Maria Laura
Lovato, Maria Eugenia
author_role author
author2 Fiasconaro, Maria Laura
Lovato, Maria Eugenia
author2_role author
author
dc.subject.none.fl_str_mv ANTHRAQUINONE DYE
OZONE
REACTION MODELING
RESPONSE SURFACE METHODOLOGY
UV RADIATION
topic ANTHRAQUINONE DYE
OZONE
REACTION MODELING
RESPONSE SURFACE METHODOLOGY
UV RADIATION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work reports the degradation of Reactive Blue 19 (RB19) dye using ozone and ozone/UV. The effects of operational parameters such as pH, ozone concentration and UV radiation were examined. A two factor with three levels factorial design was carried out and the interaction between variables was studied. Response surface methodology was applied in order to optimize ozone concentration, pH and UV radiation in terms of the half life time required for discoloration and/or mineralization of the solution. Equations of color and TOC half-life time with respect to operational conditions were determined. Contour plots and a desirability function were used to find the local points of optimization. Optimized reaction conditions were established as pH 8.26, UV radiation of 40 W and ozone concentration of 50 g Nm−3. A specific experiment was carried out under the optimal conditions where RB19 half life time was 1.59 min and TOC half life time was 30.98 min, confirming the agreement between model and experimental results. The obtained results confirm ozonation as a promising alternative for treatment of wastewater with a high content of recalcitrant reactive dyes.
Fil: Abrile, Mariana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Fiasconaro, Maria Laura. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Lovato, Maria Eugenia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description This work reports the degradation of Reactive Blue 19 (RB19) dye using ozone and ozone/UV. The effects of operational parameters such as pH, ozone concentration and UV radiation were examined. A two factor with three levels factorial design was carried out and the interaction between variables was studied. Response surface methodology was applied in order to optimize ozone concentration, pH and UV radiation in terms of the half life time required for discoloration and/or mineralization of the solution. Equations of color and TOC half-life time with respect to operational conditions were determined. Contour plots and a desirability function were used to find the local points of optimization. Optimized reaction conditions were established as pH 8.26, UV radiation of 40 W and ozone concentration of 50 g Nm−3. A specific experiment was carried out under the optimal conditions where RB19 half life time was 1.59 min and TOC half life time was 30.98 min, confirming the agreement between model and experimental results. The obtained results confirm ozonation as a promising alternative for treatment of wastewater with a high content of recalcitrant reactive dyes.
publishDate 2020
dc.date.none.fl_str_mv 2020-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/137542
Abrile, Mariana Guadalupe; Fiasconaro, Maria Laura; Lovato, Maria Eugenia; Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology; Springer; SN Applied Sciences; 2; 5; 4-2020; 1-15
2523-3963
CONICET Digital
CONICET
url http://hdl.handle.net/11336/137542
identifier_str_mv Abrile, Mariana Guadalupe; Fiasconaro, Maria Laura; Lovato, Maria Eugenia; Optimization of Reactive Blue 19 dye removal using ozone and ozone/UV employing response surface methodology; Springer; SN Applied Sciences; 2; 5; 4-2020; 1-15
2523-3963
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s42452-020-2824-y
info:eu-repo/semantics/altIdentifier/doi/10.1007/s42452-020-2824-y
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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