Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation

Autores
Montagna, Pablo N.; Inalbon, Maria Cristina; Paananen, Markus; Sixta, Herbert; Zanuttini, Miguel Angel Mario
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
During the impregnation stage of a Kraft cooking, dynamic changes occur in wood properties due to the alkali action. Particularly, its ion transport capacity, the effective capillary cross sectional area (ECCSA), is changed due to chemical reactions and swelling. In this work, the ECCSA in the transverse wood direction has been determined for Pinus sylvestris on the basis of the analogy between capillarity and electrical conductivity. Results show that the behavior of ECCSA can be associated with (a) the degree of removal of native acetyl groups and (b) the galactoglucomannan (GGM) losses due to peeling/stopping reactions and alkaline hydrolysis. Kinetic expressions for both reactions were discussed and a correlation between the ECCSA and both acetyl and GGM contents was established.
Fil: Montagna, Pablo N.. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Paananen, Markus. Aalto University. Department of Forest Products Technology; Finlandia
Fil: Sixta, Herbert. Aalto University. Department of Forest Products Technology; Finlandia
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Materia
Diffusion
Deacetylation Kinetics
Galactoglucomannan Degradation
Effective Capillary Cross Sectional Area (Eccsa)
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6382
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/6382
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradationMontagna, Pablo N.Inalbon, Maria CristinaPaananen, MarkusSixta, HerbertZanuttini, Miguel Angel MarioDiffusionDeacetylation KineticsGalactoglucomannan DegradationEffective Capillary Cross Sectional Area (Eccsa)https://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2During the impregnation stage of a Kraft cooking, dynamic changes occur in wood properties due to the alkali action. Particularly, its ion transport capacity, the effective capillary cross sectional area (ECCSA), is changed due to chemical reactions and swelling. In this work, the ECCSA in the transverse wood direction has been determined for Pinus sylvestris on the basis of the analogy between capillarity and electrical conductivity. Results show that the behavior of ECCSA can be associated with (a) the degree of removal of native acetyl groups and (b) the galactoglucomannan (GGM) losses due to peeling/stopping reactions and alkaline hydrolysis. Kinetic expressions for both reactions were discussed and a correlation between the ECCSA and both acetyl and GGM contents was established.Fil: Montagna, Pablo N.. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaFil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaFil: Paananen, Markus. Aalto University. Department of Forest Products Technology; FinlandiaFil: Sixta, Herbert. Aalto University. Department of Forest Products Technology; FinlandiaFil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaAmerican Chemical Society2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6382Montagna, Pablo N.; Inalbon, Maria Cristina; Paananen, Markus; Sixta, Herbert; Zanuttini, Miguel Angel Mario; Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation; American Chemical Society; Industrial & Engineering Chemical Research; 52; 10; 1-2013; 3658-36620888-5885enginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/full/10.1021/ie3024388info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1021/ie3024388info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:18:22Zoai:ri.conicet.gov.ar:11336/6382instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:18:22.502CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
title Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
spellingShingle Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
Montagna, Pablo N.
Diffusion
Deacetylation Kinetics
Galactoglucomannan Degradation
Effective Capillary Cross Sectional Area (Eccsa)
title_short Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
title_full Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
title_fullStr Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
title_full_unstemmed Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
title_sort Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation
dc.creator.none.fl_str_mv Montagna, Pablo N.
Inalbon, Maria Cristina
Paananen, Markus
Sixta, Herbert
Zanuttini, Miguel Angel Mario
author Montagna, Pablo N.
author_facet Montagna, Pablo N.
Inalbon, Maria Cristina
Paananen, Markus
Sixta, Herbert
Zanuttini, Miguel Angel Mario
author_role author
author2 Inalbon, Maria Cristina
Paananen, Markus
Sixta, Herbert
Zanuttini, Miguel Angel Mario
author2_role author
author
author
author
dc.subject.none.fl_str_mv Diffusion
Deacetylation Kinetics
Galactoglucomannan Degradation
Effective Capillary Cross Sectional Area (Eccsa)
topic Diffusion
Deacetylation Kinetics
Galactoglucomannan Degradation
Effective Capillary Cross Sectional Area (Eccsa)
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv During the impregnation stage of a Kraft cooking, dynamic changes occur in wood properties due to the alkali action. Particularly, its ion transport capacity, the effective capillary cross sectional area (ECCSA), is changed due to chemical reactions and swelling. In this work, the ECCSA in the transverse wood direction has been determined for Pinus sylvestris on the basis of the analogy between capillarity and electrical conductivity. Results show that the behavior of ECCSA can be associated with (a) the degree of removal of native acetyl groups and (b) the galactoglucomannan (GGM) losses due to peeling/stopping reactions and alkaline hydrolysis. Kinetic expressions for both reactions were discussed and a correlation between the ECCSA and both acetyl and GGM contents was established.
Fil: Montagna, Pablo N.. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Paananen, Markus. Aalto University. Department of Forest Products Technology; Finlandia
Fil: Sixta, Herbert. Aalto University. Department of Forest Products Technology; Finlandia
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
description During the impregnation stage of a Kraft cooking, dynamic changes occur in wood properties due to the alkali action. Particularly, its ion transport capacity, the effective capillary cross sectional area (ECCSA), is changed due to chemical reactions and swelling. In this work, the ECCSA in the transverse wood direction has been determined for Pinus sylvestris on the basis of the analogy between capillarity and electrical conductivity. Results show that the behavior of ECCSA can be associated with (a) the degree of removal of native acetyl groups and (b) the galactoglucomannan (GGM) losses due to peeling/stopping reactions and alkaline hydrolysis. Kinetic expressions for both reactions were discussed and a correlation between the ECCSA and both acetyl and GGM contents was established.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6382
Montagna, Pablo N.; Inalbon, Maria Cristina; Paananen, Markus; Sixta, Herbert; Zanuttini, Miguel Angel Mario; Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation; American Chemical Society; Industrial & Engineering Chemical Research; 52; 10; 1-2013; 3658-3662
0888-5885
url http://hdl.handle.net/11336/6382
identifier_str_mv Montagna, Pablo N.; Inalbon, Maria Cristina; Paananen, Markus; Sixta, Herbert; Zanuttini, Miguel Angel Mario; Diffusion dynamics in Pinus sylvestris Kraft impregnation: Effect of deacetylation and galactoglucomannan degradation; American Chemical Society; Industrial & Engineering Chemical Research; 52; 10; 1-2013; 3658-3662
0888-5885
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/full/10.1021/ie3024388
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1021/ie3024388
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781645558906880
score 12.982451

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