Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
- Autores
- Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.
Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina - Materia
-
alkaline pre-extraction
deacetylation kinetics
diffusion
effective capillarity - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/6384
Ver los metadatos del registro completo
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Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directionsInalbon, Maria CristinaMontagna, PabloGalván, María VerónicaDemonte, LucianoZanuttini, Miguel Angel Marioalkaline pre-extractiondeacetylation kineticsdiffusioneffective capillarityhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaFil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentinade Gruyter2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6384Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-460018-3830enginfo:eu-repo/semantics/altIdentifier/url/http://www.degruyter.com/view/j/hfsg.2013.67.issue-1/hf-2012-0030/hf-2012-0030.xmlinfo:eu-repo/semantics/altIdentifier/doi/10.1515/hf-2012-0030info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:30:52Zoai:ri.conicet.gov.ar:11336/6384instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:30:52.406CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
title |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
spellingShingle |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions Inalbon, Maria Cristina alkaline pre-extraction deacetylation kinetics diffusion effective capillarity |
title_short |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
title_full |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
title_fullStr |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
title_full_unstemmed |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
title_sort |
Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions |
dc.creator.none.fl_str_mv |
Inalbon, Maria Cristina Montagna, Pablo Galván, María Verónica Demonte, Luciano Zanuttini, Miguel Angel Mario |
author |
Inalbon, Maria Cristina |
author_facet |
Inalbon, Maria Cristina Montagna, Pablo Galván, María Verónica Demonte, Luciano Zanuttini, Miguel Angel Mario |
author_role |
author |
author2 |
Montagna, Pablo Galván, María Verónica Demonte, Luciano Zanuttini, Miguel Angel Mario |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
alkaline pre-extraction deacetylation kinetics diffusion effective capillarity |
topic |
alkaline pre-extraction deacetylation kinetics diffusion effective capillarity |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions. Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina Fil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina Fil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina |
description |
The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/6384 Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-46 0018-3830 |
url |
http://hdl.handle.net/11336/6384 |
identifier_str_mv |
Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-46 0018-3830 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.degruyter.com/view/j/hfsg.2013.67.issue-1/hf-2012-0030/hf-2012-0030.xml info:eu-repo/semantics/altIdentifier/doi/10.1515/hf-2012-0030 info:eu-repo/semantics/altIdentifier/doi/ |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
de Gruyter |
publisher.none.fl_str_mv |
de Gruyter |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614317565018112 |
score |
13.070432 |