Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions

Autores
Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.
Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Materia
alkaline pre-extraction
deacetylation kinetics
diffusion
effective capillarity
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/6384
Acceder
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repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directionsInalbon, Maria CristinaMontagna, PabloGalván, María VerónicaDemonte, LucianoZanuttini, Miguel Angel Marioalkaline pre-extractiondeacetylation kineticsdiffusioneffective capillarityhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; ArgentinaFil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; ArgentinaFil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentinade Gruyter2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/6384Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-460018-3830enginfo:eu-repo/semantics/altIdentifier/url/http://www.degruyter.com/view/j/hfsg.2013.67.issue-1/hf-2012-0030/hf-2012-0030.xmlinfo:eu-repo/semantics/altIdentifier/doi/10.1515/hf-2012-0030info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T12:03:18Zoai:ri.conicet.gov.ar:11336/6384instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 12:03:18.3CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
title Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
spellingShingle Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
Inalbon, Maria Cristina
alkaline pre-extraction
deacetylation kinetics
diffusion
effective capillarity
title_short Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
title_full Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
title_fullStr Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
title_full_unstemmed Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
title_sort Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions
dc.creator.none.fl_str_mv Inalbon, Maria Cristina
Montagna, Pablo
Galván, María Verónica
Demonte, Luciano
Zanuttini, Miguel Angel Mario
author Inalbon, Maria Cristina
author_facet Inalbon, Maria Cristina
Montagna, Pablo
Galván, María Verónica
Demonte, Luciano
Zanuttini, Miguel Angel Mario
author_role author
author2 Montagna, Pablo
Galván, María Verónica
Demonte, Luciano
Zanuttini, Miguel Angel Mario
author2_role author
author
author
author
dc.subject.none.fl_str_mv alkaline pre-extraction
deacetylation kinetics
diffusion
effective capillarity
topic alkaline pre-extraction
deacetylation kinetics
diffusion
effective capillarity
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.
Fil: Inalbon, Maria Cristina. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
Fil: Montagna, Pablo. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Galván, María Verónica. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Demonte, Luciano. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina
Fil: Zanuttini, Miguel Angel Mario. Universidad Nacional del Litoral. Facultad de Ingenieria Quimica. Instituto de Tecnologia Celulosica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Santa Fe; Argentina
description The relative ion transport capacity of wood, i.e., the Effective Capillary Cross Sectional Area (ECCSA), is determined in this work based on the analogy with the relation between the electrical conductivities of wood and liquid medium. Wood is treated under different conditions and then the corresponding ECCSAA (effective capillarity under alkali) is estimated from the value obtained in an inert solution at room temperature (ECCSAInert). The difference between radial and tangential ECCSAA-values can be considered similar irrespectively of pH, time, temperature and the presence of sodium sulfide in the treatment liquor. The results show that the degree of removal of native acetyl groups from hardwood O-acetyl-glucuronoxylan is determinant of a physical characteristic, the ECCSAA. A kinetic expression for Eucalyptus wood deacetylation is validated and used to establish the relationship between the acetyl content and ECCSAA in both directions.
publishDate 2013
dc.date.none.fl_str_mv 2013-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/6384
Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-46
0018-3830
url http://hdl.handle.net/11336/6384
identifier_str_mv Inalbon, Maria Cristina; Montagna, Pablo; Galván, María Verónica; Demonte, Luciano; Zanuttini, Miguel Angel Mario; Wood capillarity and deacetylation during eucalyptus alkaline impregnation. Suphidity effects and comparison between transverse directions; de Gruyter; Holzforschung; 67; 1; 1-2013; 41-46
0018-3830
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.degruyter.com/view/j/hfsg.2013.67.issue-1/hf-2012-0030/hf-2012-0030.xml
info:eu-repo/semantics/altIdentifier/doi/10.1515/hf-2012-0030
info:eu-repo/semantics/altIdentifier/doi/
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv de Gruyter
publisher.none.fl_str_mv de Gruyter
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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