Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures
- Autores
- Pinto, L. F.; Rodriguez Reartes, Sabrina Belen; Corazza, M. L.; Cabral, V. F.; Araújo, P. H. H. de; Madureira, E. H.; Zabaloy, Marcelo Santiago; Cardozo Filho, L.
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- In this study the phase equilibrium behavior of the binary system CO2 (1) + medroxyprogesterone acetate (2) was determined. The static synthetic method, using a variable-volume view cell, was employed to obtain the experimental data in the temperature range of (303.15 to 343.15) K and pressures up to about 22 MPa. The mole fraction of medroxyprogesterone acetate varyied in the range from 4.10-5 to 9.10-5. For this system (fluid + solid) and (fluid + fluid + solid) transitions were observed. The phase equilibrium data obtained in this work were modeled using the Peng-Robinson equation of state for describing fluid mixtures, and an expression for the fugacity of pure solid medroxyprogesterone acetate (MPgAc) for representing the solid phase. The thermodynamic model was able to satisfactorily describe the phase behavior of the system investigated.
Fil: Pinto, L. F.. Universidade Estadual de Maringá; Brasil
Fil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Corazza, M. L.. Universidade Federal Do Parana; Brasil
Fil: Cabral, V. F.. Universidade Estadual de Maringá; Brasil
Fil: Araújo, P. H. H. de. Universidade Federal Da Santa Catarina; Brasil
Fil: Madureira, E. H.. Universidade de Sao Paulo; Brasil
Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina
Fil: Cardozo Filho, L.. Universidade Estadual de Maringá; Brasil - Materia
-
Phase Equilibrium
Medroxyprogesterone Acetate
Co2
Supercritical
Equation of State - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/12012
Ver los metadatos del registro completo
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Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressuresPinto, L. F.Rodriguez Reartes, Sabrina BelenCorazza, M. L.Cabral, V. F.Araújo, P. H. H. deMadureira, E. H.Zabaloy, Marcelo SantiagoCardozo Filho, L.Phase EquilibriumMedroxyprogesterone AcetateCo2SupercriticalEquation of Statehttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2In this study the phase equilibrium behavior of the binary system CO2 (1) + medroxyprogesterone acetate (2) was determined. The static synthetic method, using a variable-volume view cell, was employed to obtain the experimental data in the temperature range of (303.15 to 343.15) K and pressures up to about 22 MPa. The mole fraction of medroxyprogesterone acetate varyied in the range from 4.10-5 to 9.10-5. For this system (fluid + solid) and (fluid + fluid + solid) transitions were observed. The phase equilibrium data obtained in this work were modeled using the Peng-Robinson equation of state for describing fluid mixtures, and an expression for the fugacity of pure solid medroxyprogesterone acetate (MPgAc) for representing the solid phase. The thermodynamic model was able to satisfactorily describe the phase behavior of the system investigated.Fil: Pinto, L. F.. Universidade Estadual de Maringá; BrasilFil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaFil: Corazza, M. L.. Universidade Federal Do Parana; BrasilFil: Cabral, V. F.. Universidade Estadual de Maringá; BrasilFil: Araújo, P. H. H. de. Universidade Federal Da Santa Catarina; BrasilFil: Madureira, E. H.. Universidade de Sao Paulo; BrasilFil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; ArgentinaFil: Cardozo Filho, L.. Universidade Estadual de Maringá; BrasilElsevier Science2013-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/12012Pinto, L. F.; Rodriguez Reartes, Sabrina Belen; Corazza, M. L.; Cabral, V. F.; Araújo, P. H. H. de; et al.; Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures; Elsevier Science; Fluid Phase Equilibria; 349; 7-2013; 1-110378-3812enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381213001465info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2013.03.019info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T09:55:13Zoai:ri.conicet.gov.ar:11336/12012instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 09:55:13.515CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
title |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
spellingShingle |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures Pinto, L. F. Phase Equilibrium Medroxyprogesterone Acetate Co2 Supercritical Equation of State |
title_short |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
title_full |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
title_fullStr |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
title_full_unstemmed |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
title_sort |
Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures |
dc.creator.none.fl_str_mv |
Pinto, L. F. Rodriguez Reartes, Sabrina Belen Corazza, M. L. Cabral, V. F. Araújo, P. H. H. de Madureira, E. H. Zabaloy, Marcelo Santiago Cardozo Filho, L. |
author |
Pinto, L. F. |
author_facet |
Pinto, L. F. Rodriguez Reartes, Sabrina Belen Corazza, M. L. Cabral, V. F. Araújo, P. H. H. de Madureira, E. H. Zabaloy, Marcelo Santiago Cardozo Filho, L. |
author_role |
author |
author2 |
Rodriguez Reartes, Sabrina Belen Corazza, M. L. Cabral, V. F. Araújo, P. H. H. de Madureira, E. H. Zabaloy, Marcelo Santiago Cardozo Filho, L. |
author2_role |
author author author author author author author |
dc.subject.none.fl_str_mv |
Phase Equilibrium Medroxyprogesterone Acetate Co2 Supercritical Equation of State |
topic |
Phase Equilibrium Medroxyprogesterone Acetate Co2 Supercritical Equation of State |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
In this study the phase equilibrium behavior of the binary system CO2 (1) + medroxyprogesterone acetate (2) was determined. The static synthetic method, using a variable-volume view cell, was employed to obtain the experimental data in the temperature range of (303.15 to 343.15) K and pressures up to about 22 MPa. The mole fraction of medroxyprogesterone acetate varyied in the range from 4.10-5 to 9.10-5. For this system (fluid + solid) and (fluid + fluid + solid) transitions were observed. The phase equilibrium data obtained in this work were modeled using the Peng-Robinson equation of state for describing fluid mixtures, and an expression for the fugacity of pure solid medroxyprogesterone acetate (MPgAc) for representing the solid phase. The thermodynamic model was able to satisfactorily describe the phase behavior of the system investigated. Fil: Pinto, L. F.. Universidade Estadual de Maringá; Brasil Fil: Rodriguez Reartes, Sabrina Belen. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina Fil: Corazza, M. L.. Universidade Federal Do Parana; Brasil Fil: Cabral, V. F.. Universidade Estadual de Maringá; Brasil Fil: Araújo, P. H. H. de. Universidade Federal Da Santa Catarina; Brasil Fil: Madureira, E. H.. Universidade de Sao Paulo; Brasil Fil: Zabaloy, Marcelo Santiago. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Planta Piloto de Ingeniería Química (i); Argentina. Universidad Nacional del Sur; Argentina Fil: Cardozo Filho, L.. Universidade Estadual de Maringá; Brasil |
description |
In this study the phase equilibrium behavior of the binary system CO2 (1) + medroxyprogesterone acetate (2) was determined. The static synthetic method, using a variable-volume view cell, was employed to obtain the experimental data in the temperature range of (303.15 to 343.15) K and pressures up to about 22 MPa. The mole fraction of medroxyprogesterone acetate varyied in the range from 4.10-5 to 9.10-5. For this system (fluid + solid) and (fluid + fluid + solid) transitions were observed. The phase equilibrium data obtained in this work were modeled using the Peng-Robinson equation of state for describing fluid mixtures, and an expression for the fugacity of pure solid medroxyprogesterone acetate (MPgAc) for representing the solid phase. The thermodynamic model was able to satisfactorily describe the phase behavior of the system investigated. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-07 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/12012 Pinto, L. F.; Rodriguez Reartes, Sabrina Belen; Corazza, M. L.; Cabral, V. F.; Araújo, P. H. H. de; et al.; Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures; Elsevier Science; Fluid Phase Equilibria; 349; 7-2013; 1-11 0378-3812 |
url |
http://hdl.handle.net/11336/12012 |
identifier_str_mv |
Pinto, L. F.; Rodriguez Reartes, Sabrina Belen; Corazza, M. L.; Cabral, V. F.; Araújo, P. H. H. de; et al.; Phase behavior of carbon dioxide + medroxyprogesterone acetate system at high pressures; Elsevier Science; Fluid Phase Equilibria; 349; 7-2013; 1-11 0378-3812 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0378381213001465 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.fluid.2013.03.019 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
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CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1842269331579207680 |
score |
13.13397 |