Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment

Autores
Sacco, Nicolás Alejandro; Banus, Ezequiel David; Bortolozzi, Juan Pablo; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The combination of the selective catalytic reduction technology with catalytic filters constitutes one of the most efficient ways for diesel engine exhaust treatment. In this paper, the development of catalytic ceramic papers as structured systems for the abatement of diesel soot particles is addressed. Ceramic papers were prepared by the dual-polyelectrolyte papermaking method, which is based on the conventional papermaking technique used for cellulosic papers, in which a portion of cellulosic fibers is replaced by ceramic ones. The deposition of Co and Ce as catalytic materials by the wet spray method on ceramic papers was studied for the development of structured catalysts using an ultrasonic nebulizer and different solvents. The use of alcohol-water solutions for the impregnation of cobalt generated smaller particles and a high dispersion of them on the ceramic fibers, greater than that obtained when pure water was employed. Temperature programmed oxidation (TPO) assays showed that the best catalytic performance was acquired with the catalysts generated with alcohol solvents, showing a maximum rate for soot combustion at a temperature close to 400 °C. The adequate soot combustion performance and the high thermal and catalytic stability make catalytic ceramic papers impregnated by the wet spray method, promising systems for their application as diesel particulate filters.
Fil: Sacco, Nicolás Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
ULTRASOUND
STRUCTURED CATALYSTS
CERAMIC PAPER
SOOT REMOVAL
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88459
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/88459
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust TreatmentSacco, Nicolás AlejandroBanus, Ezequiel DavidBortolozzi, Juan PabloMilt, Viviana GuadalupeMiro, Eduardo ErnestoULTRASOUNDSTRUCTURED CATALYSTSCERAMIC PAPERSOOT REMOVALhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The combination of the selective catalytic reduction technology with catalytic filters constitutes one of the most efficient ways for diesel engine exhaust treatment. In this paper, the development of catalytic ceramic papers as structured systems for the abatement of diesel soot particles is addressed. Ceramic papers were prepared by the dual-polyelectrolyte papermaking method, which is based on the conventional papermaking technique used for cellulosic papers, in which a portion of cellulosic fibers is replaced by ceramic ones. The deposition of Co and Ce as catalytic materials by the wet spray method on ceramic papers was studied for the development of structured catalysts using an ultrasonic nebulizer and different solvents. The use of alcohol-water solutions for the impregnation of cobalt generated smaller particles and a high dispersion of them on the ceramic fibers, greater than that obtained when pure water was employed. Temperature programmed oxidation (TPO) assays showed that the best catalytic performance was acquired with the catalysts generated with alcohol solvents, showing a maximum rate for soot combustion at a temperature close to 400 °C. The adequate soot combustion performance and the high thermal and catalytic stability make catalytic ceramic papers impregnated by the wet spray method, promising systems for their application as diesel particulate filters.Fil: Sacco, Nicolás Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaAmerican Chemical Society2018-12-26info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88459Sacco, Nicolás Alejandro; Banus, Ezequiel David; Bortolozzi, Juan Pablo; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment; American Chemical Society; ACS Omega; 3; 12; 26-12-2018; 18334-183422470-1343CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acsomega.8b02949info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.8b02949info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:24:45Zoai:ri.conicet.gov.ar:11336/88459instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:24:45.329CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
title Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
spellingShingle Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
Sacco, Nicolás Alejandro
ULTRASOUND
STRUCTURED CATALYSTS
CERAMIC PAPER
SOOT REMOVAL
title_short Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
title_full Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
title_fullStr Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
title_full_unstemmed Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
title_sort Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment
dc.creator.none.fl_str_mv Sacco, Nicolás Alejandro
Banus, Ezequiel David
Bortolozzi, Juan Pablo
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author Sacco, Nicolás Alejandro
author_facet Sacco, Nicolás Alejandro
Banus, Ezequiel David
Bortolozzi, Juan Pablo
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author_role author
author2 Banus, Ezequiel David
Bortolozzi, Juan Pablo
Milt, Viviana Guadalupe
Miro, Eduardo Ernesto
author2_role author
author
author
author
dc.subject.none.fl_str_mv ULTRASOUND
STRUCTURED CATALYSTS
CERAMIC PAPER
SOOT REMOVAL
topic ULTRASOUND
STRUCTURED CATALYSTS
CERAMIC PAPER
SOOT REMOVAL
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The combination of the selective catalytic reduction technology with catalytic filters constitutes one of the most efficient ways for diesel engine exhaust treatment. In this paper, the development of catalytic ceramic papers as structured systems for the abatement of diesel soot particles is addressed. Ceramic papers were prepared by the dual-polyelectrolyte papermaking method, which is based on the conventional papermaking technique used for cellulosic papers, in which a portion of cellulosic fibers is replaced by ceramic ones. The deposition of Co and Ce as catalytic materials by the wet spray method on ceramic papers was studied for the development of structured catalysts using an ultrasonic nebulizer and different solvents. The use of alcohol-water solutions for the impregnation of cobalt generated smaller particles and a high dispersion of them on the ceramic fibers, greater than that obtained when pure water was employed. Temperature programmed oxidation (TPO) assays showed that the best catalytic performance was acquired with the catalysts generated with alcohol solvents, showing a maximum rate for soot combustion at a temperature close to 400 °C. The adequate soot combustion performance and the high thermal and catalytic stability make catalytic ceramic papers impregnated by the wet spray method, promising systems for their application as diesel particulate filters.
Fil: Sacco, Nicolás Alejandro. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Banus, Ezequiel David. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bortolozzi, Juan Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Miro, Eduardo Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description The combination of the selective catalytic reduction technology with catalytic filters constitutes one of the most efficient ways for diesel engine exhaust treatment. In this paper, the development of catalytic ceramic papers as structured systems for the abatement of diesel soot particles is addressed. Ceramic papers were prepared by the dual-polyelectrolyte papermaking method, which is based on the conventional papermaking technique used for cellulosic papers, in which a portion of cellulosic fibers is replaced by ceramic ones. The deposition of Co and Ce as catalytic materials by the wet spray method on ceramic papers was studied for the development of structured catalysts using an ultrasonic nebulizer and different solvents. The use of alcohol-water solutions for the impregnation of cobalt generated smaller particles and a high dispersion of them on the ceramic fibers, greater than that obtained when pure water was employed. Temperature programmed oxidation (TPO) assays showed that the best catalytic performance was acquired with the catalysts generated with alcohol solvents, showing a maximum rate for soot combustion at a temperature close to 400 °C. The adequate soot combustion performance and the high thermal and catalytic stability make catalytic ceramic papers impregnated by the wet spray method, promising systems for their application as diesel particulate filters.
publishDate 2018
dc.date.none.fl_str_mv 2018-12-26
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88459
Sacco, Nicolás Alejandro; Banus, Ezequiel David; Bortolozzi, Juan Pablo; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment; American Chemical Society; ACS Omega; 3; 12; 26-12-2018; 18334-18342
2470-1343
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88459
identifier_str_mv Sacco, Nicolás Alejandro; Banus, Ezequiel David; Bortolozzi, Juan Pablo; Milt, Viviana Guadalupe; Miro, Eduardo Ernesto; Ultrasound-Assisted Deposition of Co-CeO2 onto Ceramic Microfibers to Conform Catalytic Papers: Their Application in Engine Exhaust Treatment; American Chemical Society; ACS Omega; 3; 12; 26-12-2018; 18334-18342
2470-1343
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/10.1021/acsomega.8b02949
info:eu-repo/semantics/altIdentifier/doi/10.1021/acsomega.8b02949
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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