Comparison of lattice-fluid binary parameters for mixtures and block copolymers

Autores
Riccardi, Carmen Cristina; Schroeder, Walter Fabian; Serrano, Elena; Mondragon, Iñaki
Año de publicación
2012
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The aim of this report is to discuss the method of determination of lattice-fluid binary interaction parameters by comparing well characterized immiscible blends and block copolymers of poly(methyl methacrylate) (PMMA) and poly(ε−caprolactone) (PCL). Experimental pressure-volume-temperature (PVT) data in the liquid state were correlated with the Sanchez-Lacombe (SL) equation of state with the scaling parameters for mixtures and copolymers obtained through combination rules of the characteristic parameters for the pure homopolymers. The lattice-fluid binary parameters for energy and volume were higher than those of block copolymers implying that the copolymers were more compatible due to the chemical links between the blocks. Therefore, a common parameter cannot account for both homopolymer blend and block copolymer phase behaviors based on current theory. As we were able to adjust all data of the mixtures with a single set of lattice-binary parameters and all data of the block copolymers with another single set we can conclude that both parameters did not depend on the composition for this system. This characteristic, plus the fact that the additivity law of specific volumes can be suitably applied for this system, allowed us to model the behavior of the immiscible blend with the SL equation of state. In addition, a discussion on the relationship between lattice-fluid binary parameters and the Flory-Huggins interaction parameter obtained from Leibler's theory is presented.
Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Schroeder, Walter Fabian. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Serrano, Elena. Universidad de Alicante. Departamento de Física; España;
Fil: Mondragon, Iñaki. Universidad del Pais Vasco; España
Materia
BLOCK COPOLYMER
IMMISCIBLE BLEND
INTERACTION PARAMETER
LATTICE-BINARY PARAMETER
PVT
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/2586
Acceder
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Comparison of lattice-fluid binary parameters for mixtures and block copolymersRiccardi, Carmen CristinaSchroeder, Walter FabianSerrano, ElenaMondragon, IñakiBLOCK COPOLYMERIMMISCIBLE BLENDINTERACTION PARAMETERLATTICE-BINARY PARAMETERPVThttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2https://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The aim of this report is to discuss the method of determination of lattice-fluid binary interaction parameters by comparing well characterized immiscible blends and block copolymers of poly(methyl methacrylate) (PMMA) and poly(ε−caprolactone) (PCL). Experimental pressure-volume-temperature (PVT) data in the liquid state were correlated with the Sanchez-Lacombe (SL) equation of state with the scaling parameters for mixtures and copolymers obtained through combination rules of the characteristic parameters for the pure homopolymers. The lattice-fluid binary parameters for energy and volume were higher than those of block copolymers implying that the copolymers were more compatible due to the chemical links between the blocks. Therefore, a common parameter cannot account for both homopolymer blend and block copolymer phase behaviors based on current theory. As we were able to adjust all data of the mixtures with a single set of lattice-binary parameters and all data of the block copolymers with another single set we can conclude that both parameters did not depend on the composition for this system. This characteristic, plus the fact that the additivity law of specific volumes can be suitably applied for this system, allowed us to model the behavior of the immiscible blend with the SL equation of state. In addition, a discussion on the relationship between lattice-fluid binary parameters and the Flory-Huggins interaction parameter obtained from Leibler's theory is presented.Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Schroeder, Walter Fabian. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); ArgentinaFil: Serrano, Elena. Universidad de Alicante. Departamento de Física; España;Fil: Mondragon, Iñaki. Universidad del Pais Vasco; EspañaTaylor & Francis2012-10-16info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/2586Riccardi, Carmen Cristina; Schroeder, Walter Fabian; Serrano, Elena; Mondragon, Iñaki; Comparison of lattice-fluid binary parameters for mixtures and block copolymers; Taylor & Francis; Journal Of Macromolecular Science-physics; 52; 1; 16-10-2012; 65-830022-2348enginfo:eu-repo/semantics/altIdentifier/doi/10.1080/00222348.2012.685829info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/toc/lmsb20/52/1info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:52:52Zoai:ri.conicet.gov.ar:11336/2586instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:52:52.86CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Comparison of lattice-fluid binary parameters for mixtures and block copolymers
title Comparison of lattice-fluid binary parameters for mixtures and block copolymers
spellingShingle Comparison of lattice-fluid binary parameters for mixtures and block copolymers
Riccardi, Carmen Cristina
BLOCK COPOLYMER
IMMISCIBLE BLEND
INTERACTION PARAMETER
LATTICE-BINARY PARAMETER
PVT
title_short Comparison of lattice-fluid binary parameters for mixtures and block copolymers
title_full Comparison of lattice-fluid binary parameters for mixtures and block copolymers
title_fullStr Comparison of lattice-fluid binary parameters for mixtures and block copolymers
title_full_unstemmed Comparison of lattice-fluid binary parameters for mixtures and block copolymers
title_sort Comparison of lattice-fluid binary parameters for mixtures and block copolymers
dc.creator.none.fl_str_mv Riccardi, Carmen Cristina
Schroeder, Walter Fabian
Serrano, Elena
Mondragon, Iñaki
author Riccardi, Carmen Cristina
author_facet Riccardi, Carmen Cristina
Schroeder, Walter Fabian
Serrano, Elena
Mondragon, Iñaki
author_role author
author2 Schroeder, Walter Fabian
Serrano, Elena
Mondragon, Iñaki
author2_role author
author
author
dc.subject.none.fl_str_mv BLOCK COPOLYMER
IMMISCIBLE BLEND
INTERACTION PARAMETER
LATTICE-BINARY PARAMETER
PVT
topic BLOCK COPOLYMER
IMMISCIBLE BLEND
INTERACTION PARAMETER
LATTICE-BINARY PARAMETER
PVT
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The aim of this report is to discuss the method of determination of lattice-fluid binary interaction parameters by comparing well characterized immiscible blends and block copolymers of poly(methyl methacrylate) (PMMA) and poly(ε−caprolactone) (PCL). Experimental pressure-volume-temperature (PVT) data in the liquid state were correlated with the Sanchez-Lacombe (SL) equation of state with the scaling parameters for mixtures and copolymers obtained through combination rules of the characteristic parameters for the pure homopolymers. The lattice-fluid binary parameters for energy and volume were higher than those of block copolymers implying that the copolymers were more compatible due to the chemical links between the blocks. Therefore, a common parameter cannot account for both homopolymer blend and block copolymer phase behaviors based on current theory. As we were able to adjust all data of the mixtures with a single set of lattice-binary parameters and all data of the block copolymers with another single set we can conclude that both parameters did not depend on the composition for this system. This characteristic, plus the fact that the additivity law of specific volumes can be suitably applied for this system, allowed us to model the behavior of the immiscible blend with the SL equation of state. In addition, a discussion on the relationship between lattice-fluid binary parameters and the Flory-Huggins interaction parameter obtained from Leibler's theory is presented.
Fil: Riccardi, Carmen Cristina. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Schroeder, Walter Fabian. Universidad Nacional de Mar del Plata. Facultad de Ingenieria; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Mar del Plata. Instituto de Investigación en Ciencia y Tecnología de Materiales (i); Argentina
Fil: Serrano, Elena. Universidad de Alicante. Departamento de Física; España;
Fil: Mondragon, Iñaki. Universidad del Pais Vasco; España
description The aim of this report is to discuss the method of determination of lattice-fluid binary interaction parameters by comparing well characterized immiscible blends and block copolymers of poly(methyl methacrylate) (PMMA) and poly(ε−caprolactone) (PCL). Experimental pressure-volume-temperature (PVT) data in the liquid state were correlated with the Sanchez-Lacombe (SL) equation of state with the scaling parameters for mixtures and copolymers obtained through combination rules of the characteristic parameters for the pure homopolymers. The lattice-fluid binary parameters for energy and volume were higher than those of block copolymers implying that the copolymers were more compatible due to the chemical links between the blocks. Therefore, a common parameter cannot account for both homopolymer blend and block copolymer phase behaviors based on current theory. As we were able to adjust all data of the mixtures with a single set of lattice-binary parameters and all data of the block copolymers with another single set we can conclude that both parameters did not depend on the composition for this system. This characteristic, plus the fact that the additivity law of specific volumes can be suitably applied for this system, allowed us to model the behavior of the immiscible blend with the SL equation of state. In addition, a discussion on the relationship between lattice-fluid binary parameters and the Flory-Huggins interaction parameter obtained from Leibler's theory is presented.
publishDate 2012
dc.date.none.fl_str_mv 2012-10-16
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/2586
Riccardi, Carmen Cristina; Schroeder, Walter Fabian; Serrano, Elena; Mondragon, Iñaki; Comparison of lattice-fluid binary parameters for mixtures and block copolymers; Taylor & Francis; Journal Of Macromolecular Science-physics; 52; 1; 16-10-2012; 65-83
0022-2348
url http://hdl.handle.net/11336/2586
identifier_str_mv Riccardi, Carmen Cristina; Schroeder, Walter Fabian; Serrano, Elena; Mondragon, Iñaki; Comparison of lattice-fluid binary parameters for mixtures and block copolymers; Taylor & Francis; Journal Of Macromolecular Science-physics; 52; 1; 16-10-2012; 65-83
0022-2348
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1080/00222348.2012.685829
info:eu-repo/semantics/altIdentifier/url/http://www.tandfonline.com/toc/lmsb20/52/1
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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