Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries

Autores
Gonzalez Peña, Yarivith Carolina; Alcaraz Romo, Lorena; Alguacil, Francisco J.; Gonzalez, Jorge Alberto; Barbosa, Lucía Isabel; López, Félix A.
Año de publicación
2022
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The abundant use of lithium-ion batteries (LIBs) in a wide variety of electric devices and vehicles will generate a large number of depleted batteries, which contain several valuable metals, such as Li, Co, Mn, and Ni, present in the structure of the cathode material (LiMO2). The present work investigates the extraction of lithium, as lithium chloride, from spent LIBs by carbochlorination roasting. The starting samples consisted of a mixture of cathode and anode materials from different spent LIBs known as black mass. Calcium chloride was used as a chlorinating agent, and carbon black was used as a reducing agent. The black mass, calcium chloride, and carbon black were mixed in 50:20:30 w/w % proportions. Non-isothermal thermogravimetric tests up to 850 °C and isothermal tests at 350, 500, and 700 °C were carried out in an inert atmosphere. It was observed that the carbochlorination reaction starts at 500 °C. An extraction percentage of 99% was attained through carbochlorination at 700 °C. The characterization results indicate that CaCO3, Ni, and Co and, to a lesser extent, CoO, NiO, and MnO2 are present in the roasted sample after the processes of washing, filtering, and drying.
Fil: Gonzalez Peña, Yarivith Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Alcaraz Romo, Lorena. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; España
Fil: Alguacil, Francisco J.. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; España
Fil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: López, Félix A.. Consejo Superior de Investigaciones Científicas; España. Centro Nacional de Investigaciones Metalúrgicas; España
Materia
CARBOCHLORINATION
CIRCULAR ECONOMY
LICL
RECYCLE
SPENT LITHIUM-ION BATTERIES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/211377
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/211377
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion BatteriesGonzalez Peña, Yarivith CarolinaAlcaraz Romo, LorenaAlguacil, Francisco J.Gonzalez, Jorge AlbertoBarbosa, Lucía IsabelLópez, Félix A.CARBOCHLORINATIONCIRCULAR ECONOMYLICLRECYCLESPENT LITHIUM-ION BATTERIEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1The abundant use of lithium-ion batteries (LIBs) in a wide variety of electric devices and vehicles will generate a large number of depleted batteries, which contain several valuable metals, such as Li, Co, Mn, and Ni, present in the structure of the cathode material (LiMO2). The present work investigates the extraction of lithium, as lithium chloride, from spent LIBs by carbochlorination roasting. The starting samples consisted of a mixture of cathode and anode materials from different spent LIBs known as black mass. Calcium chloride was used as a chlorinating agent, and carbon black was used as a reducing agent. The black mass, calcium chloride, and carbon black were mixed in 50:20:30 w/w % proportions. Non-isothermal thermogravimetric tests up to 850 °C and isothermal tests at 350, 500, and 700 °C were carried out in an inert atmosphere. It was observed that the carbochlorination reaction starts at 500 °C. An extraction percentage of 99% was attained through carbochlorination at 700 °C. The characterization results indicate that CaCO3, Ni, and Co and, to a lesser extent, CoO, NiO, and MnO2 are present in the roasted sample after the processes of washing, filtering, and drying.Fil: Gonzalez Peña, Yarivith Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Alcaraz Romo, Lorena. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; EspañaFil: Alguacil, Francisco J.. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; EspañaFil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; ArgentinaFil: López, Félix A.. Consejo Superior de Investigaciones Científicas; España. Centro Nacional de Investigaciones Metalúrgicas; EspañaMultidisciplinary Digital Publishing Institute2022-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/211377Gonzalez Peña, Yarivith Carolina; Alcaraz Romo, Lorena; Alguacil, Francisco J.; Gonzalez, Jorge Alberto; Barbosa, Lucía Isabel; et al.; Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries; Multidisciplinary Digital Publishing Institute; Batteries; 9; 1; 12-2022; 1-232313-0105CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2313-0105/9/1/12info:eu-repo/semantics/altIdentifier/doi/10.3390/batteries9010012info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:35:59Zoai:ri.conicet.gov.ar:11336/211377instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:35:59.38CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
title Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
spellingShingle Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
Gonzalez Peña, Yarivith Carolina
CARBOCHLORINATION
CIRCULAR ECONOMY
LICL
RECYCLE
SPENT LITHIUM-ION BATTERIES
title_short Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
title_full Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
title_fullStr Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
title_full_unstemmed Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
title_sort Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries
dc.creator.none.fl_str_mv Gonzalez Peña, Yarivith Carolina
Alcaraz Romo, Lorena
Alguacil, Francisco J.
Gonzalez, Jorge Alberto
Barbosa, Lucía Isabel
López, Félix A.
author Gonzalez Peña, Yarivith Carolina
author_facet Gonzalez Peña, Yarivith Carolina
Alcaraz Romo, Lorena
Alguacil, Francisco J.
Gonzalez, Jorge Alberto
Barbosa, Lucía Isabel
López, Félix A.
author_role author
author2 Alcaraz Romo, Lorena
Alguacil, Francisco J.
Gonzalez, Jorge Alberto
Barbosa, Lucía Isabel
López, Félix A.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv CARBOCHLORINATION
CIRCULAR ECONOMY
LICL
RECYCLE
SPENT LITHIUM-ION BATTERIES
topic CARBOCHLORINATION
CIRCULAR ECONOMY
LICL
RECYCLE
SPENT LITHIUM-ION BATTERIES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv The abundant use of lithium-ion batteries (LIBs) in a wide variety of electric devices and vehicles will generate a large number of depleted batteries, which contain several valuable metals, such as Li, Co, Mn, and Ni, present in the structure of the cathode material (LiMO2). The present work investigates the extraction of lithium, as lithium chloride, from spent LIBs by carbochlorination roasting. The starting samples consisted of a mixture of cathode and anode materials from different spent LIBs known as black mass. Calcium chloride was used as a chlorinating agent, and carbon black was used as a reducing agent. The black mass, calcium chloride, and carbon black were mixed in 50:20:30 w/w % proportions. Non-isothermal thermogravimetric tests up to 850 °C and isothermal tests at 350, 500, and 700 °C were carried out in an inert atmosphere. It was observed that the carbochlorination reaction starts at 500 °C. An extraction percentage of 99% was attained through carbochlorination at 700 °C. The characterization results indicate that CaCO3, Ni, and Co and, to a lesser extent, CoO, NiO, and MnO2 are present in the roasted sample after the processes of washing, filtering, and drying.
Fil: Gonzalez Peña, Yarivith Carolina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Alcaraz Romo, Lorena. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; España
Fil: Alguacil, Francisco J.. Centro Nacional de Investigaciones Metalúrgicas; España. Consejo Superior de Investigaciones Científicas; España
Fil: Gonzalez, Jorge Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: Barbosa, Lucía Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Investigaciones en Tecnología Química. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Investigaciones en Tecnología Química; Argentina
Fil: López, Félix A.. Consejo Superior de Investigaciones Científicas; España. Centro Nacional de Investigaciones Metalúrgicas; España
description The abundant use of lithium-ion batteries (LIBs) in a wide variety of electric devices and vehicles will generate a large number of depleted batteries, which contain several valuable metals, such as Li, Co, Mn, and Ni, present in the structure of the cathode material (LiMO2). The present work investigates the extraction of lithium, as lithium chloride, from spent LIBs by carbochlorination roasting. The starting samples consisted of a mixture of cathode and anode materials from different spent LIBs known as black mass. Calcium chloride was used as a chlorinating agent, and carbon black was used as a reducing agent. The black mass, calcium chloride, and carbon black were mixed in 50:20:30 w/w % proportions. Non-isothermal thermogravimetric tests up to 850 °C and isothermal tests at 350, 500, and 700 °C were carried out in an inert atmosphere. It was observed that the carbochlorination reaction starts at 500 °C. An extraction percentage of 99% was attained through carbochlorination at 700 °C. The characterization results indicate that CaCO3, Ni, and Co and, to a lesser extent, CoO, NiO, and MnO2 are present in the roasted sample after the processes of washing, filtering, and drying.
publishDate 2022
dc.date.none.fl_str_mv 2022-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/211377
Gonzalez Peña, Yarivith Carolina; Alcaraz Romo, Lorena; Alguacil, Francisco J.; Gonzalez, Jorge Alberto; Barbosa, Lucía Isabel; et al.; Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries; Multidisciplinary Digital Publishing Institute; Batteries; 9; 1; 12-2022; 1-23
2313-0105
CONICET Digital
CONICET
url http://hdl.handle.net/11336/211377
identifier_str_mv Gonzalez Peña, Yarivith Carolina; Alcaraz Romo, Lorena; Alguacil, Francisco J.; Gonzalez, Jorge Alberto; Barbosa, Lucía Isabel; et al.; Study of the Carbochlorination Process with CaCl2 and Water Leaching for the Extraction of Lithium from Spent Lithium-Ion Batteries; Multidisciplinary Digital Publishing Institute; Batteries; 9; 1; 12-2022; 1-23
2313-0105
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/2313-0105/9/1/12
info:eu-repo/semantics/altIdentifier/doi/10.3390/batteries9010012
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082822981287936
score 13.22299

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