Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals

Autores
Rada Arias, Eduardo Alberto; Bertero, Melisa Paola; Jozami, Emiliano; Feldman, Susana Raquel; Falco, Marisa Guadalupe; Sedran, Ulises Anselmo
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Spartina argentinensis, Panicum prionitis, and Arundo donax are perennial grasses and Geofroea decorticans is a shrub, all of which grow under adverse conditions in the Litoral region in Argentina. The pyrolytic conversion of these biomasses was studied at 550 °C in a fxed bed reactor during 30 min under N2 fow with a 20 °C min−1 heating ramp starting at room temperature. The main products were liquid, two phases (aqueous and oil) being observed with the aqueous phasesbeing the most important in all the cases (yields from 29.2 to 45.7 wt%). The highest yield for an oil phase (18 wt%) was observed with the shrub and the yield of gases and chars were similar in all the cases. By means of sequential vacuum distillation I was possible to selectively separate water, methanol and acetic acid which were present in the aqueous phases, thus increasing the concentration of high value compounds such as ketones, phenols and furans in the residual fraction. The concentration of phenolic compounds in the residual fraction was 60% higher than the initial one in the aqueous phase. The oil phase mainly contained phenols, ketones and acids with high molecular weight. According to these results, these biomasses can be considered as a source of energy, fuels or chemicals, and it is possible to propose a methodology to upgrade the aqueous fractions in pyrolysis liquids.
Fil: Rada Arias, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Jozami, Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; Argentina
Fil: Feldman, Susana Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
PYROLYSIS
PERENNIAL GRASSES
RANGELANDS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/119164
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/119164
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicalsRada Arias, Eduardo AlbertoBertero, Melisa PaolaJozami, EmilianoFeldman, Susana RaquelFalco, Marisa GuadalupeSedran, Ulises AnselmoPYROLYSISPERENNIAL GRASSESRANGELANDShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Spartina argentinensis, Panicum prionitis, and Arundo donax are perennial grasses and Geofroea decorticans is a shrub, all of which grow under adverse conditions in the Litoral region in Argentina. The pyrolytic conversion of these biomasses was studied at 550 °C in a fxed bed reactor during 30 min under N2 fow with a 20 °C min−1 heating ramp starting at room temperature. The main products were liquid, two phases (aqueous and oil) being observed with the aqueous phasesbeing the most important in all the cases (yields from 29.2 to 45.7 wt%). The highest yield for an oil phase (18 wt%) was observed with the shrub and the yield of gases and chars were similar in all the cases. By means of sequential vacuum distillation I was possible to selectively separate water, methanol and acetic acid which were present in the aqueous phases, thus increasing the concentration of high value compounds such as ketones, phenols and furans in the residual fraction. The concentration of phenolic compounds in the residual fraction was 60% higher than the initial one in the aqueous phase. The oil phase mainly contained phenols, ketones and acids with high molecular weight. According to these results, these biomasses can be considered as a source of energy, fuels or chemicals, and it is possible to propose a methodology to upgrade the aqueous fractions in pyrolysis liquids.Fil: Rada Arias, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Jozami, Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; ArgentinaFil: Feldman, Susana Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; ArgentinaFil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaSpringer Nature2019-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/119164Rada Arias, Eduardo Alberto; Bertero, Melisa Paola; Jozami, Emiliano; Feldman, Susana Raquel; Falco, Marisa Guadalupe; et al.; Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals; Springer Nature; SN Applied Sciences; 2; 1; 12-2019; 2-162523-3963CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s42452-019-1911-4info:eu-repo/semantics/altIdentifier/doi/10.1007/s42452-019-1911-4info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:17:34Zoai:ri.conicet.gov.ar:11336/119164instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:17:34.531CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
title Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
spellingShingle Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
Rada Arias, Eduardo Alberto
PYROLYSIS
PERENNIAL GRASSES
RANGELANDS
title_short Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
title_full Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
title_fullStr Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
title_full_unstemmed Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
title_sort Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals
dc.creator.none.fl_str_mv Rada Arias, Eduardo Alberto
Bertero, Melisa Paola
Jozami, Emiliano
Feldman, Susana Raquel
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author Rada Arias, Eduardo Alberto
author_facet Rada Arias, Eduardo Alberto
Bertero, Melisa Paola
Jozami, Emiliano
Feldman, Susana Raquel
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author_role author
author2 Bertero, Melisa Paola
Jozami, Emiliano
Feldman, Susana Raquel
Falco, Marisa Guadalupe
Sedran, Ulises Anselmo
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv PYROLYSIS
PERENNIAL GRASSES
RANGELANDS
topic PYROLYSIS
PERENNIAL GRASSES
RANGELANDS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Spartina argentinensis, Panicum prionitis, and Arundo donax are perennial grasses and Geofroea decorticans is a shrub, all of which grow under adverse conditions in the Litoral region in Argentina. The pyrolytic conversion of these biomasses was studied at 550 °C in a fxed bed reactor during 30 min under N2 fow with a 20 °C min−1 heating ramp starting at room temperature. The main products were liquid, two phases (aqueous and oil) being observed with the aqueous phasesbeing the most important in all the cases (yields from 29.2 to 45.7 wt%). The highest yield for an oil phase (18 wt%) was observed with the shrub and the yield of gases and chars were similar in all the cases. By means of sequential vacuum distillation I was possible to selectively separate water, methanol and acetic acid which were present in the aqueous phases, thus increasing the concentration of high value compounds such as ketones, phenols and furans in the residual fraction. The concentration of phenolic compounds in the residual fraction was 60% higher than the initial one in the aqueous phase. The oil phase mainly contained phenols, ketones and acids with high molecular weight. According to these results, these biomasses can be considered as a source of energy, fuels or chemicals, and it is possible to propose a methodology to upgrade the aqueous fractions in pyrolysis liquids.
Fil: Rada Arias, Eduardo Alberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Bertero, Melisa Paola. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Jozami, Emiliano. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; Argentina
Fil: Feldman, Susana Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Rosario. Instituto de Investigaciones en Ciencias Agrarias de Rosario. Universidad Nacional de Rosario. Facultad de Ciencias Agrarias. Instituto de Investigaciones en Ciencias Agrarias de Rosario; Argentina
Fil: Falco, Marisa Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Sedran, Ulises Anselmo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description Spartina argentinensis, Panicum prionitis, and Arundo donax are perennial grasses and Geofroea decorticans is a shrub, all of which grow under adverse conditions in the Litoral region in Argentina. The pyrolytic conversion of these biomasses was studied at 550 °C in a fxed bed reactor during 30 min under N2 fow with a 20 °C min−1 heating ramp starting at room temperature. The main products were liquid, two phases (aqueous and oil) being observed with the aqueous phasesbeing the most important in all the cases (yields from 29.2 to 45.7 wt%). The highest yield for an oil phase (18 wt%) was observed with the shrub and the yield of gases and chars were similar in all the cases. By means of sequential vacuum distillation I was possible to selectively separate water, methanol and acetic acid which were present in the aqueous phases, thus increasing the concentration of high value compounds such as ketones, phenols and furans in the residual fraction. The concentration of phenolic compounds in the residual fraction was 60% higher than the initial one in the aqueous phase. The oil phase mainly contained phenols, ketones and acids with high molecular weight. According to these results, these biomasses can be considered as a source of energy, fuels or chemicals, and it is possible to propose a methodology to upgrade the aqueous fractions in pyrolysis liquids.
publishDate 2019
dc.date.none.fl_str_mv 2019-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/119164
Rada Arias, Eduardo Alberto; Bertero, Melisa Paola; Jozami, Emiliano; Feldman, Susana Raquel; Falco, Marisa Guadalupe; et al.; Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals; Springer Nature; SN Applied Sciences; 2; 1; 12-2019; 2-16
2523-3963
CONICET Digital
CONICET
url http://hdl.handle.net/11336/119164
identifier_str_mv Rada Arias, Eduardo Alberto; Bertero, Melisa Paola; Jozami, Emiliano; Feldman, Susana Raquel; Falco, Marisa Guadalupe; et al.; Pyrolytic conversion of perennial grasses and woody shrubs to energy and chemicals; Springer Nature; SN Applied Sciences; 2; 1; 12-2019; 2-16
2523-3963
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://link.springer.com/10.1007/s42452-019-1911-4
info:eu-repo/semantics/altIdentifier/doi/10.1007/s42452-019-1911-4
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Springer Nature
publisher.none.fl_str_mv Springer Nature
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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