Autocatalytic O -Formylation of Alcohols Using CO 2

Autores
Gastelu, Gabriela; Savary, David; Hulla, Martin; Ortiz, Daniel; Uranga, Jorge Gustavo; Dyson, Paul J.
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Global drive away from fossil feedstock requires the development of synthetic procedures to enhance the efficiency of CO2 capture and utilization processes using renewable starting materials and catalysts. Here, we report an alternative reaction pathway for the O-formylation of alcohols and bio-alcohols, which affords industrially relevant formate esters. Most products, reported herein, derive their carbon atoms exclusively from renewable sources. The reaction is catalyzed by formic acid, which can also be produced directly from CO2 captured in the reaction. The resulting in situ produced formic acid improves the reaction rate, with each catalyst recycling by simple filtration, product distillation, and reuse of the residual reaction mixture. Hence, CO2 is used as a C1 building block and simultaneously reduced to formic acid, which in turn autocatalytically promotes the reaction.
Fil: Gastelu, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Savary, David. École Polytechnique Fédérale de Lausanne; Suiza
Fil: Hulla, Martin. Karlova Univerzita (cuni);
Fil: Ortiz, Daniel. École Polytechnique Fédérale de Lausanne; Suiza
Fil: Uranga, Jorge Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dyson, Paul J.. École Polytechnique Fédérale de Lausanne; Suiza
Materia
AUTOCATALYSIS
CO2 UTILIZATION
O-FORMYLATION
ORGANOCATALYSIS
REDUCTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226755
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Autocatalytic O -Formylation of Alcohols Using CO 2Gastelu, GabrielaSavary, DavidHulla, MartinOrtiz, DanielUranga, Jorge GustavoDyson, Paul J.AUTOCATALYSISCO2 UTILIZATIONO-FORMYLATIONORGANOCATALYSISREDUCTIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Global drive away from fossil feedstock requires the development of synthetic procedures to enhance the efficiency of CO2 capture and utilization processes using renewable starting materials and catalysts. Here, we report an alternative reaction pathway for the O-formylation of alcohols and bio-alcohols, which affords industrially relevant formate esters. Most products, reported herein, derive their carbon atoms exclusively from renewable sources. The reaction is catalyzed by formic acid, which can also be produced directly from CO2 captured in the reaction. The resulting in situ produced formic acid improves the reaction rate, with each catalyst recycling by simple filtration, product distillation, and reuse of the residual reaction mixture. Hence, CO2 is used as a C1 building block and simultaneously reduced to formic acid, which in turn autocatalytically promotes the reaction.Fil: Gastelu, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Savary, David. École Polytechnique Fédérale de Lausanne; SuizaFil: Hulla, Martin. Karlova Univerzita (cuni);Fil: Ortiz, Daniel. École Polytechnique Fédérale de Lausanne; SuizaFil: Uranga, Jorge Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Dyson, Paul J.. École Polytechnique Fédérale de Lausanne; SuizaAmerican Chemical Society2023-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226755Gastelu, Gabriela; Savary, David; Hulla, Martin; Ortiz, Daniel; Uranga, Jorge Gustavo; et al.; Autocatalytic O -Formylation of Alcohols Using CO 2; American Chemical Society; ACS Catalysis; 13; 4; 2-2023; 2403-24092155-5435CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acscatal.2c06218info:eu-repo/semantics/altIdentifier/doi/10.1021/acscatal.2c06218info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:27:42Zoai:ri.conicet.gov.ar:11336/226755instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:27:43.266CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Autocatalytic O -Formylation of Alcohols Using CO 2
title Autocatalytic O -Formylation of Alcohols Using CO 2
spellingShingle Autocatalytic O -Formylation of Alcohols Using CO 2
Gastelu, Gabriela
AUTOCATALYSIS
CO2 UTILIZATION
O-FORMYLATION
ORGANOCATALYSIS
REDUCTION
title_short Autocatalytic O -Formylation of Alcohols Using CO 2
title_full Autocatalytic O -Formylation of Alcohols Using CO 2
title_fullStr Autocatalytic O -Formylation of Alcohols Using CO 2
title_full_unstemmed Autocatalytic O -Formylation of Alcohols Using CO 2
title_sort Autocatalytic O -Formylation of Alcohols Using CO 2
dc.creator.none.fl_str_mv Gastelu, Gabriela
Savary, David
Hulla, Martin
Ortiz, Daniel
Uranga, Jorge Gustavo
Dyson, Paul J.
author Gastelu, Gabriela
author_facet Gastelu, Gabriela
Savary, David
Hulla, Martin
Ortiz, Daniel
Uranga, Jorge Gustavo
Dyson, Paul J.
author_role author
author2 Savary, David
Hulla, Martin
Ortiz, Daniel
Uranga, Jorge Gustavo
Dyson, Paul J.
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv AUTOCATALYSIS
CO2 UTILIZATION
O-FORMYLATION
ORGANOCATALYSIS
REDUCTION
topic AUTOCATALYSIS
CO2 UTILIZATION
O-FORMYLATION
ORGANOCATALYSIS
REDUCTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Global drive away from fossil feedstock requires the development of synthetic procedures to enhance the efficiency of CO2 capture and utilization processes using renewable starting materials and catalysts. Here, we report an alternative reaction pathway for the O-formylation of alcohols and bio-alcohols, which affords industrially relevant formate esters. Most products, reported herein, derive their carbon atoms exclusively from renewable sources. The reaction is catalyzed by formic acid, which can also be produced directly from CO2 captured in the reaction. The resulting in situ produced formic acid improves the reaction rate, with each catalyst recycling by simple filtration, product distillation, and reuse of the residual reaction mixture. Hence, CO2 is used as a C1 building block and simultaneously reduced to formic acid, which in turn autocatalytically promotes the reaction.
Fil: Gastelu, Gabriela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Savary, David. École Polytechnique Fédérale de Lausanne; Suiza
Fil: Hulla, Martin. Karlova Univerzita (cuni);
Fil: Ortiz, Daniel. École Polytechnique Fédérale de Lausanne; Suiza
Fil: Uranga, Jorge Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Dyson, Paul J.. École Polytechnique Fédérale de Lausanne; Suiza
description Global drive away from fossil feedstock requires the development of synthetic procedures to enhance the efficiency of CO2 capture and utilization processes using renewable starting materials and catalysts. Here, we report an alternative reaction pathway for the O-formylation of alcohols and bio-alcohols, which affords industrially relevant formate esters. Most products, reported herein, derive their carbon atoms exclusively from renewable sources. The reaction is catalyzed by formic acid, which can also be produced directly from CO2 captured in the reaction. The resulting in situ produced formic acid improves the reaction rate, with each catalyst recycling by simple filtration, product distillation, and reuse of the residual reaction mixture. Hence, CO2 is used as a C1 building block and simultaneously reduced to formic acid, which in turn autocatalytically promotes the reaction.
publishDate 2023
dc.date.none.fl_str_mv 2023-02
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226755
Gastelu, Gabriela; Savary, David; Hulla, Martin; Ortiz, Daniel; Uranga, Jorge Gustavo; et al.; Autocatalytic O -Formylation of Alcohols Using CO 2; American Chemical Society; ACS Catalysis; 13; 4; 2-2023; 2403-2409
2155-5435
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226755
identifier_str_mv Gastelu, Gabriela; Savary, David; Hulla, Martin; Ortiz, Daniel; Uranga, Jorge Gustavo; et al.; Autocatalytic O -Formylation of Alcohols Using CO 2; American Chemical Society; ACS Catalysis; 13; 4; 2-2023; 2403-2409
2155-5435
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.acs.org/doi/10.1021/acscatal.2c06218
info:eu-repo/semantics/altIdentifier/doi/10.1021/acscatal.2c06218
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082735294119936
score 13.22299

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