Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones

Autores
Schroeder, Chelsea M.; Politano, Fabrizio; Ohlhorst, Kristiane K.; Leadbeater, Nicholas E.
Año de publicación
2023
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A protocol for the oxidation of alcohols to aldehydes and ketones employing an electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic amount of the radical and the use of a base is not required. It is performed using readily available electrodes in a commercially available electrochemistry apparatus and does not require a reference electrode. The methodology is applicable to a range of structurally and electronically diverse substrates, including the oxidation of primary alcohols to aldehydes rather than the more commonly formed carboxylic acids.
Fil: Schroeder, Chelsea M.. University of Connecticut; Estados Unidos
Fil: Politano, Fabrizio. University of Connecticut; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Ohlhorst, Kristiane K.. University of Connecticut; Estados Unidos
Fil: Leadbeater, Nicholas E.. University of Connecticut; Estados Unidos
Materia
ACETAMIDO-TEMPO
ELECTROCHEMISTRY
ALCOHOL OXIDATION
KETONES
ALDEHYDES
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/226794
Acceder
id CONICETDig_948bad54313f0c6d6731986a1b3ba04a
oai_identifier_str oai:ri.conicet.gov.ar:11336/226794
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketonesSchroeder, Chelsea M.Politano, FabrizioOhlhorst, Kristiane K.Leadbeater, Nicholas E.ACETAMIDO-TEMPOELECTROCHEMISTRYALCOHOL OXIDATIONKETONESALDEHYDEShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A protocol for the oxidation of alcohols to aldehydes and ketones employing an electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic amount of the radical and the use of a base is not required. It is performed using readily available electrodes in a commercially available electrochemistry apparatus and does not require a reference electrode. The methodology is applicable to a range of structurally and electronically diverse substrates, including the oxidation of primary alcohols to aldehydes rather than the more commonly formed carboxylic acids.Fil: Schroeder, Chelsea M.. University of Connecticut; Estados UnidosFil: Politano, Fabrizio. University of Connecticut; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; ArgentinaFil: Ohlhorst, Kristiane K.. University of Connecticut; Estados UnidosFil: Leadbeater, Nicholas E.. University of Connecticut; Estados UnidosRoyal Society of Chemistry2023-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/226794Schroeder, Chelsea M.; Politano, Fabrizio; Ohlhorst, Kristiane K.; Leadbeater, Nicholas E.; Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones; Royal Society of Chemistry; RSC Advances; 13; 36; 8-2023; 25459-254632046-2069CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3RA04608Ginfo:eu-repo/semantics/altIdentifier/doi/10.1039/D3RA04608Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:28:23Zoai:ri.conicet.gov.ar:11336/226794instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:28:23.98CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
title Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
spellingShingle Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
Schroeder, Chelsea M.
ACETAMIDO-TEMPO
ELECTROCHEMISTRY
ALCOHOL OXIDATION
KETONES
ALDEHYDES
title_short Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
title_full Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
title_fullStr Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
title_full_unstemmed Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
title_sort Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones
dc.creator.none.fl_str_mv Schroeder, Chelsea M.
Politano, Fabrizio
Ohlhorst, Kristiane K.
Leadbeater, Nicholas E.
author Schroeder, Chelsea M.
author_facet Schroeder, Chelsea M.
Politano, Fabrizio
Ohlhorst, Kristiane K.
Leadbeater, Nicholas E.
author_role author
author2 Politano, Fabrizio
Ohlhorst, Kristiane K.
Leadbeater, Nicholas E.
author2_role author
author
author
dc.subject.none.fl_str_mv ACETAMIDO-TEMPO
ELECTROCHEMISTRY
ALCOHOL OXIDATION
KETONES
ALDEHYDES
topic ACETAMIDO-TEMPO
ELECTROCHEMISTRY
ALCOHOL OXIDATION
KETONES
ALDEHYDES
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A protocol for the oxidation of alcohols to aldehydes and ketones employing an electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic amount of the radical and the use of a base is not required. It is performed using readily available electrodes in a commercially available electrochemistry apparatus and does not require a reference electrode. The methodology is applicable to a range of structurally and electronically diverse substrates, including the oxidation of primary alcohols to aldehydes rather than the more commonly formed carboxylic acids.
Fil: Schroeder, Chelsea M.. University of Connecticut; Estados Unidos
Fil: Politano, Fabrizio. University of Connecticut; Estados Unidos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Córdoba. Instituto de Investigaciones en Físico-química de Córdoba. Universidad Nacional de Córdoba. Facultad de Ciencias Químicas. Instituto de Investigaciones en Físico-química de Córdoba; Argentina
Fil: Ohlhorst, Kristiane K.. University of Connecticut; Estados Unidos
Fil: Leadbeater, Nicholas E.. University of Connecticut; Estados Unidos
description A protocol for the oxidation of alcohols to aldehydes and ketones employing an electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic amount of the radical and the use of a base is not required. It is performed using readily available electrodes in a commercially available electrochemistry apparatus and does not require a reference electrode. The methodology is applicable to a range of structurally and electronically diverse substrates, including the oxidation of primary alcohols to aldehydes rather than the more commonly formed carboxylic acids.
publishDate 2023
dc.date.none.fl_str_mv 2023-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/226794
Schroeder, Chelsea M.; Politano, Fabrizio; Ohlhorst, Kristiane K.; Leadbeater, Nicholas E.; Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones; Royal Society of Chemistry; RSC Advances; 13; 36; 8-2023; 25459-25463
2046-2069
CONICET Digital
CONICET
url http://hdl.handle.net/11336/226794
identifier_str_mv Schroeder, Chelsea M.; Politano, Fabrizio; Ohlhorst, Kristiane K.; Leadbeater, Nicholas E.; Acetamido-TEMPO mediated electrochemical oxidation of alcohols to aldehydes and ketones; Royal Society of Chemistry; RSC Advances; 13; 36; 8-2023; 25459-25463
2046-2069
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://xlink.rsc.org/?DOI=D3RA04608G
info:eu-repo/semantics/altIdentifier/doi/10.1039/D3RA04608G
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846082747252080640
score 13.22299

Publicaciones similares