Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts
- Autores
- Milt, Viviana Guadalupe; Ivanova, S.; Sanz, O.; Domínguez, M. I.; Corrales, A.; Odriozola, J.A.; Centeno, M.A.
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Metallic supported structured catalysts were obtained by washcoating AluchromYHf monoliths with an Au/TiO2 catalyst. The powder catalyst was synthesized by DAE (direct anionic exchange) method. Using this catalyst, a stable slurry was prepared and used to washcoat the monoliths. TEM and SEM studies revealed that gold nanoparticles in the Au/TiO2 powder catalyst had an average diameter of 3–4 nm, but during the preparation of the structured catalyst, aggregate Au particles of the slurry reached diameters of 9 nm. Before coating, Aluchrom YHf monoliths were thermally treated to generate a homogeneous and well-adhered oxide rough surface layer, mainly composed of -Al2O3 whiskers, which favored the anchoring of the catalyst. The catalytic layer deposited was well attached and contained not only the Au/TiO2 catalyst but also metallic oxides formed from stainless steel components that diffused through the oxide scale. The structural characterization was performed by XRD, XRF, TEM, SEM, GD-OES and SBET.
The catalytic activity of the powder and structured catalysts was tested in the oxidation of the CO
reaction. Catalysts demonstrated to be active at room temperature. After a first activation run, and in spite of their larger gold particle size, the catalytic activities of the structured catalysts overcame those of the powder catalyst. This improvement is probably due to the segregation of the transition metal oxides toward the surface oxide scale.
Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina
Fil: Ivanova, S.. Universidad de Sevilla; España
Fil: Sanz, O.. Universidad de Sevilla; España
Fil: Domínguez, M. I.. Universidad de Sevilla; España
Fil: Corrales, A.. Universidad de Sevilla; España
Fil: Odriozola, J.A.. Universidad de Sevilla; España
Fil: Centeno, M.A.. Universidad de Sevilla; España - Materia
-
Structured Catalysts
Au/Tio2
Co Oxidation
Metallic Catalysts
Aluchrom Yhf - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/21225
Ver los metadatos del registro completo
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Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalystsMilt, Viviana GuadalupeIvanova, S.Sanz, O.Domínguez, M. I.Corrales, A.Odriozola, J.A.Centeno, M.A.Structured CatalystsAu/Tio2Co OxidationMetallic CatalystsAluchrom Yhfhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2Metallic supported structured catalysts were obtained by washcoating AluchromYHf monoliths with an Au/TiO2 catalyst. The powder catalyst was synthesized by DAE (direct anionic exchange) method. Using this catalyst, a stable slurry was prepared and used to washcoat the monoliths. TEM and SEM studies revealed that gold nanoparticles in the Au/TiO2 powder catalyst had an average diameter of 3–4 nm, but during the preparation of the structured catalyst, aggregate Au particles of the slurry reached diameters of 9 nm. Before coating, Aluchrom YHf monoliths were thermally treated to generate a homogeneous and well-adhered oxide rough surface layer, mainly composed of -Al2O3 whiskers, which favored the anchoring of the catalyst. The catalytic layer deposited was well attached and contained not only the Au/TiO2 catalyst but also metallic oxides formed from stainless steel components that diffused through the oxide scale. The structural characterization was performed by XRD, XRF, TEM, SEM, GD-OES and SBET.<br />The catalytic activity of the powder and structured catalysts was tested in the oxidation of the CO<br />reaction. Catalysts demonstrated to be active at room temperature. After a first activation run, and in spite of their larger gold particle size, the catalytic activities of the structured catalysts overcame those of the powder catalyst. This improvement is probably due to the segregation of the transition metal oxides toward the surface oxide scale.Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; ArgentinaFil: Ivanova, S.. Universidad de Sevilla; EspañaFil: Sanz, O.. Universidad de Sevilla; EspañaFil: Domínguez, M. I.. Universidad de Sevilla; EspañaFil: Corrales, A.. Universidad de Sevilla; EspañaFil: Odriozola, J.A.. Universidad de Sevilla; EspañaFil: Centeno, M.A.. Universidad de Sevilla; EspañaElsevier2013-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/21225Milt, Viviana Guadalupe; Ivanova, S.; Sanz, O.; Domínguez, M. I.; Corrales, A.; et al.; Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts; Elsevier; Applied Surface Science; 270; 1-2013; 169-1770169-4332CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2012.12.159info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321300007Xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:11:33Zoai:ri.conicet.gov.ar:11336/21225instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:11:33.433CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
title |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
spellingShingle |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts Milt, Viviana Guadalupe Structured Catalysts Au/Tio2 Co Oxidation Metallic Catalysts Aluchrom Yhf |
title_short |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
title_full |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
title_fullStr |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
title_full_unstemmed |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
title_sort |
Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts |
dc.creator.none.fl_str_mv |
Milt, Viviana Guadalupe Ivanova, S. Sanz, O. Domínguez, M. I. Corrales, A. Odriozola, J.A. Centeno, M.A. |
author |
Milt, Viviana Guadalupe |
author_facet |
Milt, Viviana Guadalupe Ivanova, S. Sanz, O. Domínguez, M. I. Corrales, A. Odriozola, J.A. Centeno, M.A. |
author_role |
author |
author2 |
Ivanova, S. Sanz, O. Domínguez, M. I. Corrales, A. Odriozola, J.A. Centeno, M.A. |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
Structured Catalysts Au/Tio2 Co Oxidation Metallic Catalysts Aluchrom Yhf |
topic |
Structured Catalysts Au/Tio2 Co Oxidation Metallic Catalysts Aluchrom Yhf |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
Metallic supported structured catalysts were obtained by washcoating AluchromYHf monoliths with an Au/TiO2 catalyst. The powder catalyst was synthesized by DAE (direct anionic exchange) method. Using this catalyst, a stable slurry was prepared and used to washcoat the monoliths. TEM and SEM studies revealed that gold nanoparticles in the Au/TiO2 powder catalyst had an average diameter of 3–4 nm, but during the preparation of the structured catalyst, aggregate Au particles of the slurry reached diameters of 9 nm. Before coating, Aluchrom YHf monoliths were thermally treated to generate a homogeneous and well-adhered oxide rough surface layer, mainly composed of -Al2O3 whiskers, which favored the anchoring of the catalyst. The catalytic layer deposited was well attached and contained not only the Au/TiO2 catalyst but also metallic oxides formed from stainless steel components that diffused through the oxide scale. The structural characterization was performed by XRD, XRF, TEM, SEM, GD-OES and SBET.<br />The catalytic activity of the powder and structured catalysts was tested in the oxidation of the CO<br />reaction. Catalysts demonstrated to be active at room temperature. After a first activation run, and in spite of their larger gold particle size, the catalytic activities of the structured catalysts overcame those of the powder catalyst. This improvement is probably due to the segregation of the transition metal oxides toward the surface oxide scale. Fil: Milt, Viviana Guadalupe. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones En Catalisis y Petroquímica "ing. Jose Miguel Parera"; Argentina Fil: Ivanova, S.. Universidad de Sevilla; España Fil: Sanz, O.. Universidad de Sevilla; España Fil: Domínguez, M. I.. Universidad de Sevilla; España Fil: Corrales, A.. Universidad de Sevilla; España Fil: Odriozola, J.A.. Universidad de Sevilla; España Fil: Centeno, M.A.. Universidad de Sevilla; España |
description |
Metallic supported structured catalysts were obtained by washcoating AluchromYHf monoliths with an Au/TiO2 catalyst. The powder catalyst was synthesized by DAE (direct anionic exchange) method. Using this catalyst, a stable slurry was prepared and used to washcoat the monoliths. TEM and SEM studies revealed that gold nanoparticles in the Au/TiO2 powder catalyst had an average diameter of 3–4 nm, but during the preparation of the structured catalyst, aggregate Au particles of the slurry reached diameters of 9 nm. Before coating, Aluchrom YHf monoliths were thermally treated to generate a homogeneous and well-adhered oxide rough surface layer, mainly composed of -Al2O3 whiskers, which favored the anchoring of the catalyst. The catalytic layer deposited was well attached and contained not only the Au/TiO2 catalyst but also metallic oxides formed from stainless steel components that diffused through the oxide scale. The structural characterization was performed by XRD, XRF, TEM, SEM, GD-OES and SBET.<br />The catalytic activity of the powder and structured catalysts was tested in the oxidation of the CO<br />reaction. Catalysts demonstrated to be active at room temperature. After a first activation run, and in spite of their larger gold particle size, the catalytic activities of the structured catalysts overcame those of the powder catalyst. This improvement is probably due to the segregation of the transition metal oxides toward the surface oxide scale. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-01 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/21225 Milt, Viviana Guadalupe; Ivanova, S.; Sanz, O.; Domínguez, M. I.; Corrales, A.; et al.; Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts; Elsevier; Applied Surface Science; 270; 1-2013; 169-177 0169-4332 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/21225 |
identifier_str_mv |
Milt, Viviana Guadalupe; Ivanova, S.; Sanz, O.; Domínguez, M. I.; Corrales, A.; et al.; Au/TiO2 supported on ferritic stainless steel monoliths as CO oxidation catalysts; Elsevier; Applied Surface Science; 270; 1-2013; 169-177 0169-4332 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.apsusc.2012.12.159 info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S016943321300007X |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
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CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844614015729270784 |
score |
13.070432 |