Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour

Autores
Ballarini, Adriana Daniela; de Miguel, Sergio Ruben; Jablonski, Estanislao Lorenzo; Scelza, Osvaldo Antonio; Castro, Alberto Antonio
Año de publicación
2005
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper reports a study about the behaviour of different Pt-based catalysts supported on Al2O3, Na-Al2O 3, K-Al2O3 and ZrO2 in methane reforming with CO2. Results indicate that Pt/Na (0.3 wt%)-Al 2O3 and Pt/ZrO2 catalysts show both a good activity and selectivity with a very high catalytic stability at 1073 K. The Pt/K (0.3 wt%)-Al2O3 catalyst showed a good performance but a slightly lower conversion level than Pt/Na (0.3 wt%)-Al2O 3. On the other hand, the Pt/Al2O3 catalyst displayed an important decrease of the methane conversion through the reaction time at 1073 K and hence, a lower catalytic stability due mainly to the carbon deposition. It can be concluded that either Na or K addition to Pt/Al 2O3 enhances the catalytic stability since they provide basic sites, which favour the dissociation reaction of CO2 into CO and O. The O species can react with the carbon deposited on the Pt, thus cleaning the metallic phase of the doped catalysts.
Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Jablonski, Estanislao Lorenzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
Catalytic Stability
Dry Reforming
Metallic Supported Catalysts
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/78037
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/78037
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviourBallarini, Adriana Danielade Miguel, Sergio RubenJablonski, Estanislao LorenzoScelza, Osvaldo AntonioCastro, Alberto AntonioCatalytic StabilityDry ReformingMetallic Supported Catalystshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2This paper reports a study about the behaviour of different Pt-based catalysts supported on Al2O3, Na-Al2O 3, K-Al2O3 and ZrO2 in methane reforming with CO2. Results indicate that Pt/Na (0.3 wt%)-Al 2O3 and Pt/ZrO2 catalysts show both a good activity and selectivity with a very high catalytic stability at 1073 K. The Pt/K (0.3 wt%)-Al2O3 catalyst showed a good performance but a slightly lower conversion level than Pt/Na (0.3 wt%)-Al2O 3. On the other hand, the Pt/Al2O3 catalyst displayed an important decrease of the methane conversion through the reaction time at 1073 K and hence, a lower catalytic stability due mainly to the carbon deposition. It can be concluded that either Na or K addition to Pt/Al 2O3 enhances the catalytic stability since they provide basic sites, which favour the dissociation reaction of CO2 into CO and O. The O species can react with the carbon deposited on the Pt, thus cleaning the metallic phase of the doped catalysts.Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Jablonski, Estanislao Lorenzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaElsevier Science2005-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78037Ballarini, Adriana Daniela; de Miguel, Sergio Ruben; Jablonski, Estanislao Lorenzo; Scelza, Osvaldo Antonio; Castro, Alberto Antonio; Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour; Elsevier Science; Catalysis Today; 107-108; 10-2005; 481-4860920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2005.07.058info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:30:41Zoai:ri.conicet.gov.ar:11336/78037instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:30:41.911CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
title Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
spellingShingle Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
Ballarini, Adriana Daniela
Catalytic Stability
Dry Reforming
Metallic Supported Catalysts
title_short Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
title_full Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
title_fullStr Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
title_full_unstemmed Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
title_sort Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour
dc.creator.none.fl_str_mv Ballarini, Adriana Daniela
de Miguel, Sergio Ruben
Jablonski, Estanislao Lorenzo
Scelza, Osvaldo Antonio
Castro, Alberto Antonio
author Ballarini, Adriana Daniela
author_facet Ballarini, Adriana Daniela
de Miguel, Sergio Ruben
Jablonski, Estanislao Lorenzo
Scelza, Osvaldo Antonio
Castro, Alberto Antonio
author_role author
author2 de Miguel, Sergio Ruben
Jablonski, Estanislao Lorenzo
Scelza, Osvaldo Antonio
Castro, Alberto Antonio
author2_role author
author
author
author
dc.subject.none.fl_str_mv Catalytic Stability
Dry Reforming
Metallic Supported Catalysts
topic Catalytic Stability
Dry Reforming
Metallic Supported Catalysts
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This paper reports a study about the behaviour of different Pt-based catalysts supported on Al2O3, Na-Al2O 3, K-Al2O3 and ZrO2 in methane reforming with CO2. Results indicate that Pt/Na (0.3 wt%)-Al 2O3 and Pt/ZrO2 catalysts show both a good activity and selectivity with a very high catalytic stability at 1073 K. The Pt/K (0.3 wt%)-Al2O3 catalyst showed a good performance but a slightly lower conversion level than Pt/Na (0.3 wt%)-Al2O 3. On the other hand, the Pt/Al2O3 catalyst displayed an important decrease of the methane conversion through the reaction time at 1073 K and hence, a lower catalytic stability due mainly to the carbon deposition. It can be concluded that either Na or K addition to Pt/Al 2O3 enhances the catalytic stability since they provide basic sites, which favour the dissociation reaction of CO2 into CO and O. The O species can react with the carbon deposited on the Pt, thus cleaning the metallic phase of the doped catalysts.
Fil: Ballarini, Adriana Daniela. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: de Miguel, Sergio Ruben. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Jablonski, Estanislao Lorenzo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Scelza, Osvaldo Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Castro, Alberto Antonio. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description This paper reports a study about the behaviour of different Pt-based catalysts supported on Al2O3, Na-Al2O 3, K-Al2O3 and ZrO2 in methane reforming with CO2. Results indicate that Pt/Na (0.3 wt%)-Al 2O3 and Pt/ZrO2 catalysts show both a good activity and selectivity with a very high catalytic stability at 1073 K. The Pt/K (0.3 wt%)-Al2O3 catalyst showed a good performance but a slightly lower conversion level than Pt/Na (0.3 wt%)-Al2O 3. On the other hand, the Pt/Al2O3 catalyst displayed an important decrease of the methane conversion through the reaction time at 1073 K and hence, a lower catalytic stability due mainly to the carbon deposition. It can be concluded that either Na or K addition to Pt/Al 2O3 enhances the catalytic stability since they provide basic sites, which favour the dissociation reaction of CO2 into CO and O. The O species can react with the carbon deposited on the Pt, thus cleaning the metallic phase of the doped catalysts.
publishDate 2005
dc.date.none.fl_str_mv 2005-10
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/78037
Ballarini, Adriana Daniela; de Miguel, Sergio Ruben; Jablonski, Estanislao Lorenzo; Scelza, Osvaldo Antonio; Castro, Alberto Antonio; Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour; Elsevier Science; Catalysis Today; 107-108; 10-2005; 481-486
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/78037
identifier_str_mv Ballarini, Adriana Daniela; de Miguel, Sergio Ruben; Jablonski, Estanislao Lorenzo; Scelza, Osvaldo Antonio; Castro, Alberto Antonio; Reforming of CH4 with CO2 on Pt-supported catalysts: Effect of the support on the catalytic behaviour; Elsevier Science; Catalysis Today; 107-108; 10-2005; 481-486
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2005.07.058
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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