Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material

Autores
Ayala Claveria, Martin; Carlesi, Carlos; Puig, Julieta; Olguin, Gianni
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Graphene oxide membranes have emerged as cutting-edge materials in desalination and wastewater treatment technologies due to valuable attributes such as ready accessibility, mechanical strength, chemical affinity, high water permeability, and pollutant selectivity. However, a significant challenge arises from the distortion of the nanochannels responsible for water transport due to the hydration of oxidized groups over the graphene oxide nanoplates. This compromises selectivity and alters water transport dynamics. To surmount this drawback, innovative strategies involve the incorporation of additives, or crosslinkers, into the graphene oxide matrix to stabilize these critical nanochannels. This comprehensive review investigates the performance of graphene oxide membranes for desalination and wastewater treatment, where graphene oxide was functionalized through crosslinker integration. A novel classification based on the connector element is considered for relating the crosslinker nature and performance in water treatment, accompanied by a statistical analysis highlighting key factors influencing the performance. It was found that additives based on metallic connectors offer a high likelihood of obtaining high performance while incorporating oxygen-based additives shows the highest performance. Furthermore, the hydrophobic character of the selective graphene oxide layer arises as the key factor in determining the final performance in water depuration.
Fil: Ayala Claveria, Martin. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Carlesi, Carlos. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Olguin, Gianni. Pontificia Universidad Católica de Valparaíso; Chile
Materia
Membrane technology
Graphene oxide
Functionalization
Water treatment
Crosslinker
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/263976
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing materialAyala Claveria, MartinCarlesi, CarlosPuig, JulietaOlguin, GianniMembrane technologyGraphene oxideFunctionalizationWater treatmentCrosslinkerhttps://purl.org/becyt/ford/2.7https://purl.org/becyt/ford/2Graphene oxide membranes have emerged as cutting-edge materials in desalination and wastewater treatment technologies due to valuable attributes such as ready accessibility, mechanical strength, chemical affinity, high water permeability, and pollutant selectivity. However, a significant challenge arises from the distortion of the nanochannels responsible for water transport due to the hydration of oxidized groups over the graphene oxide nanoplates. This compromises selectivity and alters water transport dynamics. To surmount this drawback, innovative strategies involve the incorporation of additives, or crosslinkers, into the graphene oxide matrix to stabilize these critical nanochannels. This comprehensive review investigates the performance of graphene oxide membranes for desalination and wastewater treatment, where graphene oxide was functionalized through crosslinker integration. A novel classification based on the connector element is considered for relating the crosslinker nature and performance in water treatment, accompanied by a statistical analysis highlighting key factors influencing the performance. It was found that additives based on metallic connectors offer a high likelihood of obtaining high performance while incorporating oxygen-based additives shows the highest performance. Furthermore, the hydrophobic character of the selective graphene oxide layer arises as the key factor in determining the final performance in water depuration.Fil: Ayala Claveria, Martin. Pontificia Universidad Católica de Valparaíso; ChileFil: Carlesi, Carlos. Pontificia Universidad Católica de Valparaíso; ChileFil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaFil: Olguin, Gianni. Pontificia Universidad Católica de Valparaíso; ChileElsevier2024-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/263976Ayala Claveria, Martin; Carlesi, Carlos; Puig, Julieta; Olguin, Gianni; Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material; Elsevier; Chemical Engineering Journal Advances; 20; 11-2024; 1-722666-8211CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2666821124001017info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceja.2024.100684info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T14:47:39Zoai:ri.conicet.gov.ar:11336/263976instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 14:47:39.457CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
title Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
spellingShingle Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
Ayala Claveria, Martin
Membrane technology
Graphene oxide
Functionalization
Water treatment
Crosslinker
title_short Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
title_full Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
title_fullStr Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
title_full_unstemmed Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
title_sort Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material
dc.creator.none.fl_str_mv Ayala Claveria, Martin
Carlesi, Carlos
Puig, Julieta
Olguin, Gianni
author Ayala Claveria, Martin
author_facet Ayala Claveria, Martin
Carlesi, Carlos
Puig, Julieta
Olguin, Gianni
author_role author
author2 Carlesi, Carlos
Puig, Julieta
Olguin, Gianni
author2_role author
author
author
dc.subject.none.fl_str_mv Membrane technology
Graphene oxide
Functionalization
Water treatment
Crosslinker
topic Membrane technology
Graphene oxide
Functionalization
Water treatment
Crosslinker
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.7
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Graphene oxide membranes have emerged as cutting-edge materials in desalination and wastewater treatment technologies due to valuable attributes such as ready accessibility, mechanical strength, chemical affinity, high water permeability, and pollutant selectivity. However, a significant challenge arises from the distortion of the nanochannels responsible for water transport due to the hydration of oxidized groups over the graphene oxide nanoplates. This compromises selectivity and alters water transport dynamics. To surmount this drawback, innovative strategies involve the incorporation of additives, or crosslinkers, into the graphene oxide matrix to stabilize these critical nanochannels. This comprehensive review investigates the performance of graphene oxide membranes for desalination and wastewater treatment, where graphene oxide was functionalized through crosslinker integration. A novel classification based on the connector element is considered for relating the crosslinker nature and performance in water treatment, accompanied by a statistical analysis highlighting key factors influencing the performance. It was found that additives based on metallic connectors offer a high likelihood of obtaining high performance while incorporating oxygen-based additives shows the highest performance. Furthermore, the hydrophobic character of the selective graphene oxide layer arises as the key factor in determining the final performance in water depuration.
Fil: Ayala Claveria, Martin. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Carlesi, Carlos. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Puig, Julieta. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Fil: Olguin, Gianni. Pontificia Universidad Católica de Valparaíso; Chile
description Graphene oxide membranes have emerged as cutting-edge materials in desalination and wastewater treatment technologies due to valuable attributes such as ready accessibility, mechanical strength, chemical affinity, high water permeability, and pollutant selectivity. However, a significant challenge arises from the distortion of the nanochannels responsible for water transport due to the hydration of oxidized groups over the graphene oxide nanoplates. This compromises selectivity and alters water transport dynamics. To surmount this drawback, innovative strategies involve the incorporation of additives, or crosslinkers, into the graphene oxide matrix to stabilize these critical nanochannels. This comprehensive review investigates the performance of graphene oxide membranes for desalination and wastewater treatment, where graphene oxide was functionalized through crosslinker integration. A novel classification based on the connector element is considered for relating the crosslinker nature and performance in water treatment, accompanied by a statistical analysis highlighting key factors influencing the performance. It was found that additives based on metallic connectors offer a high likelihood of obtaining high performance while incorporating oxygen-based additives shows the highest performance. Furthermore, the hydrophobic character of the selective graphene oxide layer arises as the key factor in determining the final performance in water depuration.
publishDate 2024
dc.date.none.fl_str_mv 2024-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/263976
Ayala Claveria, Martin; Carlesi, Carlos; Puig, Julieta; Olguin, Gianni; Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material; Elsevier; Chemical Engineering Journal Advances; 20; 11-2024; 1-72
2666-8211
CONICET Digital
CONICET
url http://hdl.handle.net/11336/263976
identifier_str_mv Ayala Claveria, Martin; Carlesi, Carlos; Puig, Julieta; Olguin, Gianni; Effects of the functionalization on the performance of graphene oxide-based membranes in the desalination and wastewater treatment: A new classification of functionalizing material; Elsevier; Chemical Engineering Journal Advances; 20; 11-2024; 1-72
2666-8211
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S2666821124001017
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.ceja.2024.100684
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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