Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents
- Autores
- Sautereau, H.; Pascault, J. P.; Bonnet, A.; Bonnaud, L.; Riccardi, Carmen Cristina
- Año de publicación
- 2002
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- The influence of different factors on the miscibility of diglycidyl ether of bisphenol A (DGEBA)/thermoplastic blends was studied. DGEBA/poly(ether imide) (PEI) blends exhibited upper critical solution temperature behavior. The addition of a trifunctional epoxy [triglycidyl para-amino phenol (TGpAP)] increased the miscibility window. The addition of diamines as hardeners could also increase [4,4′-methylene-bis(3-chloro-2,6-diethylaniline) (MCDEA)] or decrease (4,4′-diaminodiphenylsulfone) the miscibility window. DGEBA/poly(ether sulfone) (PES) blends showed lower critical solution temperature behavior. The addition of TGpAP had an effect similar to that for PEI blends, but the presence of MCDEA as a hardener decreased the miscibility of epoxy/PES blends. The modeling of the cloud-point curves was performed with the Flory-Huggins equation (Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953; p 672) according to the procedure developed by K. Kamide, S. Matsuada, and H. Shirataki (Eur Polym J 1990, 26, 379), with the interaction parameter used as the fitting parameter. A phenomenological model that takes into account the molar mass of DGEBA and the amount of TGpAP is proposed and is found to predict the cloud-point temperature of any TGpAP/DGEBA/PEI blend.
Fil: Sautereau, H.. Centre National de la Recherche Scientifique; Francia
Fil: Pascault, J. P.. Centre National de la Recherche Scientifique; Francia
Fil: Bonnet, A.. Centre National de la Recherche Scientifique; Francia
Fil: Bonnaud, L.. Centre National de la Recherche Scientifique; Francia
Fil: Riccardi, Carmen Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina - Materia
-
Flory-Huggins Equation
Phase Diagrams
Phase Separation
Poly(Ether Imides)
Poly(Ether Sulfones)
Thermoplastic-Modified Epoxies - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/36893
Ver los metadatos del registro completo
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Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solventsSautereau, H.Pascault, J. P.Bonnet, A.Bonnaud, L.Riccardi, Carmen CristinaFlory-Huggins EquationPhase DiagramsPhase SeparationPoly(Ether Imides)Poly(Ether Sulfones)Thermoplastic-Modified Epoxieshttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2The influence of different factors on the miscibility of diglycidyl ether of bisphenol A (DGEBA)/thermoplastic blends was studied. DGEBA/poly(ether imide) (PEI) blends exhibited upper critical solution temperature behavior. The addition of a trifunctional epoxy [triglycidyl para-amino phenol (TGpAP)] increased the miscibility window. The addition of diamines as hardeners could also increase [4,4′-methylene-bis(3-chloro-2,6-diethylaniline) (MCDEA)] or decrease (4,4′-diaminodiphenylsulfone) the miscibility window. DGEBA/poly(ether sulfone) (PES) blends showed lower critical solution temperature behavior. The addition of TGpAP had an effect similar to that for PEI blends, but the presence of MCDEA as a hardener decreased the miscibility of epoxy/PES blends. The modeling of the cloud-point curves was performed with the Flory-Huggins equation (Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953; p 672) according to the procedure developed by K. Kamide, S. Matsuada, and H. Shirataki (Eur Polym J 1990, 26, 379), with the interaction parameter used as the fitting parameter. A phenomenological model that takes into account the molar mass of DGEBA and the amount of TGpAP is proposed and is found to predict the cloud-point temperature of any TGpAP/DGEBA/PEI blend.Fil: Sautereau, H.. Centre National de la Recherche Scientifique; FranciaFil: Pascault, J. P.. Centre National de la Recherche Scientifique; FranciaFil: Bonnet, A.. Centre National de la Recherche Scientifique; FranciaFil: Bonnaud, L.. Centre National de la Recherche Scientifique; FranciaFil: Riccardi, Carmen Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaJohn Wiley & Sons Inc2002-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/mswordapplication/pdfhttp://hdl.handle.net/11336/36893Sautereau, H.; Pascault, J. P.; Bonnet, A.; Bonnaud, L.; Riccardi, Carmen Cristina; Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents; John Wiley & Sons Inc; Journal of Applied Polymer Science; 83; 6; 2-2002; 1385-13960021-8995CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/app.10029info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.10029/fullinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:42:10Zoai:ri.conicet.gov.ar:11336/36893instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:42:10.366CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
title |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
spellingShingle |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents Sautereau, H. Flory-Huggins Equation Phase Diagrams Phase Separation Poly(Ether Imides) Poly(Ether Sulfones) Thermoplastic-Modified Epoxies |
title_short |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
title_full |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
title_fullStr |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
title_full_unstemmed |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
title_sort |
Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents |
dc.creator.none.fl_str_mv |
Sautereau, H. Pascault, J. P. Bonnet, A. Bonnaud, L. Riccardi, Carmen Cristina |
author |
Sautereau, H. |
author_facet |
Sautereau, H. Pascault, J. P. Bonnet, A. Bonnaud, L. Riccardi, Carmen Cristina |
author_role |
author |
author2 |
Pascault, J. P. Bonnet, A. Bonnaud, L. Riccardi, Carmen Cristina |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
Flory-Huggins Equation Phase Diagrams Phase Separation Poly(Ether Imides) Poly(Ether Sulfones) Thermoplastic-Modified Epoxies |
topic |
Flory-Huggins Equation Phase Diagrams Phase Separation Poly(Ether Imides) Poly(Ether Sulfones) Thermoplastic-Modified Epoxies |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.4 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
The influence of different factors on the miscibility of diglycidyl ether of bisphenol A (DGEBA)/thermoplastic blends was studied. DGEBA/poly(ether imide) (PEI) blends exhibited upper critical solution temperature behavior. The addition of a trifunctional epoxy [triglycidyl para-amino phenol (TGpAP)] increased the miscibility window. The addition of diamines as hardeners could also increase [4,4′-methylene-bis(3-chloro-2,6-diethylaniline) (MCDEA)] or decrease (4,4′-diaminodiphenylsulfone) the miscibility window. DGEBA/poly(ether sulfone) (PES) blends showed lower critical solution temperature behavior. The addition of TGpAP had an effect similar to that for PEI blends, but the presence of MCDEA as a hardener decreased the miscibility of epoxy/PES blends. The modeling of the cloud-point curves was performed with the Flory-Huggins equation (Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953; p 672) according to the procedure developed by K. Kamide, S. Matsuada, and H. Shirataki (Eur Polym J 1990, 26, 379), with the interaction parameter used as the fitting parameter. A phenomenological model that takes into account the molar mass of DGEBA and the amount of TGpAP is proposed and is found to predict the cloud-point temperature of any TGpAP/DGEBA/PEI blend. Fil: Sautereau, H.. Centre National de la Recherche Scientifique; Francia Fil: Pascault, J. P.. Centre National de la Recherche Scientifique; Francia Fil: Bonnet, A.. Centre National de la Recherche Scientifique; Francia Fil: Bonnaud, L.. Centre National de la Recherche Scientifique; Francia Fil: Riccardi, Carmen Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina |
description |
The influence of different factors on the miscibility of diglycidyl ether of bisphenol A (DGEBA)/thermoplastic blends was studied. DGEBA/poly(ether imide) (PEI) blends exhibited upper critical solution temperature behavior. The addition of a trifunctional epoxy [triglycidyl para-amino phenol (TGpAP)] increased the miscibility window. The addition of diamines as hardeners could also increase [4,4′-methylene-bis(3-chloro-2,6-diethylaniline) (MCDEA)] or decrease (4,4′-diaminodiphenylsulfone) the miscibility window. DGEBA/poly(ether sulfone) (PES) blends showed lower critical solution temperature behavior. The addition of TGpAP had an effect similar to that for PEI blends, but the presence of MCDEA as a hardener decreased the miscibility of epoxy/PES blends. The modeling of the cloud-point curves was performed with the Flory-Huggins equation (Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953; p 672) according to the procedure developed by K. Kamide, S. Matsuada, and H. Shirataki (Eur Polym J 1990, 26, 379), with the interaction parameter used as the fitting parameter. A phenomenological model that takes into account the molar mass of DGEBA and the amount of TGpAP is proposed and is found to predict the cloud-point temperature of any TGpAP/DGEBA/PEI blend. |
publishDate |
2002 |
dc.date.none.fl_str_mv |
2002-02 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/36893 Sautereau, H.; Pascault, J. P.; Bonnet, A.; Bonnaud, L.; Riccardi, Carmen Cristina; Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents; John Wiley & Sons Inc; Journal of Applied Polymer Science; 83; 6; 2-2002; 1385-1396 0021-8995 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/36893 |
identifier_str_mv |
Sautereau, H.; Pascault, J. P.; Bonnet, A.; Bonnaud, L.; Riccardi, Carmen Cristina; Different parameters controlling the initial solubility of two thermoplastics in epoxy reactive solvents; John Wiley & Sons Inc; Journal of Applied Polymer Science; 83; 6; 2-2002; 1385-1396 0021-8995 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/doi/10.1002/app.10029 info:eu-repo/semantics/altIdentifier/url/http://onlinelibrary.wiley.com/doi/10.1002/app.10029/full |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/msword application/pdf |
dc.publisher.none.fl_str_mv |
John Wiley & Sons Inc |
publisher.none.fl_str_mv |
John Wiley & Sons Inc |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613329289478144 |
score |
13.070432 |