Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy

Autores
Constantin, François; Fenouillot, Françoise; Pascault, Jean-Pierre; Williams, Roberto Juan Jose
Año de publicación
2004
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
A thermoplastic poly(hydroxyl‐amino ether) polymer (BLOX) was blended with a diglycidyl ether of bisphenol A monomer (DGEBA). This system may be used as a crosslinkable thermoplastic. It means that it may be processed in an extruder like a classic thermoplastic, and cured by etherification reactions initiated by tertiary amine groups of the BLOX in a second step, to produce a material with good mechanical properties. In order to understand and quantify the etherification reactions occurring at high temperature (135 °C), between epoxy groups of the diepoxy and hydroxyl groups of the thermoplastic, a model system was studied based on DGEBA in excess and ethanolamine. In the model system the rate of the etherification reaction was well described by a second‐order kinetic equation. The specific rate constants and the epoxy conversion at the gel were related to the polarity of the reactive medium. The polyetherification occurring in the DGEBA‐BLOX system could also be fitted with a second‐order kinetics. A significant increase in the reaction rate was observed when using high BLOX concentrations.
Fil: Constantin, François. Centre National de la Recherche Scientifique; Francia
Fil: Fenouillot, Françoise. Centre National de la Recherche Scientifique; Francia
Fil: Pascault, Jean-Pierre. Centre National de la Recherche Scientifique; Francia
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
Materia
BLENDS
EPOXY ETHERIFICATION
POLY(HYDROXYL-AMINO ETHER)
POST-CROSSLINKABLE THERMOPLASTIC
THERMOSETS
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/96405
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a DiepoxyConstantin, FrançoisFenouillot, FrançoisePascault, Jean-PierreWilliams, Roberto Juan JoseBLENDSEPOXY ETHERIFICATIONPOLY(HYDROXYL-AMINO ETHER)POST-CROSSLINKABLE THERMOPLASTICTHERMOSETShttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1A thermoplastic poly(hydroxyl‐amino ether) polymer (BLOX) was blended with a diglycidyl ether of bisphenol A monomer (DGEBA). This system may be used as a crosslinkable thermoplastic. It means that it may be processed in an extruder like a classic thermoplastic, and cured by etherification reactions initiated by tertiary amine groups of the BLOX in a second step, to produce a material with good mechanical properties. In order to understand and quantify the etherification reactions occurring at high temperature (135 °C), between epoxy groups of the diepoxy and hydroxyl groups of the thermoplastic, a model system was studied based on DGEBA in excess and ethanolamine. In the model system the rate of the etherification reaction was well described by a second‐order kinetic equation. The specific rate constants and the epoxy conversion at the gel were related to the polarity of the reactive medium. The polyetherification occurring in the DGEBA‐BLOX system could also be fitted with a second‐order kinetics. A significant increase in the reaction rate was observed when using high BLOX concentrations.Fil: Constantin, François. Centre National de la Recherche Scientifique; FranciaFil: Fenouillot, Françoise. Centre National de la Recherche Scientifique; FranciaFil: Pascault, Jean-Pierre. Centre National de la Recherche Scientifique; FranciaFil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; ArgentinaWiley VCH Verlag2004-11info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/96405Constantin, François; Fenouillot, Françoise; Pascault, Jean-Pierre; Williams, Roberto Juan Jose; Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy; Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 289; 11; 11-2004; 1027-10321438-7492CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1002/mame.200400151info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mame.200400151info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:16:01Zoai:ri.conicet.gov.ar:11336/96405instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:16:01.669CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
title Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
spellingShingle Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
Constantin, François
BLENDS
EPOXY ETHERIFICATION
POLY(HYDROXYL-AMINO ETHER)
POST-CROSSLINKABLE THERMOPLASTIC
THERMOSETS
title_short Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
title_full Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
title_fullStr Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
title_full_unstemmed Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
title_sort Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy
dc.creator.none.fl_str_mv Constantin, François
Fenouillot, Françoise
Pascault, Jean-Pierre
Williams, Roberto Juan Jose
author Constantin, François
author_facet Constantin, François
Fenouillot, Françoise
Pascault, Jean-Pierre
Williams, Roberto Juan Jose
author_role author
author2 Fenouillot, Françoise
Pascault, Jean-Pierre
Williams, Roberto Juan Jose
author2_role author
author
author
dc.subject.none.fl_str_mv BLENDS
EPOXY ETHERIFICATION
POLY(HYDROXYL-AMINO ETHER)
POST-CROSSLINKABLE THERMOPLASTIC
THERMOSETS
topic BLENDS
EPOXY ETHERIFICATION
POLY(HYDROXYL-AMINO ETHER)
POST-CROSSLINKABLE THERMOPLASTIC
THERMOSETS
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv A thermoplastic poly(hydroxyl‐amino ether) polymer (BLOX) was blended with a diglycidyl ether of bisphenol A monomer (DGEBA). This system may be used as a crosslinkable thermoplastic. It means that it may be processed in an extruder like a classic thermoplastic, and cured by etherification reactions initiated by tertiary amine groups of the BLOX in a second step, to produce a material with good mechanical properties. In order to understand and quantify the etherification reactions occurring at high temperature (135 °C), between epoxy groups of the diepoxy and hydroxyl groups of the thermoplastic, a model system was studied based on DGEBA in excess and ethanolamine. In the model system the rate of the etherification reaction was well described by a second‐order kinetic equation. The specific rate constants and the epoxy conversion at the gel were related to the polarity of the reactive medium. The polyetherification occurring in the DGEBA‐BLOX system could also be fitted with a second‐order kinetics. A significant increase in the reaction rate was observed when using high BLOX concentrations.
Fil: Constantin, François. Centre National de la Recherche Scientifique; Francia
Fil: Fenouillot, Françoise. Centre National de la Recherche Scientifique; Francia
Fil: Pascault, Jean-Pierre. Centre National de la Recherche Scientifique; Francia
Fil: Williams, Roberto Juan Jose. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mar del Plata. Instituto de Investigaciones en Ciencia y Tecnología de Materiales. Universidad Nacional de Mar del Plata. Facultad de Ingeniería. Instituto de Investigaciones en Ciencia y Tecnología de Materiales; Argentina
description A thermoplastic poly(hydroxyl‐amino ether) polymer (BLOX) was blended with a diglycidyl ether of bisphenol A monomer (DGEBA). This system may be used as a crosslinkable thermoplastic. It means that it may be processed in an extruder like a classic thermoplastic, and cured by etherification reactions initiated by tertiary amine groups of the BLOX in a second step, to produce a material with good mechanical properties. In order to understand and quantify the etherification reactions occurring at high temperature (135 °C), between epoxy groups of the diepoxy and hydroxyl groups of the thermoplastic, a model system was studied based on DGEBA in excess and ethanolamine. In the model system the rate of the etherification reaction was well described by a second‐order kinetic equation. The specific rate constants and the epoxy conversion at the gel were related to the polarity of the reactive medium. The polyetherification occurring in the DGEBA‐BLOX system could also be fitted with a second‐order kinetics. A significant increase in the reaction rate was observed when using high BLOX concentrations.
publishDate 2004
dc.date.none.fl_str_mv 2004-11
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/96405
Constantin, François; Fenouillot, Françoise; Pascault, Jean-Pierre; Williams, Roberto Juan Jose; Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy; Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 289; 11; 11-2004; 1027-1032
1438-7492
CONICET Digital
CONICET
url http://hdl.handle.net/11336/96405
identifier_str_mv Constantin, François; Fenouillot, Françoise; Pascault, Jean-Pierre; Williams, Roberto Juan Jose; Post‐Crosslinkable Blends: Reactions Between a Linear Poly(hydroxyl‐amino ether) and a Diepoxy; Wiley VCH Verlag; Macromolecular Materials and Engineering (print); 289; 11; 11-2004; 1027-1032
1438-7492
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1002/mame.200400151
info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/mame.200400151
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley VCH Verlag
publisher.none.fl_str_mv Wiley VCH Verlag
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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