Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.

Autores
Diniz, Paulo Henrique Gonçalves Dias; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de; Fernández Band, Beatriz Susana
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.
Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Materia
Flow Batch
Glycerol
Online Extraction
Sonoluminescence
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/5417
Acceder
id CONICETDig_8e01cc378bf4eefd04de7bedce4c2353
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network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.Diniz, Paulo Henrique Gonçalves DiasPistonesi, Marcelo FabianAraújo, Mario César Ugulino deFernández Band, Beatriz SusanaFlow BatchGlycerolOnline ExtractionSonoluminescencehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; BrasilFil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaFil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; BrasilFil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaElsevier2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5417Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-420039-9140enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914013002919info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2013.04.009info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:05:11Zoai:ri.conicet.gov.ar:11336/5417instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:05:11.447CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
title Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
spellingShingle Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
Diniz, Paulo Henrique Gonçalves Dias
Flow Batch
Glycerol
Online Extraction
Sonoluminescence
title_short Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
title_full Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
title_fullStr Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
title_full_unstemmed Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
title_sort Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
dc.creator.none.fl_str_mv Diniz, Paulo Henrique Gonçalves Dias
Pistonesi, Marcelo Fabian
Araújo, Mario César Ugulino de
Fernández Band, Beatriz Susana
author Diniz, Paulo Henrique Gonçalves Dias
author_facet Diniz, Paulo Henrique Gonçalves Dias
Pistonesi, Marcelo Fabian
Araújo, Mario César Ugulino de
Fernández Band, Beatriz Susana
author_role author
author2 Pistonesi, Marcelo Fabian
Araújo, Mario César Ugulino de
Fernández Band, Beatriz Susana
author2_role author
author
author
dc.subject.none.fl_str_mv Flow Batch
Glycerol
Online Extraction
Sonoluminescence
topic Flow Batch
Glycerol
Online Extraction
Sonoluminescence
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.
Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
description This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.
publishDate 2013
dc.date.none.fl_str_mv 2013-04
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/5417
Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-42
0039-9140
url http://hdl.handle.net/11336/5417
identifier_str_mv Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-42
0039-9140
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914013002919
info:eu-repo/semantics/altIdentifier/doi/
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2013.04.009
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1846781325132955648
score 12.982451

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