Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.
- Autores
- Diniz, Paulo Henrique Gonçalves Dias; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de; Fernández Band, Beatriz Susana
- Año de publicación
- 2013
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.
Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina
Fil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; Brasil
Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina - Materia
-
Flow Batch
Glycerol
Online Extraction
Sonoluminescence - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/5417
Ver los metadatos del registro completo
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Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.Diniz, Paulo Henrique Gonçalves DiasPistonesi, Marcelo FabianAraújo, Mario César Ugulino deFernández Band, Beatriz SusanaFlow BatchGlycerolOnline ExtractionSonoluminescencehttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level.Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; BrasilFil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaFil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; BrasilFil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; ArgentinaElsevier2013-04info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/5417Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-420039-9140enginfo:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914013002919info:eu-repo/semantics/altIdentifier/doi/info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2013.04.009info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:37:03Zoai:ri.conicet.gov.ar:11336/5417instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:37:03.562CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
title |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
spellingShingle |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. Diniz, Paulo Henrique Gonçalves Dias Flow Batch Glycerol Online Extraction Sonoluminescence |
title_short |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
title_full |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
title_fullStr |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
title_full_unstemmed |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
title_sort |
Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples. |
dc.creator.none.fl_str_mv |
Diniz, Paulo Henrique Gonçalves Dias Pistonesi, Marcelo Fabian Araújo, Mario César Ugulino de Fernández Band, Beatriz Susana |
author |
Diniz, Paulo Henrique Gonçalves Dias |
author_facet |
Diniz, Paulo Henrique Gonçalves Dias Pistonesi, Marcelo Fabian Araújo, Mario César Ugulino de Fernández Band, Beatriz Susana |
author_role |
author |
author2 |
Pistonesi, Marcelo Fabian Araújo, Mario César Ugulino de Fernández Band, Beatriz Susana |
author2_role |
author author author |
dc.subject.none.fl_str_mv |
Flow Batch Glycerol Online Extraction Sonoluminescence |
topic |
Flow Batch Glycerol Online Extraction Sonoluminescence |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level. Fil: Diniz, Paulo Henrique Gonçalves Dias. Universidade Federal da Paraíba. Departamento de Química; Brasil Fil: Pistonesi, Marcelo Fabian. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina Fil: Araújo, Mario César Ugulino de. Universidade Federal da Paraíba. Departamento de Química; Brasil Fil: Fernández Band, Beatriz Susana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Bahía Blanca. Instituto de Química del Sur; Argentina. Universidad Nacional del Sur; Argentina |
description |
This paper proposes a flow-batch methodology for the determination of free glycerol in biodiesel that is notably eco-friendly, since non-chemical reagents are used. Deionized water (the solvent) was used alone for glycerol (sample) extractions from the biodiesel. The same water was used to generate water-cavitation sonoluminescence signals, which were modulated by the quenching effect associated with the amount of extracted glycerol. The necessarily reproducible signal generation was achieved by using a simple and inexpensive piezoelectric device. A linear response was observed for glycerol within the 0.001–100 mg/L range, equivalent to 0.004–400 mg/kg free glycerol in biodiesel. The lowest measurable concentration of free glycerol was estimated at 1.0 µg/L. The selectivity of the proposed method was confirmed by comparing the shape and retention of both real and calibration samples to standard solution chromatograms, presenting no peaks other than glycerol. All samples (after extraction) are greatly diluted; this minimizes (toward non-detectability) potential interference effects. The methodology was successfully applied to biodiesel analysis at a high sampling rate, with neither reagent nor solvent (other than water), and with minimum waste generation. The results agreed with the reference method (ASTM D6584-07), at a 95% confidence level. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-04 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/5417 Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-42 0039-9140 |
url |
http://hdl.handle.net/11336/5417 |
identifier_str_mv |
Diniz, Paulo Henrique Gonçalves Dias ; Pistonesi, Marcelo Fabian; Araújo, Mario César Ugulino de ; Fernández Band, Beatriz Susana; Eco-friendly sonoluminescent determination of free glycerol in biodiesel samples.; Elsevier; Talanta; 114; 4-2013; 38-42 0039-9140 |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://www.sciencedirect.com/science/article/pii/S0039914013002919 info:eu-repo/semantics/altIdentifier/doi/ info:eu-repo/semantics/altIdentifier/doi/10.1016/j.talanta.2013.04.009 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier |
publisher.none.fl_str_mv |
Elsevier |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613165545947136 |
score |
13.070432 |