Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries

Autores
de la Llave, Ezequiel Pablo; Nayak, Prasant Kumar; Levi, Elena; Tirupathi Rao, Penki; Bublil, Shaul; Hartmann, Pascal; Chesneau, Frederick Francois; Greenstein, Miri; Nazar, Linda F.; Aurbach, Doron
Año de publicación
2017
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Na0.6[Li0.2Ni0.2Mn0.6]O2 is synthesized by a self-combustion reaction (SCR) and studied for the first time as a cathode material for Na-ion batteries. The Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode presents remarkable high rate capability and prolonged stability under galvanostatic cycling. A detailed analysis of X-ray diffraction (XRD) patterns at various states of cycling reveals that the excellent structural stability is due to a primarily solid-solution sodiation/desodiation mechanism of the material during cycling. Moreover, a meaningful comparison with Na0.6MnO2 and Na0.6[Li0.2Mn0.8]O2 reveals that the Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode achieves a very high working-average voltage that outperforms most of the lithium-doped manganese-oxide cathodes published to date.
Fil: de la Llave, Ezequiel Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Bar-Ilan University; Israel
Fil: Nayak, Prasant Kumar. Bar-Ilan University; Israel
Fil: Levi, Elena. Bar-Ilan University; Israel
Fil: Tirupathi Rao, Penki. Bar-Ilan University; Israel
Fil: Bublil, Shaul. Bar-Ilan University; Israel
Fil: Hartmann, Pascal. Basf; Alemania
Fil: Chesneau, Frederick Francois. Basf; Alemania
Fil: Greenstein, Miri. Bar-Ilan University; Israel
Fil: Nazar, Linda F.. University of Waterloo; Canadá
Fil: Aurbach, Doron. Bar-Ilan University; Israel
Materia
Na-Ion Batteries
Self-Combustion
Cathode
Electrochemistry
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/65766
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/65766
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteriesde la Llave, Ezequiel PabloNayak, Prasant KumarLevi, ElenaTirupathi Rao, PenkiBublil, ShaulHartmann, PascalChesneau, Frederick FrancoisGreenstein, MiriNazar, Linda F.Aurbach, DoronNa-Ion BatteriesSelf-CombustionCathodeElectrochemistryhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Na0.6[Li0.2Ni0.2Mn0.6]O2 is synthesized by a self-combustion reaction (SCR) and studied for the first time as a cathode material for Na-ion batteries. The Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode presents remarkable high rate capability and prolonged stability under galvanostatic cycling. A detailed analysis of X-ray diffraction (XRD) patterns at various states of cycling reveals that the excellent structural stability is due to a primarily solid-solution sodiation/desodiation mechanism of the material during cycling. Moreover, a meaningful comparison with Na0.6MnO2 and Na0.6[Li0.2Mn0.8]O2 reveals that the Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode achieves a very high working-average voltage that outperforms most of the lithium-doped manganese-oxide cathodes published to date.Fil: de la Llave, Ezequiel Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Bar-Ilan University; IsraelFil: Nayak, Prasant Kumar. Bar-Ilan University; IsraelFil: Levi, Elena. Bar-Ilan University; IsraelFil: Tirupathi Rao, Penki. Bar-Ilan University; IsraelFil: Bublil, Shaul. Bar-Ilan University; IsraelFil: Hartmann, Pascal. Basf; AlemaniaFil: Chesneau, Frederick Francois. Basf; AlemaniaFil: Greenstein, Miri. Bar-Ilan University; IsraelFil: Nazar, Linda F.. University of Waterloo; CanadáFil: Aurbach, Doron. Bar-Ilan University; IsraelRoyal Society of Chemistry2017-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/65766de la Llave, Ezequiel Pablo; Nayak, Prasant Kumar; Levi, Elena; Tirupathi Rao, Penki; Bublil, Shaul; et al.; Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 12; 12-2017; 5858-58642050-7496CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/-/content/articlelanding/2017/ta/c6ta10577g/#!divAbstractinfo:eu-repo/semantics/altIdentifier/doi/10.1039/C6TA10577Ginfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:12:50Zoai:ri.conicet.gov.ar:11336/65766instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:12:50.623CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
title Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
spellingShingle Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
de la Llave, Ezequiel Pablo
Na-Ion Batteries
Self-Combustion
Cathode
Electrochemistry
title_short Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
title_full Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
title_fullStr Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
title_full_unstemmed Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
title_sort Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries
dc.creator.none.fl_str_mv de la Llave, Ezequiel Pablo
Nayak, Prasant Kumar
Levi, Elena
Tirupathi Rao, Penki
Bublil, Shaul
Hartmann, Pascal
Chesneau, Frederick Francois
Greenstein, Miri
Nazar, Linda F.
Aurbach, Doron
author de la Llave, Ezequiel Pablo
author_facet de la Llave, Ezequiel Pablo
Nayak, Prasant Kumar
Levi, Elena
Tirupathi Rao, Penki
Bublil, Shaul
Hartmann, Pascal
Chesneau, Frederick Francois
Greenstein, Miri
Nazar, Linda F.
Aurbach, Doron
author_role author
author2 Nayak, Prasant Kumar
Levi, Elena
Tirupathi Rao, Penki
Bublil, Shaul
Hartmann, Pascal
Chesneau, Frederick Francois
Greenstein, Miri
Nazar, Linda F.
Aurbach, Doron
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Na-Ion Batteries
Self-Combustion
Cathode
Electrochemistry
topic Na-Ion Batteries
Self-Combustion
Cathode
Electrochemistry
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Na0.6[Li0.2Ni0.2Mn0.6]O2 is synthesized by a self-combustion reaction (SCR) and studied for the first time as a cathode material for Na-ion batteries. The Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode presents remarkable high rate capability and prolonged stability under galvanostatic cycling. A detailed analysis of X-ray diffraction (XRD) patterns at various states of cycling reveals that the excellent structural stability is due to a primarily solid-solution sodiation/desodiation mechanism of the material during cycling. Moreover, a meaningful comparison with Na0.6MnO2 and Na0.6[Li0.2Mn0.8]O2 reveals that the Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode achieves a very high working-average voltage that outperforms most of the lithium-doped manganese-oxide cathodes published to date.
Fil: de la Llave, Ezequiel Pablo. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria. Instituto de Química, Física de los Materiales, Medioambiente y Energía. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales. Instituto de Química, Física de los Materiales, Medioambiente y Energía; Argentina. Bar-Ilan University; Israel
Fil: Nayak, Prasant Kumar. Bar-Ilan University; Israel
Fil: Levi, Elena. Bar-Ilan University; Israel
Fil: Tirupathi Rao, Penki. Bar-Ilan University; Israel
Fil: Bublil, Shaul. Bar-Ilan University; Israel
Fil: Hartmann, Pascal. Basf; Alemania
Fil: Chesneau, Frederick Francois. Basf; Alemania
Fil: Greenstein, Miri. Bar-Ilan University; Israel
Fil: Nazar, Linda F.. University of Waterloo; Canadá
Fil: Aurbach, Doron. Bar-Ilan University; Israel
description Na0.6[Li0.2Ni0.2Mn0.6]O2 is synthesized by a self-combustion reaction (SCR) and studied for the first time as a cathode material for Na-ion batteries. The Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode presents remarkable high rate capability and prolonged stability under galvanostatic cycling. A detailed analysis of X-ray diffraction (XRD) patterns at various states of cycling reveals that the excellent structural stability is due to a primarily solid-solution sodiation/desodiation mechanism of the material during cycling. Moreover, a meaningful comparison with Na0.6MnO2 and Na0.6[Li0.2Mn0.8]O2 reveals that the Na0.6[Li0.2Ni0.2Mn0.6]O2 cathode achieves a very high working-average voltage that outperforms most of the lithium-doped manganese-oxide cathodes published to date.
publishDate 2017
dc.date.none.fl_str_mv 2017-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/65766
de la Llave, Ezequiel Pablo; Nayak, Prasant Kumar; Levi, Elena; Tirupathi Rao, Penki; Bublil, Shaul; et al.; Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 12; 12-2017; 5858-5864
2050-7496
CONICET Digital
CONICET
url http://hdl.handle.net/11336/65766
identifier_str_mv de la Llave, Ezequiel Pablo; Nayak, Prasant Kumar; Levi, Elena; Tirupathi Rao, Penki; Bublil, Shaul; et al.; Electrochemical performance of Na0.6[Li0.2Ni0.2Mn0.6]O2 cathodes with high-working average voltage for Na-ion batteries; Royal Society of Chemistry; Journal of Materials Chemistry A; 5; 12; 12-2017; 5858-5864
2050-7496
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://pubs.rsc.org/-/content/articlelanding/2017/ta/c6ta10577g/#!divAbstract
info:eu-repo/semantics/altIdentifier/doi/10.1039/C6TA10577G
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1842980673073184768
score 12.993085

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