Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production

Autores
Prado Gárate, Agatha Estefanía Raquel; Felissia, Fernando Esteban; Area, Maria Cristina; Suirezs, Teresa Maria; Vallejos, María Evangelina
Año de publicación
2024
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Non-traditional lignocellulosic materials are a significant resource for producing high-value products, including nanocellulose. This work studied the nanocellulose obtention from chemical pulps of the two fast-growing bamboo species, Guadua trinii, and Guadua angustifolia. Chemical pulps were produced by soda-anthraquinone (S) pulping from both autohydrolysis-pretreated (H) and unpretreated bamboo chips. Autohydrolysis-pretreated (SHP) and unpretreated soda-anthraquinone (AQ) (SP) pulps were characterized by yield, Kappa number, alpha, beta, and gamma cellulose, degree of polymerization, water retention value, and crystallinity. The nanocellulose was produced by a sequential chemical oxidation treatment (2,2,6,6-tetramethylpiperidine-1-oxyl, TEMPO reagent) and mechanical nanofibrillation. Nanocellulose was characterized by carboxylic group content and viscosity. The results revealed that autohydrolysis pretreatment resulted in a higher hemicelluloses extraction in G. angustifolia. In contrast, the pulping yield of unpretreated samples was higher for G. trinii, and the soda-AQ pulps from this species exhibited better delignification than the autohydrolysis-pretreated pulps. The crystallinity index values of the obtained pulps were high (>80%), and the alpha-cellulose contents were similar. The viscosities of the aqueous nanocellulose suspensions were higher for the nanocellulose solutions obtained from the unpretreated soda-AQ pulps. Besides, nanocellulose from G. trinii unpretreated soda-AQ pulps had a higher rate of carboxylic groups. The results of this work are significant in assessing the potential of both bamboo species as a source of high-value products within the biorefinery framework because the viscosities of the aqueous nanocellulose suspensions depend on the size and shape of nanofibrils. It has significant importance for industrial unit operations and potential applications.
Fil: Prado Gárate, Agatha Estefanía Raquel. Universidad Nacional Agraria La Molina; Perú. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Suirezs, Teresa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Materia
NATURAL FIBER
GUADUA ANGUSTIFOLIA
GUADUA TRINII
SODA-ANTHRAQUINONE PULP
NANOCELLULOSE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/263033
Acceder
id CONICETDig_8d23865dcde0a2db80e91b548ad99486
oai_identifier_str oai:ri.conicet.gov.ar:11336/263033
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose ProductionPrado Gárate, Agatha Estefanía RaquelFelissia, Fernando EstebanArea, Maria CristinaSuirezs, Teresa MariaVallejos, María EvangelinaNATURAL FIBERGUADUA ANGUSTIFOLIAGUADUA TRINIISODA-ANTHRAQUINONE PULPNANOCELLULOSEhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Non-traditional lignocellulosic materials are a significant resource for producing high-value products, including nanocellulose. This work studied the nanocellulose obtention from chemical pulps of the two fast-growing bamboo species, Guadua trinii, and Guadua angustifolia. Chemical pulps were produced by soda-anthraquinone (S) pulping from both autohydrolysis-pretreated (H) and unpretreated bamboo chips. Autohydrolysis-pretreated (SHP) and unpretreated soda-anthraquinone (AQ) (SP) pulps were characterized by yield, Kappa number, alpha, beta, and gamma cellulose, degree of polymerization, water retention value, and crystallinity. The nanocellulose was produced by a sequential chemical oxidation treatment (2,2,6,6-tetramethylpiperidine-1-oxyl, TEMPO reagent) and mechanical nanofibrillation. Nanocellulose was characterized by carboxylic group content and viscosity. The results revealed that autohydrolysis pretreatment resulted in a higher hemicelluloses extraction in G. angustifolia. In contrast, the pulping yield of unpretreated samples was higher for G. trinii, and the soda-AQ pulps from this species exhibited better delignification than the autohydrolysis-pretreated pulps. The crystallinity index values of the obtained pulps were high (>80%), and the alpha-cellulose contents were similar. The viscosities of the aqueous nanocellulose suspensions were higher for the nanocellulose solutions obtained from the unpretreated soda-AQ pulps. Besides, nanocellulose from G. trinii unpretreated soda-AQ pulps had a higher rate of carboxylic groups. The results of this work are significant in assessing the potential of both bamboo species as a source of high-value products within the biorefinery framework because the viscosities of the aqueous nanocellulose suspensions depend on the size and shape of nanofibrils. It has significant importance for industrial unit operations and potential applications.Fil: Prado Gárate, Agatha Estefanía Raquel. Universidad Nacional Agraria La Molina; Perú. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Suirezs, Teresa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaFil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; ArgentinaTech Science Press2024-08info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/263033Prado Gárate, Agatha Estefanía Raquel; Felissia, Fernando Esteban; Area, Maria Cristina; Suirezs, Teresa Maria; Vallejos, María Evangelina; Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production; Tech Science Press; Journal of Renewable Materials; 12; 9; 8-2024; 1541-15552164-6341CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.techscience.com/jrm/online/detail/21376info:eu-repo/semantics/altIdentifier/doi/10.32604/jrm.2024.052481info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:36:07Zoai:ri.conicet.gov.ar:11336/263033instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:36:07.74CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
title Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
spellingShingle Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
Prado Gárate, Agatha Estefanía Raquel
NATURAL FIBER
GUADUA ANGUSTIFOLIA
GUADUA TRINII
SODA-ANTHRAQUINONE PULP
NANOCELLULOSE
title_short Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
title_full Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
title_fullStr Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
title_full_unstemmed Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
title_sort Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production
dc.creator.none.fl_str_mv Prado Gárate, Agatha Estefanía Raquel
Felissia, Fernando Esteban
Area, Maria Cristina
Suirezs, Teresa Maria
Vallejos, María Evangelina
author Prado Gárate, Agatha Estefanía Raquel
author_facet Prado Gárate, Agatha Estefanía Raquel
Felissia, Fernando Esteban
Area, Maria Cristina
Suirezs, Teresa Maria
Vallejos, María Evangelina
author_role author
author2 Felissia, Fernando Esteban
Area, Maria Cristina
Suirezs, Teresa Maria
Vallejos, María Evangelina
author2_role author
author
author
author
dc.subject.none.fl_str_mv NATURAL FIBER
GUADUA ANGUSTIFOLIA
GUADUA TRINII
SODA-ANTHRAQUINONE PULP
NANOCELLULOSE
topic NATURAL FIBER
GUADUA ANGUSTIFOLIA
GUADUA TRINII
SODA-ANTHRAQUINONE PULP
NANOCELLULOSE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Non-traditional lignocellulosic materials are a significant resource for producing high-value products, including nanocellulose. This work studied the nanocellulose obtention from chemical pulps of the two fast-growing bamboo species, Guadua trinii, and Guadua angustifolia. Chemical pulps were produced by soda-anthraquinone (S) pulping from both autohydrolysis-pretreated (H) and unpretreated bamboo chips. Autohydrolysis-pretreated (SHP) and unpretreated soda-anthraquinone (AQ) (SP) pulps were characterized by yield, Kappa number, alpha, beta, and gamma cellulose, degree of polymerization, water retention value, and crystallinity. The nanocellulose was produced by a sequential chemical oxidation treatment (2,2,6,6-tetramethylpiperidine-1-oxyl, TEMPO reagent) and mechanical nanofibrillation. Nanocellulose was characterized by carboxylic group content and viscosity. The results revealed that autohydrolysis pretreatment resulted in a higher hemicelluloses extraction in G. angustifolia. In contrast, the pulping yield of unpretreated samples was higher for G. trinii, and the soda-AQ pulps from this species exhibited better delignification than the autohydrolysis-pretreated pulps. The crystallinity index values of the obtained pulps were high (>80%), and the alpha-cellulose contents were similar. The viscosities of the aqueous nanocellulose suspensions were higher for the nanocellulose solutions obtained from the unpretreated soda-AQ pulps. Besides, nanocellulose from G. trinii unpretreated soda-AQ pulps had a higher rate of carboxylic groups. The results of this work are significant in assessing the potential of both bamboo species as a source of high-value products within the biorefinery framework because the viscosities of the aqueous nanocellulose suspensions depend on the size and shape of nanofibrils. It has significant importance for industrial unit operations and potential applications.
Fil: Prado Gárate, Agatha Estefanía Raquel. Universidad Nacional Agraria La Molina; Perú. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas, Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Felissia, Fernando Esteban. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Area, Maria Cristina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Suirezs, Teresa Maria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
Fil: Vallejos, María Evangelina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Nordeste. Instituto de Materiales de Misiones. Universidad Nacional de Misiones. Facultad de Ciencias Exactas Químicas y Naturales. Instituto de Materiales de Misiones; Argentina
description Non-traditional lignocellulosic materials are a significant resource for producing high-value products, including nanocellulose. This work studied the nanocellulose obtention from chemical pulps of the two fast-growing bamboo species, Guadua trinii, and Guadua angustifolia. Chemical pulps were produced by soda-anthraquinone (S) pulping from both autohydrolysis-pretreated (H) and unpretreated bamboo chips. Autohydrolysis-pretreated (SHP) and unpretreated soda-anthraquinone (AQ) (SP) pulps were characterized by yield, Kappa number, alpha, beta, and gamma cellulose, degree of polymerization, water retention value, and crystallinity. The nanocellulose was produced by a sequential chemical oxidation treatment (2,2,6,6-tetramethylpiperidine-1-oxyl, TEMPO reagent) and mechanical nanofibrillation. Nanocellulose was characterized by carboxylic group content and viscosity. The results revealed that autohydrolysis pretreatment resulted in a higher hemicelluloses extraction in G. angustifolia. In contrast, the pulping yield of unpretreated samples was higher for G. trinii, and the soda-AQ pulps from this species exhibited better delignification than the autohydrolysis-pretreated pulps. The crystallinity index values of the obtained pulps were high (>80%), and the alpha-cellulose contents were similar. The viscosities of the aqueous nanocellulose suspensions were higher for the nanocellulose solutions obtained from the unpretreated soda-AQ pulps. Besides, nanocellulose from G. trinii unpretreated soda-AQ pulps had a higher rate of carboxylic groups. The results of this work are significant in assessing the potential of both bamboo species as a source of high-value products within the biorefinery framework because the viscosities of the aqueous nanocellulose suspensions depend on the size and shape of nanofibrils. It has significant importance for industrial unit operations and potential applications.
publishDate 2024
dc.date.none.fl_str_mv 2024-08
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/263033
Prado Gárate, Agatha Estefanía Raquel; Felissia, Fernando Esteban; Area, Maria Cristina; Suirezs, Teresa Maria; Vallejos, María Evangelina; Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production; Tech Science Press; Journal of Renewable Materials; 12; 9; 8-2024; 1541-1555
2164-6341
CONICET Digital
CONICET
url http://hdl.handle.net/11336/263033
identifier_str_mv Prado Gárate, Agatha Estefanía Raquel; Felissia, Fernando Esteban; Area, Maria Cristina; Suirezs, Teresa Maria; Vallejos, María Evangelina; Potential of Bamboo Species Guadua trinii and Guadua angustifolia for Nanocellulose Production; Tech Science Press; Journal of Renewable Materials; 12; 9; 8-2024; 1541-1555
2164-6341
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://www.techscience.com/jrm/online/detail/21376
info:eu-repo/semantics/altIdentifier/doi/10.32604/jrm.2024.052481
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Tech Science Press
publisher.none.fl_str_mv Tech Science Press
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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