Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben

Autores
Sun, Tingwei; Benedictto, Germán Pablo; Gonzalez, Maximiliano Ricardo; Legnoverde, María Soledad; Raymundo Piñero, Encarnacion; Basaldella, Elena Isabel; Ania, Conchi
Año de publicación
2025
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The scope of this study is to improve the photocatalytic performance of C3N4 for the degradation of methylparaben in solution, upon the immobilization of the semiconductor in the interlayer spacing of a NiZnAlhydrotalcite like compound (LDH). The growth of LDH in the presence of a homogenous dispersion of increasing amounts of carbon nitride allowed the incorporation of this carbon-based semiconductor in the interlayer space of the LDH. The prepared photocatalysts exhibited light absorption features similar to those of the pristine semiconductor and displayed better photocatalytic performance for the degradation of methylparaben and intermediates (higher conversions and degradation rates). This is attributed to the improved separation of the photogenerated charge carriers boosted by the interfacial contact between the carbon nitride confined in the lamellar structure of the hydrotalcite-like compound. The best performing material containing 15 wt% of carbon nitride showed good cycling stability over 20 h of illumination. The confinement of C3N4 affects the photodegradation mechanisms of methylparaben, with a hydroxylation-mediated reaction through the photogenerated holes as the main oxidation pathway and a minor impact of dissolved oxygen formed upon reaction of the photogenerated electrons.
Fil: Sun, Tingwei. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
Fil: Benedictto, Germán Pablo. Universidad Tecnológica Nacional. Facultad Regional Avellaneda; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Gonzalez, Maximiliano Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Raymundo Piñero, Encarnacion. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ania, Conchi. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
Materia
LDH-carbon nitride
photocatalysis
emerging pollutants
scavengers
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/281759
Acceder
id CONICETDig_8ba6e255ebb8286e89e7954b336f09f2
oai_identifier_str oai:ri.conicet.gov.ar:11336/281759
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparabenSun, TingweiBenedictto, Germán PabloGonzalez, Maximiliano RicardoLegnoverde, María SoledadRaymundo Piñero, EncarnacionBasaldella, Elena IsabelAnia, ConchiLDH-carbon nitridephotocatalysisemerging pollutantsscavengershttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The scope of this study is to improve the photocatalytic performance of C3N4 for the degradation of methylparaben in solution, upon the immobilization of the semiconductor in the interlayer spacing of a NiZnAlhydrotalcite like compound (LDH). The growth of LDH in the presence of a homogenous dispersion of increasing amounts of carbon nitride allowed the incorporation of this carbon-based semiconductor in the interlayer space of the LDH. The prepared photocatalysts exhibited light absorption features similar to those of the pristine semiconductor and displayed better photocatalytic performance for the degradation of methylparaben and intermediates (higher conversions and degradation rates). This is attributed to the improved separation of the photogenerated charge carriers boosted by the interfacial contact between the carbon nitride confined in the lamellar structure of the hydrotalcite-like compound. The best performing material containing 15 wt% of carbon nitride showed good cycling stability over 20 h of illumination. The confinement of C3N4 affects the photodegradation mechanisms of methylparaben, with a hydroxylation-mediated reaction through the photogenerated holes as the main oxidation pathway and a minor impact of dissolved oxygen formed upon reaction of the photogenerated electrons.Fil: Sun, Tingwei. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; FranciaFil: Benedictto, Germán Pablo. Universidad Tecnológica Nacional. Facultad Regional Avellaneda; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Gonzalez, Maximiliano Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Raymundo Piñero, Encarnacion. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; FranciaFil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; ArgentinaFil: Ania, Conchi. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; FranciaElsevier Science2025-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/281759Sun, Tingwei; Benedictto, Germán Pablo; Gonzalez, Maximiliano Ricardo; Legnoverde, María Soledad; Raymundo Piñero, Encarnacion; et al.; Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben; Elsevier Science; Catalysis Today; 459; 6-2025; 1-120920-5861CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586125002500info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2025.115432info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-03-11T12:30:31Zoai:ri.conicet.gov.ar:11336/281759instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-03-11 12:30:31.796CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
title Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
spellingShingle Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
Sun, Tingwei
LDH-carbon nitride
photocatalysis
emerging pollutants
scavengers
title_short Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
title_full Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
title_fullStr Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
title_full_unstemmed Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
title_sort Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben
dc.creator.none.fl_str_mv Sun, Tingwei
Benedictto, Germán Pablo
Gonzalez, Maximiliano Ricardo
Legnoverde, María Soledad
Raymundo Piñero, Encarnacion
Basaldella, Elena Isabel
Ania, Conchi
author Sun, Tingwei
author_facet Sun, Tingwei
Benedictto, Germán Pablo
Gonzalez, Maximiliano Ricardo
Legnoverde, María Soledad
Raymundo Piñero, Encarnacion
Basaldella, Elena Isabel
Ania, Conchi
author_role author
author2 Benedictto, Germán Pablo
Gonzalez, Maximiliano Ricardo
Legnoverde, María Soledad
Raymundo Piñero, Encarnacion
Basaldella, Elena Isabel
Ania, Conchi
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv LDH-carbon nitride
photocatalysis
emerging pollutants
scavengers
topic LDH-carbon nitride
photocatalysis
emerging pollutants
scavengers
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The scope of this study is to improve the photocatalytic performance of C3N4 for the degradation of methylparaben in solution, upon the immobilization of the semiconductor in the interlayer spacing of a NiZnAlhydrotalcite like compound (LDH). The growth of LDH in the presence of a homogenous dispersion of increasing amounts of carbon nitride allowed the incorporation of this carbon-based semiconductor in the interlayer space of the LDH. The prepared photocatalysts exhibited light absorption features similar to those of the pristine semiconductor and displayed better photocatalytic performance for the degradation of methylparaben and intermediates (higher conversions and degradation rates). This is attributed to the improved separation of the photogenerated charge carriers boosted by the interfacial contact between the carbon nitride confined in the lamellar structure of the hydrotalcite-like compound. The best performing material containing 15 wt% of carbon nitride showed good cycling stability over 20 h of illumination. The confinement of C3N4 affects the photodegradation mechanisms of methylparaben, with a hydroxylation-mediated reaction through the photogenerated holes as the main oxidation pathway and a minor impact of dissolved oxygen formed upon reaction of the photogenerated electrons.
Fil: Sun, Tingwei. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
Fil: Benedictto, Germán Pablo. Universidad Tecnológica Nacional. Facultad Regional Avellaneda; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Gonzalez, Maximiliano Ricardo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Legnoverde, María Soledad. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Raymundo Piñero, Encarnacion. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
Fil: Basaldella, Elena Isabel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Ciencias Aplicadas "Dr. Jorge J. Ronco". Universidad Nacional de la Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Ciencias Aplicadas; Argentina
Fil: Ania, Conchi. Centre National de la Recherche Scientifique. Laboratorie Et Conditions Extrêmes Et Matériaux : Haute Température Et Irradiation Upr3079.; Francia
description The scope of this study is to improve the photocatalytic performance of C3N4 for the degradation of methylparaben in solution, upon the immobilization of the semiconductor in the interlayer spacing of a NiZnAlhydrotalcite like compound (LDH). The growth of LDH in the presence of a homogenous dispersion of increasing amounts of carbon nitride allowed the incorporation of this carbon-based semiconductor in the interlayer space of the LDH. The prepared photocatalysts exhibited light absorption features similar to those of the pristine semiconductor and displayed better photocatalytic performance for the degradation of methylparaben and intermediates (higher conversions and degradation rates). This is attributed to the improved separation of the photogenerated charge carriers boosted by the interfacial contact between the carbon nitride confined in the lamellar structure of the hydrotalcite-like compound. The best performing material containing 15 wt% of carbon nitride showed good cycling stability over 20 h of illumination. The confinement of C3N4 affects the photodegradation mechanisms of methylparaben, with a hydroxylation-mediated reaction through the photogenerated holes as the main oxidation pathway and a minor impact of dissolved oxygen formed upon reaction of the photogenerated electrons.
publishDate 2025
dc.date.none.fl_str_mv 2025-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/281759
Sun, Tingwei; Benedictto, Germán Pablo; Gonzalez, Maximiliano Ricardo; Legnoverde, María Soledad; Raymundo Piñero, Encarnacion; et al.; Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben; Elsevier Science; Catalysis Today; 459; 6-2025; 1-12
0920-5861
CONICET Digital
CONICET
url http://hdl.handle.net/11336/281759
identifier_str_mv Sun, Tingwei; Benedictto, Germán Pablo; Gonzalez, Maximiliano Ricardo; Legnoverde, María Soledad; Raymundo Piñero, Encarnacion; et al.; Photocatalytic activity of NiZnAl hydrotalcite-like compound/carbon nitride composites for the degradation of methylparaben; Elsevier Science; Catalysis Today; 459; 6-2025; 1-12
0920-5861
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://linkinghub.elsevier.com/retrieve/pii/S0920586125002500
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.cattod.2025.115432
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science
publisher.none.fl_str_mv Elsevier Science
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1859460497043095552
score 12.977003

Publicaciones similares