Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction
- Autores
- Mastalir, Ágnes; Quiroga, Monica Esther; Szabó, Tamás; Zsigmond, Ágnes; Dékány, Imre
- Año de publicación
- 2014
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- A Pd(II) complex with chloride and tridecylamine ligands (PdCl2(TDA)2) was immobilized on graphite oxide modified with the cationic surfactant octadecyltrimethylammonium bromide (C18TABr). Samples with different Pd loadings were synthesized and tested for the liquid-phase hydrogenation of 1-pentyne and the Heck coupling reactions of styrene–bromobenzene and styrene–iodobenzene. For the hydrogenation of 1-pentyne, the catalytic performance was found to be affected by the pretreatment procedure. For the Heck coupling reactions, the PdCl2(TDA)2/GO samples proved to be highly efficient catalysts. The catalytic activity was found to depend on the Pd loading for both reactions.
Fil: Mastalir, Ágnes. Szegedi Tudományegyetem (szte); Hungría
Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Fil: Szabó, Tamás. Department of Physical Chemistry and Materials Science; Hungría
Fil: Zsigmond, Ágnes. Szegedi Tudományegyetem (szte); Hungría
Fil: Dékány, Imre. Department of Physical Chemistry and Materials Science; Hungría - Materia
-
Alkyne Hydrogenation
Graphite Oxide
Heck Reaction
Immobilization
[Pdcl≪Inf≫2≪/Inf≫(Tda)≪Inf≫2≪/Inf≫] - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
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- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/78603
Ver los metadatos del registro completo
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Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reactionMastalir, ÁgnesQuiroga, Monica EstherSzabó, TamásZsigmond, ÁgnesDékány, ImreAlkyne HydrogenationGraphite OxideHeck ReactionImmobilization[Pdcl≪Inf≫2≪/Inf≫(Tda)≪Inf≫2≪/Inf≫]https://purl.org/becyt/ford/2.10https://purl.org/becyt/ford/2A Pd(II) complex with chloride and tridecylamine ligands (PdCl2(TDA)2) was immobilized on graphite oxide modified with the cationic surfactant octadecyltrimethylammonium bromide (C18TABr). Samples with different Pd loadings were synthesized and tested for the liquid-phase hydrogenation of 1-pentyne and the Heck coupling reactions of styrene–bromobenzene and styrene–iodobenzene. For the hydrogenation of 1-pentyne, the catalytic performance was found to be affected by the pretreatment procedure. For the Heck coupling reactions, the PdCl2(TDA)2/GO samples proved to be highly efficient catalysts. The catalytic activity was found to depend on the Pd loading for both reactions.Fil: Mastalir, Ágnes. Szegedi Tudományegyetem (szte); HungríaFil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaFil: Szabó, Tamás. Department of Physical Chemistry and Materials Science; HungríaFil: Zsigmond, Ágnes. Szegedi Tudományegyetem (szte); HungríaFil: Dékány, Imre. Department of Physical Chemistry and Materials Science; HungríaSpringer2014-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/78603Mastalir, Ágnes; Quiroga, Monica Esther; Szabó, Tamás; Zsigmond, Ágnes; Dékány, Imre; Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction; Springer; Reaction Kinetics, Mechanisms and Catalysis; 113; 1; 6-2014; 61-681878-5204CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1007/s11144-014-0735-xinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-10T13:24:35Zoai:ri.conicet.gov.ar:11336/78603instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-10 13:24:35.682CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
| dc.title.none.fl_str_mv |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| title |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| spellingShingle |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction Mastalir, Ágnes Alkyne Hydrogenation Graphite Oxide Heck Reaction Immobilization [Pdcl≪Inf≫2≪/Inf≫(Tda)≪Inf≫2≪/Inf≫] |
| title_short |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| title_full |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| title_fullStr |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| title_full_unstemmed |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| title_sort |
Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction |
| dc.creator.none.fl_str_mv |
Mastalir, Ágnes Quiroga, Monica Esther Szabó, Tamás Zsigmond, Ágnes Dékány, Imre |
| author |
Mastalir, Ágnes |
| author_facet |
Mastalir, Ágnes Quiroga, Monica Esther Szabó, Tamás Zsigmond, Ágnes Dékány, Imre |
| author_role |
author |
| author2 |
Quiroga, Monica Esther Szabó, Tamás Zsigmond, Ágnes Dékány, Imre |
| author2_role |
author author author author |
| dc.subject.none.fl_str_mv |
Alkyne Hydrogenation Graphite Oxide Heck Reaction Immobilization [Pdcl≪Inf≫2≪/Inf≫(Tda)≪Inf≫2≪/Inf≫] |
| topic |
Alkyne Hydrogenation Graphite Oxide Heck Reaction Immobilization [Pdcl≪Inf≫2≪/Inf≫(Tda)≪Inf≫2≪/Inf≫] |
| purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.10 https://purl.org/becyt/ford/2 |
| dc.description.none.fl_txt_mv |
A Pd(II) complex with chloride and tridecylamine ligands (PdCl2(TDA)2) was immobilized on graphite oxide modified with the cationic surfactant octadecyltrimethylammonium bromide (C18TABr). Samples with different Pd loadings were synthesized and tested for the liquid-phase hydrogenation of 1-pentyne and the Heck coupling reactions of styrene–bromobenzene and styrene–iodobenzene. For the hydrogenation of 1-pentyne, the catalytic performance was found to be affected by the pretreatment procedure. For the Heck coupling reactions, the PdCl2(TDA)2/GO samples proved to be highly efficient catalysts. The catalytic activity was found to depend on the Pd loading for both reactions. Fil: Mastalir, Ágnes. Szegedi Tudományegyetem (szte); Hungría Fil: Quiroga, Monica Esther. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina Fil: Szabó, Tamás. Department of Physical Chemistry and Materials Science; Hungría Fil: Zsigmond, Ágnes. Szegedi Tudományegyetem (szte); Hungría Fil: Dékány, Imre. Department of Physical Chemistry and Materials Science; Hungría |
| description |
A Pd(II) complex with chloride and tridecylamine ligands (PdCl2(TDA)2) was immobilized on graphite oxide modified with the cationic surfactant octadecyltrimethylammonium bromide (C18TABr). Samples with different Pd loadings were synthesized and tested for the liquid-phase hydrogenation of 1-pentyne and the Heck coupling reactions of styrene–bromobenzene and styrene–iodobenzene. For the hydrogenation of 1-pentyne, the catalytic performance was found to be affected by the pretreatment procedure. For the Heck coupling reactions, the PdCl2(TDA)2/GO samples proved to be highly efficient catalysts. The catalytic activity was found to depend on the Pd loading for both reactions. |
| publishDate |
2014 |
| dc.date.none.fl_str_mv |
2014-06 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
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article |
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publishedVersion |
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http://hdl.handle.net/11336/78603 Mastalir, Ágnes; Quiroga, Monica Esther; Szabó, Tamás; Zsigmond, Ágnes; Dékány, Imre; Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction; Springer; Reaction Kinetics, Mechanisms and Catalysis; 113; 1; 6-2014; 61-68 1878-5204 CONICET Digital CONICET |
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http://hdl.handle.net/11336/78603 |
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Mastalir, Ágnes; Quiroga, Monica Esther; Szabó, Tamás; Zsigmond, Ágnes; Dékány, Imre; Catalytic investigation of PdCl2(TDA)2 immobilized on hydrophobic graphite oxide in the hydrogenation of 1-pentyne and the Heck coupling reaction; Springer; Reaction Kinetics, Mechanisms and Catalysis; 113; 1; 6-2014; 61-68 1878-5204 CONICET Digital CONICET |
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eng |
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eng |
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info:eu-repo/semantics/altIdentifier/doi/10.1007/s11144-014-0735-x |
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openAccess |
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application/pdf application/pdf |
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Springer |
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Springer |
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CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
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dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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