Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe

Autores
Barone, Vicente Luis; Botto, Irma Lia
Año de publicación
2013
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Sulphides and selenides are mineral species that commonly occur together in natural deposits, according to the relative abundance. Moreover, the emerging importance of selenium in several fields of sciences, the economic value of the metal silver, commonly associated to selenide by chemical affinity and the existence of selenium deposits in Argentina lead to study the CuAgSe eucairite oxidation process in air atmosphere, by thermal and acid treatments in order to the Se and Ag recovery. The analysis was carried out with pure mineral by means of (TGA-DTGA) Thermogravimetric technique, X-ray Diffraction (XRD), Infrared Spectroscopy (FTIR), Chemical analysis, Scanning Electron Microscopy (SEM-EDS) and treatments with HCl, H2SO4 and HNO3 (0.1 M, up to 180 min and 60 ºC). Thermal oxidation permits the separation of SeO2(g) from a solid residue in the 500-750 ºC range, whereas the adequate combination of soft acid and thermal treatments can be formulated as a potential strategy to separate Agº from a copper (II) solution.
Fil: Barone, Vicente Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Materia
Eucairite
thermal effects
acid oxidative effects
TGA and FTIR studies
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24372
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/24372
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSeBarone, Vicente LuisBotto, Irma LiaEucairitethermal effectsacid oxidative effectsTGA and FTIR studieshttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Sulphides and selenides are mineral species that commonly occur together in natural deposits, according to the relative abundance. Moreover, the emerging importance of selenium in several fields of sciences, the economic value of the metal silver, commonly associated to selenide by chemical affinity and the existence of selenium deposits in Argentina lead to study the CuAgSe eucairite oxidation process in air atmosphere, by thermal and acid treatments in order to the Se and Ag recovery. The analysis was carried out with pure mineral by means of (TGA-DTGA) Thermogravimetric technique, X-ray Diffraction (XRD), Infrared Spectroscopy (FTIR), Chemical analysis, Scanning Electron Microscopy (SEM-EDS) and treatments with HCl, H2SO4 and HNO3 (0.1 M, up to 180 min and 60 ºC). Thermal oxidation permits the separation of SeO2(g) from a solid residue in the 500-750 ºC range, whereas the adequate combination of soft acid and thermal treatments can be formulated as a potential strategy to separate Agº from a copper (II) solution.Fil: Barone, Vicente Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaFil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; ArgentinaAsian Journal of Research In Chemistry2013-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24372Barone, Vicente Luis; Botto, Irma Lia; Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe; Asian Journal of Research In Chemistry; Asian Journal of Research In Chemistry; 6; 8; 6-2013; 755-7600974-41690974-4150CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://ajrconline.org/AbstractView.aspx?PID=2013-6-8-11info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:41:46Zoai:ri.conicet.gov.ar:11336/24372instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:41:46.394CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
title Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
spellingShingle Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
Barone, Vicente Luis
Eucairite
thermal effects
acid oxidative effects
TGA and FTIR studies
title_short Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
title_full Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
title_fullStr Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
title_full_unstemmed Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
title_sort Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe
dc.creator.none.fl_str_mv Barone, Vicente Luis
Botto, Irma Lia
author Barone, Vicente Luis
author_facet Barone, Vicente Luis
Botto, Irma Lia
author_role author
author2 Botto, Irma Lia
author2_role author
dc.subject.none.fl_str_mv Eucairite
thermal effects
acid oxidative effects
TGA and FTIR studies
topic Eucairite
thermal effects
acid oxidative effects
TGA and FTIR studies
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Sulphides and selenides are mineral species that commonly occur together in natural deposits, according to the relative abundance. Moreover, the emerging importance of selenium in several fields of sciences, the economic value of the metal silver, commonly associated to selenide by chemical affinity and the existence of selenium deposits in Argentina lead to study the CuAgSe eucairite oxidation process in air atmosphere, by thermal and acid treatments in order to the Se and Ag recovery. The analysis was carried out with pure mineral by means of (TGA-DTGA) Thermogravimetric technique, X-ray Diffraction (XRD), Infrared Spectroscopy (FTIR), Chemical analysis, Scanning Electron Microscopy (SEM-EDS) and treatments with HCl, H2SO4 and HNO3 (0.1 M, up to 180 min and 60 ºC). Thermal oxidation permits the separation of SeO2(g) from a solid residue in the 500-750 ºC range, whereas the adequate combination of soft acid and thermal treatments can be formulated as a potential strategy to separate Agº from a copper (II) solution.
Fil: Barone, Vicente Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
Fil: Botto, Irma Lia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Química Inorgánica "Dr. Pedro J. Aymonino". Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Química Inorgánica "Dr. Pedro J. Aymonino"; Argentina
description Sulphides and selenides are mineral species that commonly occur together in natural deposits, according to the relative abundance. Moreover, the emerging importance of selenium in several fields of sciences, the economic value of the metal silver, commonly associated to selenide by chemical affinity and the existence of selenium deposits in Argentina lead to study the CuAgSe eucairite oxidation process in air atmosphere, by thermal and acid treatments in order to the Se and Ag recovery. The analysis was carried out with pure mineral by means of (TGA-DTGA) Thermogravimetric technique, X-ray Diffraction (XRD), Infrared Spectroscopy (FTIR), Chemical analysis, Scanning Electron Microscopy (SEM-EDS) and treatments with HCl, H2SO4 and HNO3 (0.1 M, up to 180 min and 60 ºC). Thermal oxidation permits the separation of SeO2(g) from a solid residue in the 500-750 ºC range, whereas the adequate combination of soft acid and thermal treatments can be formulated as a potential strategy to separate Agº from a copper (II) solution.
publishDate 2013
dc.date.none.fl_str_mv 2013-06
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24372
Barone, Vicente Luis; Botto, Irma Lia; Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe; Asian Journal of Research In Chemistry; Asian Journal of Research In Chemistry; 6; 8; 6-2013; 755-760
0974-4169
0974-4150
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24372
identifier_str_mv Barone, Vicente Luis; Botto, Irma Lia; Thermal and Acid Oxidative Strategy to Recovery Selenium and Silver from Eucairite CuAgSe; Asian Journal of Research In Chemistry; Asian Journal of Research In Chemistry; 6; 8; 6-2013; 755-760
0974-4169
0974-4150
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://ajrconline.org/AbstractView.aspx?PID=2013-6-8-11
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Asian Journal of Research In Chemistry
publisher.none.fl_str_mv Asian Journal of Research In Chemistry
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.070432

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