Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
- Autores
- Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; Troncoso, Loreto; Rojas, Paula
- Año de publicación
- 2018
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.
Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; Chile
Fil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Guzmán, Danny. Universidad de Atacama; Chile
Fil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Troncoso, Loreto. Universidad Austral de Chile; Chile
Fil: Rojas, Paula. Universidad Adolfo Ibañez; Chile - Materia
-
AMORPHOUS ALLOYS
COPPER BASED ALLOYS
MECHANICAL ALLOYING
THERMODYNAMIC ANALYSIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/126138
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CONICET Digital (CONICET) |
spelling |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloyingMartínez, CarolaAguilar, ClaudioBriones, FranciscoGuzmán, DannyZelaya, Maria EugeniaTroncoso, LoretoRojas, PaulaAMORPHOUS ALLOYSCOPPER BASED ALLOYSMECHANICAL ALLOYINGTHERMODYNAMIC ANALYSISTRANSMISSION ELECTRON MICROSCOPYX-RAY DIFFRACTIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; ChileFil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; ChileFil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; ChileFil: Guzmán, Danny. Universidad de Atacama; ChileFil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Troncoso, Loreto. Universidad Austral de Chile; ChileFil: Rojas, Paula. Universidad Adolfo Ibañez; ChileElsevier Science SA2018-10-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/126138Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-7810925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0925838818315822info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2018.04.259info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:56:51Zoai:ri.conicet.gov.ar:11336/126138instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:56:51.536CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
title |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
spellingShingle |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying Martínez, Carola AMORPHOUS ALLOYS COPPER BASED ALLOYS MECHANICAL ALLOYING THERMODYNAMIC ANALYSIS TRANSMISSION ELECTRON MICROSCOPY X-RAY DIFFRACTION |
title_short |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
title_full |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
title_fullStr |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
title_full_unstemmed |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
title_sort |
Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying |
dc.creator.none.fl_str_mv |
Martínez, Carola Aguilar, Claudio Briones, Francisco Guzmán, Danny Zelaya, Maria Eugenia Troncoso, Loreto Rojas, Paula |
author |
Martínez, Carola |
author_facet |
Martínez, Carola Aguilar, Claudio Briones, Francisco Guzmán, Danny Zelaya, Maria Eugenia Troncoso, Loreto Rojas, Paula |
author_role |
author |
author2 |
Aguilar, Claudio Briones, Francisco Guzmán, Danny Zelaya, Maria Eugenia Troncoso, Loreto Rojas, Paula |
author2_role |
author author author author author author |
dc.subject.none.fl_str_mv |
AMORPHOUS ALLOYS COPPER BASED ALLOYS MECHANICAL ALLOYING THERMODYNAMIC ANALYSIS TRANSMISSION ELECTRON MICROSCOPY X-RAY DIFFRACTION |
topic |
AMORPHOUS ALLOYS COPPER BASED ALLOYS MECHANICAL ALLOYING THERMODYNAMIC ANALYSIS TRANSMISSION ELECTRON MICROSCOPY X-RAY DIFFRACTION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/2.5 https://purl.org/becyt/ford/2 |
dc.description.none.fl_txt_mv |
This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased. Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; Chile Fil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; Chile Fil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; Chile Fil: Guzmán, Danny. Universidad de Atacama; Chile Fil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina Fil: Troncoso, Loreto. Universidad Austral de Chile; Chile Fil: Rojas, Paula. Universidad Adolfo Ibañez; Chile |
description |
This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-10-15 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/126138 Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-781 0925-8388 CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/126138 |
identifier_str_mv |
Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-781 0925-8388 CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0925838818315822 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2018.04.259 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science SA |
publisher.none.fl_str_mv |
Elsevier Science SA |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
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1844613705134768128 |
score |
13.070432 |