Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying

Autores
Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; Troncoso, Loreto; Rojas, Paula
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.
Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; Chile
Fil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Guzmán, Danny. Universidad de Atacama; Chile
Fil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Troncoso, Loreto. Universidad Austral de Chile; Chile
Fil: Rojas, Paula. Universidad Adolfo Ibañez; Chile
Materia
AMORPHOUS ALLOYS
COPPER BASED ALLOYS
MECHANICAL ALLOYING
THERMODYNAMIC ANALYSIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/126138
Acceder
id CONICETDig_8709ec0bcb3f74dde761b2113f18af14
oai_identifier_str oai:ri.conicet.gov.ar:11336/126138
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloyingMartínez, CarolaAguilar, ClaudioBriones, FranciscoGuzmán, DannyZelaya, Maria EugeniaTroncoso, LoretoRojas, PaulaAMORPHOUS ALLOYSCOPPER BASED ALLOYSMECHANICAL ALLOYINGTHERMODYNAMIC ANALYSISTRANSMISSION ELECTRON MICROSCOPYX-RAY DIFFRACTIONhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; ChileFil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; ChileFil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; ChileFil: Guzmán, Danny. Universidad de Atacama; ChileFil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; ArgentinaFil: Troncoso, Loreto. Universidad Austral de Chile; ChileFil: Rojas, Paula. Universidad Adolfo Ibañez; ChileElsevier Science SA2018-10-15info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/126138Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-7810925-8388CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0925838818315822info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2018.04.259info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-22T11:26:04Zoai:ri.conicet.gov.ar:11336/126138instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-22 11:26:04.475CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
title Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
spellingShingle Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
Martínez, Carola
AMORPHOUS ALLOYS
COPPER BASED ALLOYS
MECHANICAL ALLOYING
THERMODYNAMIC ANALYSIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
title_short Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
title_full Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
title_fullStr Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
title_full_unstemmed Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
title_sort Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying
dc.creator.none.fl_str_mv Martínez, Carola
Aguilar, Claudio
Briones, Francisco
Guzmán, Danny
Zelaya, Maria Eugenia
Troncoso, Loreto
Rojas, Paula
author Martínez, Carola
author_facet Martínez, Carola
Aguilar, Claudio
Briones, Francisco
Guzmán, Danny
Zelaya, Maria Eugenia
Troncoso, Loreto
Rojas, Paula
author_role author
author2 Aguilar, Claudio
Briones, Francisco
Guzmán, Danny
Zelaya, Maria Eugenia
Troncoso, Loreto
Rojas, Paula
author2_role author
author
author
author
author
author
dc.subject.none.fl_str_mv AMORPHOUS ALLOYS
COPPER BASED ALLOYS
MECHANICAL ALLOYING
THERMODYNAMIC ANALYSIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
topic AMORPHOUS ALLOYS
COPPER BASED ALLOYS
MECHANICAL ALLOYING
THERMODYNAMIC ANALYSIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.
Fil: Martínez, Carola. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Aguilar, Claudio. Universidad Tecnica Federico Santa Maria; Chile
Fil: Briones, Francisco. Pontificia Universidad Católica de Valparaíso; Chile
Fil: Guzmán, Danny. Universidad de Atacama; Chile
Fil: Zelaya, Maria Eugenia. Comisión Nacional de Energía Atómica. Gerencia del Área de Investigación y Aplicaciones No Nucleares. Gerencia de Física (Centro Atómico Bariloche); Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte; Argentina
Fil: Troncoso, Loreto. Universidad Austral de Chile; Chile
Fil: Rojas, Paula. Universidad Adolfo Ibañez; Chile
description This work presents the effects of high energy milling with different Ni and Zr ratios on the amorphization of ternary Cu-Ni-Zr alloys (initially, Cu-43Ni-7Zr, Cu-12Ni-31Zr, Cu-33Ni-7Zr, and Cu-12Ni-23Zr; and later, Cu-23Ni-15Zr and Cu-11Ni-7Zr). Microstructure was determined using X-Ray diffraction and electron microscopy. Results were compared to thermodynamic models. In the ternary alloys under study, the lattice parameter of the Cu-Ni solid solution was generally correlated to the amounts of nickel incorporated into the Cu lattice. However, longer milling times reduced that lattice parameter and facilitated Zr insertion into the solid solution. For example, after 5 h of milling time, microstructural analysis showed the formation of a solid solution with cubic structure in Cu-43Ni-7Zr. This pattern is consistent with the presence of a lattice parameter between that of Cu and Ni (α−phase); in contrast, the Cu-33Ni-7Zr alloy showed an α-phase and another similar to Zr. Results suggest that, as the amount of nickel increases, the ability to form an amorphous phase decreases. Additionally, experimental and thermodynamic data showed a solid-solution formation stage, followed by an amorphous phase formation stage that occurred as milling time and Zr content increased.
publishDate 2018
dc.date.none.fl_str_mv 2018-10-15
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/126138
Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-781
0925-8388
CONICET Digital
CONICET
url http://hdl.handle.net/11336/126138
identifier_str_mv Martínez, Carola; Aguilar, Claudio; Briones, Francisco; Guzmán, Danny; Zelaya, Maria Eugenia; et al.; Effects of Zr on the amorphization of Cu-Ni-Zr alloys prepared by mechanical alloying; Elsevier Science SA; Journal of Alloys and Compounds; 765; 15-10-2018; 771-781
0925-8388
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://linkinghub.elsevier.com/retrieve/pii/S0925838818315822
info:eu-repo/semantics/altIdentifier/doi/10.1016/j.jallcom.2018.04.259
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier Science SA
publisher.none.fl_str_mv Elsevier Science SA
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 12.982451

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