Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)

Autores: Corti, Horacio Roberto; Angell, C. Austen; Auffret, Tony; Levine, Harry; Buera, Maria del Pilar; Reid, David S.; Roos, Yrjö H.; Slade, Louise
Año de publicación: 2010
Idioma: inglés
Tipo de recurso: artículo
Estado: versión publicada
Descripción: This paper describes the main thermodynamic concepts related to the construction of supplemented phase (or state) diagrams (SPDs) for aqueous solutions containing vitrifying agents used in the cryo- and dehydro-preservation of natural (foods, seeds, etc.) and synthetic (pharmaceuticals) products. It also reviews the empirical and theoretical equations employed to predict equilibrium transitions (ice freezing, solute solubility) and non-equilibrium transitions (glass transition and the extrapolated freezing curve). The comparison with experimental results is restricted to carbohydrate aqueous solutions, because these are the most widely used cryoprotectant agents. The paper identifies the best standard procedure to determine the glass transition curve over the entire water-content scale, and how to determine the temperature and concentration of the maximally freeze-concentrated solution.
Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Angell, C. Austen. Arizona State University; Estados Unidos
Fil: Auffret, Tony. Pfizer Ltd.; Estados Unidos
Fil: Levine, Harry. Food Polymer Science Consultancy; Estados Unidos
Fil: Buera, Maria del Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina
Fil: Reid, David S.. University of California at Davis; Estados Unidos
Fil: Roos, Yrjö H.. University College; Irlanda
Fil: Slade, Louise. Food Polymer Science Consultancy; Estados Unidos
Materia: Supplemented phase diagrams
Sugars
criopreservation
Nivel de accesibilidad: acceso abierto
Condiciones de uso: https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
Institución: Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador: oai:ri.conicet.gov.ar:11336/280204

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spelling	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)Corti, Horacio RobertoAngell, C. AustenAuffret, TonyLevine, HarryBuera, Maria del PilarReid, David S.Roos, Yrjö H.Slade, LouiseSupplemented phase diagramsSugarscriopreservationhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1This paper describes the main thermodynamic concepts related to the construction of supplemented phase (or state) diagrams (SPDs) for aqueous solutions containing vitrifying agents used in the cryo- and dehydro-preservation of natural (foods, seeds, etc.) and synthetic (pharmaceuticals) products. It also reviews the empirical and theoretical equations employed to predict equilibrium transitions (ice freezing, solute solubility) and non-equilibrium transitions (glass transition and the extrapolated freezing curve). The comparison with experimental results is restricted to carbohydrate aqueous solutions, because these are the most widely used cryoprotectant agents. The paper identifies the best standard procedure to determine the glass transition curve over the entire water-content scale, and how to determine the temperature and concentration of the maximally freeze-concentrated solution.Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Angell, C. Austen. Arizona State University; Estados UnidosFil: Auffret, Tony. Pfizer Ltd.; Estados UnidosFil: Levine, Harry. Food Polymer Science Consultancy; Estados UnidosFil: Buera, Maria del Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; ArgentinaFil: Reid, David S.. University of California at Davis; Estados UnidosFil: Roos, Yrjö H.. University College; IrlandaFil: Slade, Louise. Food Polymer Science Consultancy; Estados UnidosInt Union Pure Applied Chemistry2010-07info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/280204Corti, Horacio Roberto; Angell, C. Austen; Auffret, Tony; Levine, Harry; Buera, Maria del Pilar; et al.; Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report); Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 82; 5; 7-2010; 1065-10970033-4545CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.degruyterbrill.com/document/doi/10.1351/PAC-REP-09-10-24/htmlinfo:eu-repo/semantics/altIdentifier/doi/10.1351/PAC-REP-09-10-24info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2026-02-06T12:46:16Zoai:ri.conicet.gov.ar:11336/280204instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982026-02-06 12:46:16.684CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
title	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
spellingShingle	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report) Corti, Horacio Roberto Supplemented phase diagrams Sugars criopreservation
title_short	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
title_full	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
title_fullStr	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
title_full_unstemmed	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
title_sort	Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)
dc.creator.none.fl_str_mv	Corti, Horacio Roberto Angell, C. Austen Auffret, Tony Levine, Harry Buera, Maria del Pilar Reid, David S. Roos, Yrjö H. Slade, Louise
author	Corti, Horacio Roberto
author_facet	Corti, Horacio Roberto Angell, C. Austen Auffret, Tony Levine, Harry Buera, Maria del Pilar Reid, David S. Roos, Yrjö H. Slade, Louise
author_role	author
author2	Angell, C. Austen Auffret, Tony Levine, Harry Buera, Maria del Pilar Reid, David S. Roos, Yrjö H. Slade, Louise
author2_role	author author author author author author author
dc.subject.none.fl_str_mv	Supplemented phase diagrams Sugars criopreservation
topic	Supplemented phase diagrams Sugars criopreservation
purl_subject.fl_str_mv	https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv	This paper describes the main thermodynamic concepts related to the construction of supplemented phase (or state) diagrams (SPDs) for aqueous solutions containing vitrifying agents used in the cryo- and dehydro-preservation of natural (foods, seeds, etc.) and synthetic (pharmaceuticals) products. It also reviews the empirical and theoretical equations employed to predict equilibrium transitions (ice freezing, solute solubility) and non-equilibrium transitions (glass transition and the extrapolated freezing curve). The comparison with experimental results is restricted to carbohydrate aqueous solutions, because these are the most widely used cryoprotectant agents. The paper identifies the best standard procedure to determine the glass transition curve over the entire water-content scale, and how to determine the temperature and concentration of the maximally freeze-concentrated solution. Fil: Corti, Horacio Roberto. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina Fil: Angell, C. Austen. Arizona State University; Estados Unidos Fil: Auffret, Tony. Pfizer Ltd.; Estados Unidos Fil: Levine, Harry. Food Polymer Science Consultancy; Estados Unidos Fil: Buera, Maria del Pilar. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Ciudad Universitaria; Argentina. Universidad de Buenos Aires. Facultad de Ciencias Exactas y Naturales; Argentina Fil: Reid, David S.. University of California at Davis; Estados Unidos Fil: Roos, Yrjö H.. University College; Irlanda Fil: Slade, Louise. Food Polymer Science Consultancy; Estados Unidos
description	This paper describes the main thermodynamic concepts related to the construction of supplemented phase (or state) diagrams (SPDs) for aqueous solutions containing vitrifying agents used in the cryo- and dehydro-preservation of natural (foods, seeds, etc.) and synthetic (pharmaceuticals) products. It also reviews the empirical and theoretical equations employed to predict equilibrium transitions (ice freezing, solute solubility) and non-equilibrium transitions (glass transition and the extrapolated freezing curve). The comparison with experimental results is restricted to carbohydrate aqueous solutions, because these are the most widely used cryoprotectant agents. The paper identifies the best standard procedure to determine the glass transition curve over the entire water-content scale, and how to determine the temperature and concentration of the maximally freeze-concentrated solution.
publishDate	2010
dc.date.none.fl_str_mv	2010-07
dc.type.none.fl_str_mv	info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo
format	article
status_str	publishedVersion
dc.identifier.none.fl_str_mv	http://hdl.handle.net/11336/280204 Corti, Horacio Roberto; Angell, C. Austen; Auffret, Tony; Levine, Harry; Buera, Maria del Pilar; et al.; Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report); Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 82; 5; 7-2010; 1065-1097 0033-4545 CONICET Digital CONICET
url	http://hdl.handle.net/11336/280204
identifier_str_mv	Corti, Horacio Roberto; Angell, C. Austen; Auffret, Tony; Levine, Harry; Buera, Maria del Pilar; et al.; Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report); Int Union Pure Applied Chemistry; Pure and Applied Chemistry; 82; 5; 7-2010; 1065-1097 0033-4545 CONICET Digital CONICET
dc.language.none.fl_str_mv	eng
language	eng
dc.relation.none.fl_str_mv	info:eu-repo/semantics/altIdentifier/url/https://www.degruyterbrill.com/document/doi/10.1351/PAC-REP-09-10-24/html info:eu-repo/semantics/altIdentifier/doi/10.1351/PAC-REP-09-10-24
dc.rights.none.fl_str_mv	info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv	openAccess
rights_invalid_str_mv	https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv	application/pdf application/pdf application/pdf
dc.publisher.none.fl_str_mv	Int Union Pure Applied Chemistry
publisher.none.fl_str_mv	Int Union Pure Applied Chemistry
dc.source.none.fl_str_mv	reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str	CONICET Digital (CONICET)
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repository.name.fl_str_mv	CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv	dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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Empirical and theoretical models of equilibrium and non-equilibrium transition temperatures of supplemented phase diagrams in aqueous systems (IUPAC Technical Report)

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