Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry

Autores
Redondas, Cintia Elizabeth; Baumler, Erica Raquel; Carelli Albarracin, Amalia Antonia
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
BACKGROUND: The sunflower oil industry produces a large amount of waste that is not currently commercially exploited, as in the case of oil‐tank settlings. The recovery of a high value‐added by‐product, such as sunflower wax, would increase the commercial value of this waste. In this original research paper, a method that allows the recovery and purification of this by‐product was developed. The wax was characterized and its potential use as an organogelator agent was investigated. RESULTS: The waste sample was composed of 45.1% oily material, 16.9% of this being impure waxes. Purification was performed through two different methods, obtaining three waxes with different degrees of purity. All the waxes were composed of wax esters with a range of 40–60 carbon atoms, exhibiting traces of carotenes, free fatty acids, and free fatty alcohols. The presence of phospholipids was observed in two of them. The third wax presented a higher total wax ester content and physicochemical characteristics (color and thermal behavior) similar to those of commercial sunflower waxes, and was the most efficient organogelator agent, requiring only a small amount of wax (1.5%) to structure high oleic sunflower oil. CONCLUSION: It was verified that sunflower wax could be recovered from oil‐tank settlings. A purification method that allowed sunflower wax with similar physicochemical properties to those of commercial waxes to be obtained was also developed. The purified waxes were capable of structuring high oleic sunflower oil. © 2019 Society of Chemical Industry
Fil: Redondas, Cintia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Baumler, Erica Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Carelli Albarracin, Amalia Antonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Materia
SUNFLOWER WAXES
OIL TANK SETTLING
DIFFERENTIAL SCANNING CALORIMETRY
COLOR
COMPOSITION
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/113629

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network_name_str CONICET Digital (CONICET)
spelling Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industryRedondas, Cintia ElizabethBaumler, Erica RaquelCarelli Albarracin, Amalia AntoniaSUNFLOWER WAXESOIL TANK SETTLINGDIFFERENTIAL SCANNING CALORIMETRYCOLORCOMPOSITIONhttps://purl.org/becyt/ford/2.11https://purl.org/becyt/ford/2BACKGROUND: The sunflower oil industry produces a large amount of waste that is not currently commercially exploited, as in the case of oil‐tank settlings. The recovery of a high value‐added by‐product, such as sunflower wax, would increase the commercial value of this waste. In this original research paper, a method that allows the recovery and purification of this by‐product was developed. The wax was characterized and its potential use as an organogelator agent was investigated. RESULTS: The waste sample was composed of 45.1% oily material, 16.9% of this being impure waxes. Purification was performed through two different methods, obtaining three waxes with different degrees of purity. All the waxes were composed of wax esters with a range of 40–60 carbon atoms, exhibiting traces of carotenes, free fatty acids, and free fatty alcohols. The presence of phospholipids was observed in two of them. The third wax presented a higher total wax ester content and physicochemical characteristics (color and thermal behavior) similar to those of commercial sunflower waxes, and was the most efficient organogelator agent, requiring only a small amount of wax (1.5%) to structure high oleic sunflower oil. CONCLUSION: It was verified that sunflower wax could be recovered from oil‐tank settlings. A purification method that allowed sunflower wax with similar physicochemical properties to those of commercial waxes to be obtained was also developed. The purified waxes were capable of structuring high oleic sunflower oil. © 2019 Society of Chemical IndustryFil: Redondas, Cintia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Baumler, Erica Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaFil: Carelli Albarracin, Amalia Antonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; ArgentinaJohn Wiley & Sons Ltd2019-11-27info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/113629Redondas, Cintia Elizabeth; Baumler, Erica Raquel; Carelli Albarracin, Amalia Antonia; Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 100; 1; 27-11-2019; 201-2110022-5142CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jsfa.10017info:eu-repo/semantics/altIdentifier/doi/10.1002/jsfa.10017info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-nd/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:36:34Zoai:ri.conicet.gov.ar:11336/113629instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:36:34.598CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
title Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
spellingShingle Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
Redondas, Cintia Elizabeth
SUNFLOWER WAXES
OIL TANK SETTLING
DIFFERENTIAL SCANNING CALORIMETRY
COLOR
COMPOSITION
title_short Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
title_full Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
title_fullStr Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
title_full_unstemmed Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
title_sort Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry
dc.creator.none.fl_str_mv Redondas, Cintia Elizabeth
Baumler, Erica Raquel
Carelli Albarracin, Amalia Antonia
author Redondas, Cintia Elizabeth
author_facet Redondas, Cintia Elizabeth
Baumler, Erica Raquel
Carelli Albarracin, Amalia Antonia
author_role author
author2 Baumler, Erica Raquel
Carelli Albarracin, Amalia Antonia
author2_role author
author
dc.subject.none.fl_str_mv SUNFLOWER WAXES
OIL TANK SETTLING
DIFFERENTIAL SCANNING CALORIMETRY
COLOR
COMPOSITION
topic SUNFLOWER WAXES
OIL TANK SETTLING
DIFFERENTIAL SCANNING CALORIMETRY
COLOR
COMPOSITION
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.11
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv BACKGROUND: The sunflower oil industry produces a large amount of waste that is not currently commercially exploited, as in the case of oil‐tank settlings. The recovery of a high value‐added by‐product, such as sunflower wax, would increase the commercial value of this waste. In this original research paper, a method that allows the recovery and purification of this by‐product was developed. The wax was characterized and its potential use as an organogelator agent was investigated. RESULTS: The waste sample was composed of 45.1% oily material, 16.9% of this being impure waxes. Purification was performed through two different methods, obtaining three waxes with different degrees of purity. All the waxes were composed of wax esters with a range of 40–60 carbon atoms, exhibiting traces of carotenes, free fatty acids, and free fatty alcohols. The presence of phospholipids was observed in two of them. The third wax presented a higher total wax ester content and physicochemical characteristics (color and thermal behavior) similar to those of commercial sunflower waxes, and was the most efficient organogelator agent, requiring only a small amount of wax (1.5%) to structure high oleic sunflower oil. CONCLUSION: It was verified that sunflower wax could be recovered from oil‐tank settlings. A purification method that allowed sunflower wax with similar physicochemical properties to those of commercial waxes to be obtained was also developed. The purified waxes were capable of structuring high oleic sunflower oil. © 2019 Society of Chemical Industry
Fil: Redondas, Cintia Elizabeth. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Baumler, Erica Raquel. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
Fil: Carelli Albarracin, Amalia Antonia. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Bahía Blanca. Planta Piloto de Ingeniería Química. Universidad Nacional del Sur. Planta Piloto de Ingeniería Química; Argentina. Universidad Nacional del Sur. Departamento de Ingeniería Química; Argentina
description BACKGROUND: The sunflower oil industry produces a large amount of waste that is not currently commercially exploited, as in the case of oil‐tank settlings. The recovery of a high value‐added by‐product, such as sunflower wax, would increase the commercial value of this waste. In this original research paper, a method that allows the recovery and purification of this by‐product was developed. The wax was characterized and its potential use as an organogelator agent was investigated. RESULTS: The waste sample was composed of 45.1% oily material, 16.9% of this being impure waxes. Purification was performed through two different methods, obtaining three waxes with different degrees of purity. All the waxes were composed of wax esters with a range of 40–60 carbon atoms, exhibiting traces of carotenes, free fatty acids, and free fatty alcohols. The presence of phospholipids was observed in two of them. The third wax presented a higher total wax ester content and physicochemical characteristics (color and thermal behavior) similar to those of commercial sunflower waxes, and was the most efficient organogelator agent, requiring only a small amount of wax (1.5%) to structure high oleic sunflower oil. CONCLUSION: It was verified that sunflower wax could be recovered from oil‐tank settlings. A purification method that allowed sunflower wax with similar physicochemical properties to those of commercial waxes to be obtained was also developed. The purified waxes were capable of structuring high oleic sunflower oil. © 2019 Society of Chemical Industry
publishDate 2019
dc.date.none.fl_str_mv 2019-11-27
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/113629
Redondas, Cintia Elizabeth; Baumler, Erica Raquel; Carelli Albarracin, Amalia Antonia; Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 100; 1; 27-11-2019; 201-211
0022-5142
CONICET Digital
CONICET
url http://hdl.handle.net/11336/113629
identifier_str_mv Redondas, Cintia Elizabeth; Baumler, Erica Raquel; Carelli Albarracin, Amalia Antonia; Sunflower wax recovered from oil tank settlings: Revaluation of a waste product from the oilseed industry; John Wiley & Sons Ltd; Journal of the Science of Food and Agriculture; 100; 1; 27-11-2019; 201-211
0022-5142
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/https://onlinelibrary.wiley.com/doi/abs/10.1002/jsfa.10017
info:eu-repo/semantics/altIdentifier/doi/10.1002/jsfa.10017
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-nd/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv John Wiley & Sons Ltd
publisher.none.fl_str_mv John Wiley & Sons Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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