Acrylic-Casein Latexes with Potential Application as Adhesives

Autores
Aguzin, Ana; Jerkovich, José Ignacio; Trucone, Julieta; Ronco, Ludmila Irene; Roque Javier Minari; Gugliotta, Luis Marcelino
Año de publicación
2020
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
The replacement of monomers derived from petrochemical sources by biopolymers like proteins, together with the development of new materials with improved properties, have an increasing importance in industrial applications. In this context, the synthesis of acrylic-casein hybrid latexes was investigated through a low environmental impact strategy, such as the surfactant-free emulsion polymerization, with the aim of producing new industrial adhesives. Different aspects of the synthesis of hybrid latexes were addressed, such us i) the use of variable content of protein; ii) the control of grafting degree between polymers, using native casein (without chemical modification) or functionalized casein, and iii) the employment of a chain transfer agent to reduce molecular weights of the acrylic polymer. The effect of the analyzed variables on the polymerization kinetics, the degree of compatibility between polymers, and the application properties of the produced latexes as adhesives were investigated.
Fil: Aguzin, Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Jerkovich, José Ignacio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Trucone, Julieta. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Roque Javier Minari. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
HYBRID LATEX
ACRYLIC-CASEIN
ADHESIVE
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/111224
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Acrylic-Casein Latexes with Potential Application as AdhesivesAguzin, AnaJerkovich, José IgnacioTrucone, JulietaRonco, Ludmila IreneRoque Javier MinariGugliotta, Luis MarcelinoHYBRID LATEXACRYLIC-CASEINADHESIVEhttps://purl.org/becyt/ford/2.5https://purl.org/becyt/ford/2The replacement of monomers derived from petrochemical sources by biopolymers like proteins, together with the development of new materials with improved properties, have an increasing importance in industrial applications. In this context, the synthesis of acrylic-casein hybrid latexes was investigated through a low environmental impact strategy, such as the surfactant-free emulsion polymerization, with the aim of producing new industrial adhesives. Different aspects of the synthesis of hybrid latexes were addressed, such us i) the use of variable content of protein; ii) the control of grafting degree between polymers, using native casein (without chemical modification) or functionalized casein, and iii) the employment of a chain transfer agent to reduce molecular weights of the acrylic polymer. The effect of the analyzed variables on the polymerization kinetics, the degree of compatibility between polymers, and the application properties of the produced latexes as adhesives were investigated.Fil: Aguzin, Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Jerkovich, José Ignacio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Trucone, Julieta. Universidad Nacional del Litoral. Facultad de Ingeniería Química; ArgentinaFil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Roque Javier Minari. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaPlanta Piloto de Ingeniería Química2020-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/111224Aguzin, Ana; Jerkovich, José Ignacio; Trucone, Julieta; Ronco, Ludmila Irene; Roque Javier Minari; et al.; Acrylic-Casein Latexes with Potential Application as Adhesives; Planta Piloto de Ingeniería Química; Latin American Applied Research; 50; 2; 1-2020; 115-1200327-07931851-8796CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/489info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T09:54:28Zoai:ri.conicet.gov.ar:11336/111224instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 09:54:28.669CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Acrylic-Casein Latexes with Potential Application as Adhesives
title Acrylic-Casein Latexes with Potential Application as Adhesives
spellingShingle Acrylic-Casein Latexes with Potential Application as Adhesives
Aguzin, Ana
HYBRID LATEX
ACRYLIC-CASEIN
ADHESIVE
title_short Acrylic-Casein Latexes with Potential Application as Adhesives
title_full Acrylic-Casein Latexes with Potential Application as Adhesives
title_fullStr Acrylic-Casein Latexes with Potential Application as Adhesives
title_full_unstemmed Acrylic-Casein Latexes with Potential Application as Adhesives
title_sort Acrylic-Casein Latexes with Potential Application as Adhesives
dc.creator.none.fl_str_mv Aguzin, Ana
Jerkovich, José Ignacio
Trucone, Julieta
Ronco, Ludmila Irene
Roque Javier Minari
Gugliotta, Luis Marcelino
author Aguzin, Ana
author_facet Aguzin, Ana
Jerkovich, José Ignacio
Trucone, Julieta
Ronco, Ludmila Irene
Roque Javier Minari
Gugliotta, Luis Marcelino
author_role author
author2 Jerkovich, José Ignacio
Trucone, Julieta
Ronco, Ludmila Irene
Roque Javier Minari
Gugliotta, Luis Marcelino
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv HYBRID LATEX
ACRYLIC-CASEIN
ADHESIVE
topic HYBRID LATEX
ACRYLIC-CASEIN
ADHESIVE
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.5
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv The replacement of monomers derived from petrochemical sources by biopolymers like proteins, together with the development of new materials with improved properties, have an increasing importance in industrial applications. In this context, the synthesis of acrylic-casein hybrid latexes was investigated through a low environmental impact strategy, such as the surfactant-free emulsion polymerization, with the aim of producing new industrial adhesives. Different aspects of the synthesis of hybrid latexes were addressed, such us i) the use of variable content of protein; ii) the control of grafting degree between polymers, using native casein (without chemical modification) or functionalized casein, and iii) the employment of a chain transfer agent to reduce molecular weights of the acrylic polymer. The effect of the analyzed variables on the polymerization kinetics, the degree of compatibility between polymers, and the application properties of the produced latexes as adhesives were investigated.
Fil: Aguzin, Ana. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Jerkovich, José Ignacio. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Trucone, Julieta. Universidad Nacional del Litoral. Facultad de Ingeniería Química; Argentina
Fil: Ronco, Ludmila Irene. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Roque Javier Minari. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description The replacement of monomers derived from petrochemical sources by biopolymers like proteins, together with the development of new materials with improved properties, have an increasing importance in industrial applications. In this context, the synthesis of acrylic-casein hybrid latexes was investigated through a low environmental impact strategy, such as the surfactant-free emulsion polymerization, with the aim of producing new industrial adhesives. Different aspects of the synthesis of hybrid latexes were addressed, such us i) the use of variable content of protein; ii) the control of grafting degree between polymers, using native casein (without chemical modification) or functionalized casein, and iii) the employment of a chain transfer agent to reduce molecular weights of the acrylic polymer. The effect of the analyzed variables on the polymerization kinetics, the degree of compatibility between polymers, and the application properties of the produced latexes as adhesives were investigated.
publishDate 2020
dc.date.none.fl_str_mv 2020-01
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/111224
Aguzin, Ana; Jerkovich, José Ignacio; Trucone, Julieta; Ronco, Ludmila Irene; Roque Javier Minari; et al.; Acrylic-Casein Latexes with Potential Application as Adhesives; Planta Piloto de Ingeniería Química; Latin American Applied Research; 50; 2; 1-2020; 115-120
0327-0793
1851-8796
CONICET Digital
CONICET
url http://hdl.handle.net/11336/111224
identifier_str_mv Aguzin, Ana; Jerkovich, José Ignacio; Trucone, Julieta; Ronco, Ludmila Irene; Roque Javier Minari; et al.; Acrylic-Casein Latexes with Potential Application as Adhesives; Planta Piloto de Ingeniería Química; Latin American Applied Research; 50; 2; 1-2020; 115-120
0327-0793
1851-8796
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/url/http://laar.plapiqui.edu.ar/OJS/index.php/laar/article/view/489
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
publisher.none.fl_str_mv Planta Piloto de Ingeniería Química
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844613654205431808
score 13.070432

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