Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization

Autores
Picchio, Matías Luis; Bohórquez, Silfredo; van den Berg, Peter G. C. A.; Barandiaran, María J.; Gugliotta, Luis Marcelino; Minari, Roque Javier
Año de publicación
2016
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Over the last few years casein-based latexes have attracted increasing interest because of their good film-forming properties. This paper investigates the use of acrylic/casein hybrid latexes with a solids content of 35% in a coating application, which involves the evaluation of non-formulated latexes as binders, the high-throughput formulation with different commercial agents (cosolvents, wetting agents and defoamers) and the formulation optimization using statistic multivariable analysis. Latexes were obtained by emulsifier-free emulsion polymerization of acrylic monomers in the presence of a chemically modified casein containing 10 vinyl bonds per molecule. The optimized clear coats formulated from the hybrid latexes showed a good performance requiring a reduced formulation-agents concentration, which could be an important benefit from environmental viewpoint. Together the above results demonstrate that the casein bio-based latexes represent a promising alternative for the development of a new generation of ecological binders.
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bohórquez, Silfredo. Allnex; Países Bajos
Fil: van den Berg, Peter G. C. A.. Allnex; Países Bajos
Fil: Barandiaran, María J.. Universidad del País Vasco; España
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Materia
Casein Derived Materials
High Solids Hybrid Latexes
Low Voc Formulations
Water-Based Coatings
Renewable Material
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/24183
Acceder
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oai_identifier_str oai:ri.conicet.gov.ar:11336/24183
network_acronym_str CONICETDig
repository_id_str 3498
network_name_str CONICET Digital (CONICET)
spelling Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating OptimizationPicchio, Matías LuisBohórquez, Silfredovan den Berg, Peter G. C. A.Barandiaran, María J.Gugliotta, Luis MarcelinoMinari, Roque JavierCasein Derived MaterialsHigh Solids Hybrid LatexesLow Voc FormulationsWater-Based CoatingsRenewable Materialhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2Over the last few years casein-based latexes have attracted increasing interest because of their good film-forming properties. This paper investigates the use of acrylic/casein hybrid latexes with a solids content of 35% in a coating application, which involves the evaluation of non-formulated latexes as binders, the high-throughput formulation with different commercial agents (cosolvents, wetting agents and defoamers) and the formulation optimization using statistic multivariable analysis. Latexes were obtained by emulsifier-free emulsion polymerization of acrylic monomers in the presence of a chemically modified casein containing 10 vinyl bonds per molecule. The optimized clear coats formulated from the hybrid latexes showed a good performance requiring a reduced formulation-agents concentration, which could be an important benefit from environmental viewpoint. Together the above results demonstrate that the casein bio-based latexes represent a promising alternative for the development of a new generation of ecological binders.Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Bohórquez, Silfredo. Allnex; Países BajosFil: van den Berg, Peter G. C. A.. Allnex; Países BajosFil: Barandiaran, María J.. Universidad del País Vasco; EspañaFil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaFil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; ArgentinaAmerican Chemical Society2016-09info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/24183Picchio, Matías Luis; Bohórquez, Silfredo; van den Berg, Peter G. C. A.; Barandiaran, María J.; Gugliotta, Luis Marcelino; et al.; Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization; American Chemical Society; Industrial & Engineering Chemical Research; 55; 39; 9-2016; 10271-102770888-5885CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.6b02105info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.iecr.6b02105info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:46:23Zoai:ri.conicet.gov.ar:11336/24183instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:46:23.862CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
title Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
spellingShingle Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
Picchio, Matías Luis
Casein Derived Materials
High Solids Hybrid Latexes
Low Voc Formulations
Water-Based Coatings
Renewable Material
title_short Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
title_full Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
title_fullStr Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
title_full_unstemmed Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
title_sort Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization
dc.creator.none.fl_str_mv Picchio, Matías Luis
Bohórquez, Silfredo
van den Berg, Peter G. C. A.
Barandiaran, María J.
Gugliotta, Luis Marcelino
Minari, Roque Javier
author Picchio, Matías Luis
author_facet Picchio, Matías Luis
Bohórquez, Silfredo
van den Berg, Peter G. C. A.
Barandiaran, María J.
Gugliotta, Luis Marcelino
Minari, Roque Javier
author_role author
author2 Bohórquez, Silfredo
van den Berg, Peter G. C. A.
Barandiaran, María J.
Gugliotta, Luis Marcelino
Minari, Roque Javier
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Casein Derived Materials
High Solids Hybrid Latexes
Low Voc Formulations
Water-Based Coatings
Renewable Material
topic Casein Derived Materials
High Solids Hybrid Latexes
Low Voc Formulations
Water-Based Coatings
Renewable Material
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv Over the last few years casein-based latexes have attracted increasing interest because of their good film-forming properties. This paper investigates the use of acrylic/casein hybrid latexes with a solids content of 35% in a coating application, which involves the evaluation of non-formulated latexes as binders, the high-throughput formulation with different commercial agents (cosolvents, wetting agents and defoamers) and the formulation optimization using statistic multivariable analysis. Latexes were obtained by emulsifier-free emulsion polymerization of acrylic monomers in the presence of a chemically modified casein containing 10 vinyl bonds per molecule. The optimized clear coats formulated from the hybrid latexes showed a good performance requiring a reduced formulation-agents concentration, which could be an important benefit from environmental viewpoint. Together the above results demonstrate that the casein bio-based latexes represent a promising alternative for the development of a new generation of ecological binders.
Fil: Picchio, Matías Luis. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Bohórquez, Silfredo. Allnex; Países Bajos
Fil: van den Berg, Peter G. C. A.. Allnex; Países Bajos
Fil: Barandiaran, María J.. Universidad del País Vasco; España
Fil: Gugliotta, Luis Marcelino. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
Fil: Minari, Roque Javier. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Desarrollo Tecnológico para la Industria Química. Universidad Nacional del Litoral. Instituto de Desarrollo Tecnológico para la Industria Química; Argentina
description Over the last few years casein-based latexes have attracted increasing interest because of their good film-forming properties. This paper investigates the use of acrylic/casein hybrid latexes with a solids content of 35% in a coating application, which involves the evaluation of non-formulated latexes as binders, the high-throughput formulation with different commercial agents (cosolvents, wetting agents and defoamers) and the formulation optimization using statistic multivariable analysis. Latexes were obtained by emulsifier-free emulsion polymerization of acrylic monomers in the presence of a chemically modified casein containing 10 vinyl bonds per molecule. The optimized clear coats formulated from the hybrid latexes showed a good performance requiring a reduced formulation-agents concentration, which could be an important benefit from environmental viewpoint. Together the above results demonstrate that the casein bio-based latexes represent a promising alternative for the development of a new generation of ecological binders.
publishDate 2016
dc.date.none.fl_str_mv 2016-09
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/24183
Picchio, Matías Luis; Bohórquez, Silfredo; van den Berg, Peter G. C. A.; Barandiaran, María J.; Gugliotta, Luis Marcelino; et al.; Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization; American Chemical Society; Industrial & Engineering Chemical Research; 55; 39; 9-2016; 10271-10277
0888-5885
CONICET Digital
CONICET
url http://hdl.handle.net/11336/24183
identifier_str_mv Picchio, Matías Luis; Bohórquez, Silfredo; van den Berg, Peter G. C. A.; Barandiaran, María J.; Gugliotta, Luis Marcelino; et al.; Waterborne Casein-Based Latexes with High Solids Content and its High-Throughput Coating Optimization; American Chemical Society; Industrial & Engineering Chemical Research; 55; 39; 9-2016; 10271-10277
0888-5885
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1021/acs.iecr.6b02105
info:eu-repo/semantics/altIdentifier/url/http://pubs.acs.org/doi/abs/10.1021/acs.iecr.6b02105
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614504997978112
score 13.070432

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