Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass
- Autores
- Pacheco, Pablo Hugo; Gil, Raul Andres; Smichowski, Patricia Nora; Polla, Griselda Ines; Martinez, Luis Dante
- Año de publicación
- 2008
- Idioma
- inglés
- Tipo de recurso
- artículo
- Estado
- versión publicada
- Descripción
- Aluminium is an element found in biological samples at low concentrations and aluminum-related neuropathological diseases in human beings have been reported. For this reason the determination of Al in this type of samples requires the development of enrichment methods capable of improving the instrumental detection for this analyte. l-methionine immobilized on controlled pore glass (CPG) was tested for the retention of aluminium. This adsorbent material was packed in a conical minicolumn and connected to an on-line flow injection system. An inductively coupled plasma optical emission spectrometer associated to an ultrasonic nebulization system (USN-ICP OES) was used for aluminium detection. Al(III) was retained at pH 12.5 and removed from the column with 20% (v/v) HNO3. The precision of the preconcentration method was evaluated by passing a measured volume of aluminium standard solution (1 μg L- 1) through the minicolumn and repeating this procedure five times. The relative standard deviation (RSD) was 2.5%, calculated with the peak heights obtained. A total enhancement factor of 1600 was attained for a sample volume of 10 mL (10-fold for the ultrasonic nebulization system and 160-fold for the preconcentration methodology). The detection limit (DL), calculated as the amount of Al required to yield a net peak equal to three times the standard deviation of the blank solution, was 25 ng L- 1. The proposed system was successfully applied to the determination of aluminium in urine, hair, and saliva samples, which were pretreated using a microwave digestion methodology with the introduction of a digestion program for saliva. The average aluminium levels found in urine, hair, and saliva samples were 5.5 μg L- 1, 19 μg g- 1 and 93 μg L- 1 respectively.
Fil: Pacheco, Pablo Hugo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Ministerio de Ciencia, Tecnología e Innovación Productiva. Agencia Nacional de Promoción Científica y Tecnológica. Fondo para la Investigación Científica y Tecnológica; Argentina
Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina
Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Comisión Nacional de Energía Atómica; Argentina
Fil: Polla, Griselda Ines. Comisión Nacional de Energía Atómica; Argentina
Fil: Martinez, Luis Dante. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina - Materia
-
ALUMINIUM
BIOLOGICAL SAMPLES
L-METHIONINE
SOLID PHASE EXTRACTION - Nivel de accesibilidad
- acceso abierto
- Condiciones de uso
- https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
- Repositorio
- Institución
- Consejo Nacional de Investigaciones Científicas y Técnicas
- OAI Identificador
- oai:ri.conicet.gov.ar:11336/93234
Ver los metadatos del registro completo
id |
CONICETDig_836c8a3b969bdb96e4cdd2a7056ab22a |
---|---|
oai_identifier_str |
oai:ri.conicet.gov.ar:11336/93234 |
network_acronym_str |
CONICETDig |
repository_id_str |
3498 |
network_name_str |
CONICET Digital (CONICET) |
spelling |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glassPacheco, Pablo HugoGil, Raul AndresSmichowski, Patricia NoraPolla, Griselda InesMartinez, Luis DanteALUMINIUMBIOLOGICAL SAMPLESL-METHIONINESOLID PHASE EXTRACTIONhttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Aluminium is an element found in biological samples at low concentrations and aluminum-related neuropathological diseases in human beings have been reported. For this reason the determination of Al in this type of samples requires the development of enrichment methods capable of improving the instrumental detection for this analyte. l-methionine immobilized on controlled pore glass (CPG) was tested for the retention of aluminium. This adsorbent material was packed in a conical minicolumn and connected to an on-line flow injection system. An inductively coupled plasma optical emission spectrometer associated to an ultrasonic nebulization system (USN-ICP OES) was used for aluminium detection. Al(III) was retained at pH 12.5 and removed from the column with 20% (v/v) HNO3. The precision of the preconcentration method was evaluated by passing a measured volume of aluminium standard solution (1 μg L- 1) through the minicolumn and repeating this procedure five times. The relative standard deviation (RSD) was 2.5%, calculated with the peak heights obtained. A total enhancement factor of 1600 was attained for a sample volume of 10 mL (10-fold for the ultrasonic nebulization system and 160-fold for the preconcentration methodology). The detection limit (DL), calculated as the amount of Al required to yield a net peak equal to three times the standard deviation of the blank solution, was 25 ng L- 1. The proposed system was successfully applied to the determination of aluminium in urine, hair, and saliva samples, which were pretreated using a microwave digestion methodology with the introduction of a digestion program for saliva. The average aluminium levels found in urine, hair, and saliva samples were 5.5 μg L- 1, 19 μg g- 1 and 93 μg L- 1 respectively.Fil: Pacheco, Pablo Hugo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Ministerio de Ciencia, Tecnología e Innovación Productiva. Agencia Nacional de Promoción Científica y Tecnológica. Fondo para la Investigación Científica y Tecnológica; ArgentinaFil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; ArgentinaFil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Polla, Griselda Ines. Comisión Nacional de Energía Atómica; ArgentinaFil: Martinez, Luis Dante. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; ArgentinaElsevier Science2008-06info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/93234Pacheco, Pablo Hugo; Gil, Raul Andres; Smichowski, Patricia Nora; Polla, Griselda Ines; Martinez, Luis Dante; Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass; Elsevier Science; Microchemical Journal; 89; 1; 6-2008; 1-60026-265XCONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0026265X07001178info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2007.10.004info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-03T10:07:25Zoai:ri.conicet.gov.ar:11336/93234instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-03 10:07:25.97CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse |
dc.title.none.fl_str_mv |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
title |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
spellingShingle |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass Pacheco, Pablo Hugo ALUMINIUM BIOLOGICAL SAMPLES L-METHIONINE SOLID PHASE EXTRACTION |
title_short |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
title_full |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
title_fullStr |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
title_full_unstemmed |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
title_sort |
Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass |
dc.creator.none.fl_str_mv |
Pacheco, Pablo Hugo Gil, Raul Andres Smichowski, Patricia Nora Polla, Griselda Ines Martinez, Luis Dante |
author |
Pacheco, Pablo Hugo |
author_facet |
Pacheco, Pablo Hugo Gil, Raul Andres Smichowski, Patricia Nora Polla, Griselda Ines Martinez, Luis Dante |
author_role |
author |
author2 |
Gil, Raul Andres Smichowski, Patricia Nora Polla, Griselda Ines Martinez, Luis Dante |
author2_role |
author author author author |
dc.subject.none.fl_str_mv |
ALUMINIUM BIOLOGICAL SAMPLES L-METHIONINE SOLID PHASE EXTRACTION |
topic |
ALUMINIUM BIOLOGICAL SAMPLES L-METHIONINE SOLID PHASE EXTRACTION |
purl_subject.fl_str_mv |
https://purl.org/becyt/ford/1.4 https://purl.org/becyt/ford/1 |
dc.description.none.fl_txt_mv |
Aluminium is an element found in biological samples at low concentrations and aluminum-related neuropathological diseases in human beings have been reported. For this reason the determination of Al in this type of samples requires the development of enrichment methods capable of improving the instrumental detection for this analyte. l-methionine immobilized on controlled pore glass (CPG) was tested for the retention of aluminium. This adsorbent material was packed in a conical minicolumn and connected to an on-line flow injection system. An inductively coupled plasma optical emission spectrometer associated to an ultrasonic nebulization system (USN-ICP OES) was used for aluminium detection. Al(III) was retained at pH 12.5 and removed from the column with 20% (v/v) HNO3. The precision of the preconcentration method was evaluated by passing a measured volume of aluminium standard solution (1 μg L- 1) through the minicolumn and repeating this procedure five times. The relative standard deviation (RSD) was 2.5%, calculated with the peak heights obtained. A total enhancement factor of 1600 was attained for a sample volume of 10 mL (10-fold for the ultrasonic nebulization system and 160-fold for the preconcentration methodology). The detection limit (DL), calculated as the amount of Al required to yield a net peak equal to three times the standard deviation of the blank solution, was 25 ng L- 1. The proposed system was successfully applied to the determination of aluminium in urine, hair, and saliva samples, which were pretreated using a microwave digestion methodology with the introduction of a digestion program for saliva. The average aluminium levels found in urine, hair, and saliva samples were 5.5 μg L- 1, 19 μg g- 1 and 93 μg L- 1 respectively. Fil: Pacheco, Pablo Hugo. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Ministerio de Ciencia, Tecnología e Innovación Productiva. Agencia Nacional de Promoción Científica y Tecnológica. Fondo para la Investigación Científica y Tecnológica; Argentina Fil: Gil, Raul Andres. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina Fil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina. Comisión Nacional de Energía Atómica; Argentina Fil: Polla, Griselda Ines. Comisión Nacional de Energía Atómica; Argentina Fil: Martinez, Luis Dante. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Departamento de Química. Área de Química Analítica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - San Luis. Instituto de Química de San Luis. Universidad Nacional de San Luis. Facultad de Química, Bioquímica y Farmacia. Instituto de Química de San Luis; Argentina |
description |
Aluminium is an element found in biological samples at low concentrations and aluminum-related neuropathological diseases in human beings have been reported. For this reason the determination of Al in this type of samples requires the development of enrichment methods capable of improving the instrumental detection for this analyte. l-methionine immobilized on controlled pore glass (CPG) was tested for the retention of aluminium. This adsorbent material was packed in a conical minicolumn and connected to an on-line flow injection system. An inductively coupled plasma optical emission spectrometer associated to an ultrasonic nebulization system (USN-ICP OES) was used for aluminium detection. Al(III) was retained at pH 12.5 and removed from the column with 20% (v/v) HNO3. The precision of the preconcentration method was evaluated by passing a measured volume of aluminium standard solution (1 μg L- 1) through the minicolumn and repeating this procedure five times. The relative standard deviation (RSD) was 2.5%, calculated with the peak heights obtained. A total enhancement factor of 1600 was attained for a sample volume of 10 mL (10-fold for the ultrasonic nebulization system and 160-fold for the preconcentration methodology). The detection limit (DL), calculated as the amount of Al required to yield a net peak equal to three times the standard deviation of the blank solution, was 25 ng L- 1. The proposed system was successfully applied to the determination of aluminium in urine, hair, and saliva samples, which were pretreated using a microwave digestion methodology with the introduction of a digestion program for saliva. The average aluminium levels found in urine, hair, and saliva samples were 5.5 μg L- 1, 19 μg g- 1 and 93 μg L- 1 respectively. |
publishDate |
2008 |
dc.date.none.fl_str_mv |
2008-06 |
dc.type.none.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion http://purl.org/coar/resource_type/c_6501 info:ar-repo/semantics/articulo |
format |
article |
status_str |
publishedVersion |
dc.identifier.none.fl_str_mv |
http://hdl.handle.net/11336/93234 Pacheco, Pablo Hugo; Gil, Raul Andres; Smichowski, Patricia Nora; Polla, Griselda Ines; Martinez, Luis Dante; Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass; Elsevier Science; Microchemical Journal; 89; 1; 6-2008; 1-6 0026-265X CONICET Digital CONICET |
url |
http://hdl.handle.net/11336/93234 |
identifier_str_mv |
Pacheco, Pablo Hugo; Gil, Raul Andres; Smichowski, Patricia Nora; Polla, Griselda Ines; Martinez, Luis Dante; Trace aluminium determination in biological samples after microwave digestion followed by solid phase extraction with l-methionine on controlled pore glass; Elsevier Science; Microchemical Journal; 89; 1; 6-2008; 1-6 0026-265X CONICET Digital CONICET |
dc.language.none.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
info:eu-repo/semantics/altIdentifier/url/https://www.sciencedirect.com/science/article/abs/pii/S0026265X07001178 info:eu-repo/semantics/altIdentifier/doi/10.1016/j.microc.2007.10.004 |
dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
eu_rights_str_mv |
openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/ |
dc.format.none.fl_str_mv |
application/pdf application/pdf |
dc.publisher.none.fl_str_mv |
Elsevier Science |
publisher.none.fl_str_mv |
Elsevier Science |
dc.source.none.fl_str_mv |
reponame:CONICET Digital (CONICET) instname:Consejo Nacional de Investigaciones Científicas y Técnicas |
reponame_str |
CONICET Digital (CONICET) |
collection |
CONICET Digital (CONICET) |
instname_str |
Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.name.fl_str_mv |
CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas |
repository.mail.fl_str_mv |
dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar |
_version_ |
1842270003539214336 |
score |
13.13397 |