Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues

Autores
Albis Arrieta, Alberto Ricardo; Ortiz Muñoz, Ever; Piñeres Ariza, Ismael; Suarez Escobar, Andres Felipe; Ariza Barraza, Cindy Skarlett
Año de publicación
2018
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
By using the mass spectrometry technique, the catalytic effect of ferric sulfate onthe evolved gases of the pyrolysis of residues from the cassava starch industrywas studied. There were identified 31 m/e ratios in the evolved gases with enoughsignal to noise ratio. The presence (or absence) of m/e signals in the pyrolysisevolved gases with (or without) catalyst suggest a change in the product distribution caused by the catalytic activity of the ferric sulfate. These signals were fitted withthe DAEM using the kinetic parameters calculated from previousthermogravimetry data. As result, 90% of the m/e ratios presented a good fit. Thepoor description of the model for the rest of the signals could be attributed tosecondary reactions in the gas phase.
Fil: Albis Arrieta, Alberto Ricardo. Universidad del Atlantico; Colombia
Fil: Ortiz Muñoz, Ever. Universidad del Atlantico; Colombia
Fil: Piñeres Ariza, Ismael. Universidad del Atlantico; Colombia
Fil: Suarez Escobar, Andres Felipe. Universitario;
Fil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
Materia
BIOMASS PYROLYSIS
CASSAVA INDUSTRIAL WASTE
FERRIC SULFATE
MASS SPECTROMETRY
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/88464
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch ResiduesAlbis Arrieta, Alberto RicardoOrtiz Muñoz, EverPiñeres Ariza, IsmaelSuarez Escobar, Andres FelipeAriza Barraza, Cindy SkarlettBIOMASS PYROLYSISCASSAVA INDUSTRIAL WASTEFERRIC SULFATEMASS SPECTROMETRYhttps://purl.org/becyt/ford/2.4https://purl.org/becyt/ford/2By using the mass spectrometry technique, the catalytic effect of ferric sulfate onthe evolved gases of the pyrolysis of residues from the cassava starch industrywas studied. There were identified 31 m/e ratios in the evolved gases with enoughsignal to noise ratio. The presence (or absence) of m/e signals in the pyrolysisevolved gases with (or without) catalyst suggest a change in the product distribution caused by the catalytic activity of the ferric sulfate. These signals were fitted withthe DAEM using the kinetic parameters calculated from previousthermogravimetry data. As result, 90% of the m/e ratios presented a good fit. Thepoor description of the model for the rest of the signals could be attributed tosecondary reactions in the gas phase.Fil: Albis Arrieta, Alberto Ricardo. Universidad del Atlantico; ColombiaFil: Ortiz Muñoz, Ever. Universidad del Atlantico; ColombiaFil: Piñeres Ariza, Ismael. Universidad del Atlantico; ColombiaFil: Suarez Escobar, Andres Felipe. Universitario;Fil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; ArgentinaHikari Ltd2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/88464Albis Arrieta, Alberto Ricardo; Ortiz Muñoz, Ever; Piñeres Ariza, Ismael; Suarez Escobar, Andres Felipe; Ariza Barraza, Cindy Skarlett; Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues; Hikari Ltd; Contemporary Engineering Sciences; 11; 72; 2018; 3599-36081313-6569CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.12988/ces.2018.88371info:eu-repo/semantics/altIdentifier/url/http://www.m-hikari.com/ces/ces2018/ces69-72-2018/p/albisCES69-72-2018-3.pdfinfo:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-09-29T10:47:19Zoai:ri.conicet.gov.ar:11336/88464instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-09-29 10:47:19.991CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
title Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
spellingShingle Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
Albis Arrieta, Alberto Ricardo
BIOMASS PYROLYSIS
CASSAVA INDUSTRIAL WASTE
FERRIC SULFATE
MASS SPECTROMETRY
title_short Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
title_full Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
title_fullStr Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
title_full_unstemmed Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
title_sort Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues
dc.creator.none.fl_str_mv Albis Arrieta, Alberto Ricardo
Ortiz Muñoz, Ever
Piñeres Ariza, Ismael
Suarez Escobar, Andres Felipe
Ariza Barraza, Cindy Skarlett
author Albis Arrieta, Alberto Ricardo
author_facet Albis Arrieta, Alberto Ricardo
Ortiz Muñoz, Ever
Piñeres Ariza, Ismael
Suarez Escobar, Andres Felipe
Ariza Barraza, Cindy Skarlett
author_role author
author2 Ortiz Muñoz, Ever
Piñeres Ariza, Ismael
Suarez Escobar, Andres Felipe
Ariza Barraza, Cindy Skarlett
author2_role author
author
author
author
dc.subject.none.fl_str_mv BIOMASS PYROLYSIS
CASSAVA INDUSTRIAL WASTE
FERRIC SULFATE
MASS SPECTROMETRY
topic BIOMASS PYROLYSIS
CASSAVA INDUSTRIAL WASTE
FERRIC SULFATE
MASS SPECTROMETRY
purl_subject.fl_str_mv https://purl.org/becyt/ford/2.4
https://purl.org/becyt/ford/2
dc.description.none.fl_txt_mv By using the mass spectrometry technique, the catalytic effect of ferric sulfate onthe evolved gases of the pyrolysis of residues from the cassava starch industrywas studied. There were identified 31 m/e ratios in the evolved gases with enoughsignal to noise ratio. The presence (or absence) of m/e signals in the pyrolysisevolved gases with (or without) catalyst suggest a change in the product distribution caused by the catalytic activity of the ferric sulfate. These signals were fitted withthe DAEM using the kinetic parameters calculated from previousthermogravimetry data. As result, 90% of the m/e ratios presented a good fit. Thepoor description of the model for the rest of the signals could be attributed tosecondary reactions in the gas phase.
Fil: Albis Arrieta, Alberto Ricardo. Universidad del Atlantico; Colombia
Fil: Ortiz Muñoz, Ever. Universidad del Atlantico; Colombia
Fil: Piñeres Ariza, Ismael. Universidad del Atlantico; Colombia
Fil: Suarez Escobar, Andres Felipe. Universitario;
Fil: Ariza Barraza, Cindy Skarlett. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Santa Fe. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera". Universidad Nacional del Litoral. Instituto de Investigaciones en Catálisis y Petroquímica "Ing. José Miguel Parera"; Argentina
description By using the mass spectrometry technique, the catalytic effect of ferric sulfate onthe evolved gases of the pyrolysis of residues from the cassava starch industrywas studied. There were identified 31 m/e ratios in the evolved gases with enoughsignal to noise ratio. The presence (or absence) of m/e signals in the pyrolysisevolved gases with (or without) catalyst suggest a change in the product distribution caused by the catalytic activity of the ferric sulfate. These signals were fitted withthe DAEM using the kinetic parameters calculated from previousthermogravimetry data. As result, 90% of the m/e ratios presented a good fit. Thepoor description of the model for the rest of the signals could be attributed tosecondary reactions in the gas phase.
publishDate 2018
dc.date.none.fl_str_mv 2018
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/88464
Albis Arrieta, Alberto Ricardo; Ortiz Muñoz, Ever; Piñeres Ariza, Ismael; Suarez Escobar, Andres Felipe; Ariza Barraza, Cindy Skarlett; Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues; Hikari Ltd; Contemporary Engineering Sciences; 11; 72; 2018; 3599-3608
1313-6569
CONICET Digital
CONICET
url http://hdl.handle.net/11336/88464
identifier_str_mv Albis Arrieta, Alberto Ricardo; Ortiz Muñoz, Ever; Piñeres Ariza, Ismael; Suarez Escobar, Andres Felipe; Ariza Barraza, Cindy Skarlett; Mass Spectrometry Characterization of Evolved Gases from Catalytic Pyrolysis of Cassava Starch Residues; Hikari Ltd; Contemporary Engineering Sciences; 11; 72; 2018; 3599-3608
1313-6569
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.12988/ces.2018.88371
info:eu-repo/semantics/altIdentifier/url/http://www.m-hikari.com/ces/ces2018/ces69-72-2018/p/albisCES69-72-2018-3.pdf
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Hikari Ltd
publisher.none.fl_str_mv Hikari Ltd
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
_version_ 1844614517150973952
score 13.070432

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