Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds

Autores
Barata Vallejo, Sebastian; Postigo, Jose Alberto
Año de publicación
2019
Idioma
inglés
Tipo de recurso
artículo
Estado
versión publicada
Descripción
Among the realm of visible light photocatalytic transformations, late-stagedifluoromethylation reactions (introduction of difluoromethyl groups in the last stages of syntheticprotocols) have played relevant roles as the CF2X group substitutions exert positive impacts on thephysical properties of organic compounds including solubility, metabolic stability, andlipophilicity, which are tenets of considerable importance in pharmaceutical, agrochemical, andmaterials science. Visible-light-photocatalyzed difluoromethylation reactions are shown to beaccomplished on (hetero)aromatic and carbon?carbon unsaturated aliphatic substrates under mildand environmentally benign conditions.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Materia
DIFLUOROMETHYLATION
CF2-AROMATICS
DIFLUOROMETHYLATION OF MULTIPLE BONDS
PHOTOCATALYTIC
Nivel de accesibilidad
acceso abierto
Condiciones de uso
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
Repositorio
CONICET Digital (CONICET)
Institución
Consejo Nacional de Investigaciones Científicas y Técnicas
OAI Identificador
oai:ri.conicet.gov.ar:11336/109117
Acceder
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network_name_str CONICET Digital (CONICET)
spelling Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C BondsBarata Vallejo, SebastianPostigo, Jose AlbertoDIFLUOROMETHYLATIONCF2-AROMATICSDIFLUOROMETHYLATION OF MULTIPLE BONDSPHOTOCATALYTIChttps://purl.org/becyt/ford/1.4https://purl.org/becyt/ford/1Among the realm of visible light photocatalytic transformations, late-stagedifluoromethylation reactions (introduction of difluoromethyl groups in the last stages of syntheticprotocols) have played relevant roles as the CF2X group substitutions exert positive impacts on thephysical properties of organic compounds including solubility, metabolic stability, andlipophilicity, which are tenets of considerable importance in pharmaceutical, agrochemical, andmaterials science. Visible-light-photocatalyzed difluoromethylation reactions are shown to beaccomplished on (hetero)aromatic and carbon?carbon unsaturated aliphatic substrates under mildand environmentally benign conditions.Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaFil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; ArgentinaMolecular Diversity Preservation International2019-12info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionhttp://purl.org/coar/resource_type/c_6501info:ar-repo/semantics/articuloapplication/pdfapplication/pdfhttp://hdl.handle.net/11336/109117Barata Vallejo, Sebastian; Postigo, Jose Alberto; Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds; Molecular Diversity Preservation International; Molecules; 24; 12-2019; 4483-45201420-3049CONICET DigitalCONICETenginfo:eu-repo/semantics/altIdentifier/doi/10.3390/molecules24244483info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/24/24/4483info:eu-repo/semantics/openAccesshttps://creativecommons.org/licenses/by-nc-sa/2.5/ar/reponame:CONICET Digital (CONICET)instname:Consejo Nacional de Investigaciones Científicas y Técnicas2025-10-15T15:44:44Zoai:ri.conicet.gov.ar:11336/109117instacron:CONICETInstitucionalhttp://ri.conicet.gov.ar/Organismo científico-tecnológicoNo correspondehttp://ri.conicet.gov.ar/oai/requestdasensio@conicet.gov.ar; lcarlino@conicet.gov.arArgentinaNo correspondeNo correspondeNo correspondeopendoar:34982025-10-15 15:44:45.152CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicasfalse
dc.title.none.fl_str_mv Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
title Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
spellingShingle Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
Barata Vallejo, Sebastian
DIFLUOROMETHYLATION
CF2-AROMATICS
DIFLUOROMETHYLATION OF MULTIPLE BONDS
PHOTOCATALYTIC
title_short Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
title_full Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
title_fullStr Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
title_full_unstemmed Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
title_sort Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds
dc.creator.none.fl_str_mv Barata Vallejo, Sebastian
Postigo, Jose Alberto
author Barata Vallejo, Sebastian
author_facet Barata Vallejo, Sebastian
Postigo, Jose Alberto
author_role author
author2 Postigo, Jose Alberto
author2_role author
dc.subject.none.fl_str_mv DIFLUOROMETHYLATION
CF2-AROMATICS
DIFLUOROMETHYLATION OF MULTIPLE BONDS
PHOTOCATALYTIC
topic DIFLUOROMETHYLATION
CF2-AROMATICS
DIFLUOROMETHYLATION OF MULTIPLE BONDS
PHOTOCATALYTIC
purl_subject.fl_str_mv https://purl.org/becyt/ford/1.4
https://purl.org/becyt/ford/1
dc.description.none.fl_txt_mv Among the realm of visible light photocatalytic transformations, late-stagedifluoromethylation reactions (introduction of difluoromethyl groups in the last stages of syntheticprotocols) have played relevant roles as the CF2X group substitutions exert positive impacts on thephysical properties of organic compounds including solubility, metabolic stability, andlipophilicity, which are tenets of considerable importance in pharmaceutical, agrochemical, andmaterials science. Visible-light-photocatalyzed difluoromethylation reactions are shown to beaccomplished on (hetero)aromatic and carbon?carbon unsaturated aliphatic substrates under mildand environmentally benign conditions.
Fil: Barata Vallejo, Sebastian. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
Fil: Postigo, Jose Alberto. Universidad de Buenos Aires. Facultad de Farmacia y Bioquímica. Departamento de Química Orgánica; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas. Oficina de Coordinación Administrativa Houssay; Argentina
description Among the realm of visible light photocatalytic transformations, late-stagedifluoromethylation reactions (introduction of difluoromethyl groups in the last stages of syntheticprotocols) have played relevant roles as the CF2X group substitutions exert positive impacts on thephysical properties of organic compounds including solubility, metabolic stability, andlipophilicity, which are tenets of considerable importance in pharmaceutical, agrochemical, andmaterials science. Visible-light-photocatalyzed difluoromethylation reactions are shown to beaccomplished on (hetero)aromatic and carbon?carbon unsaturated aliphatic substrates under mildand environmentally benign conditions.
publishDate 2019
dc.date.none.fl_str_mv 2019-12
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
http://purl.org/coar/resource_type/c_6501
info:ar-repo/semantics/articulo
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/11336/109117
Barata Vallejo, Sebastian; Postigo, Jose Alberto; Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds; Molecular Diversity Preservation International; Molecules; 24; 12-2019; 4483-4520
1420-3049
CONICET Digital
CONICET
url http://hdl.handle.net/11336/109117
identifier_str_mv Barata Vallejo, Sebastian; Postigo, Jose Alberto; Photocatalytic Difluoromethylation Reactions of Aromatic Compounds and Aliphatic Multiple C-C Bonds; Molecular Diversity Preservation International; Molecules; 24; 12-2019; 4483-4520
1420-3049
CONICET Digital
CONICET
dc.language.none.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.3390/molecules24244483
info:eu-repo/semantics/altIdentifier/url/https://www.mdpi.com/1420-3049/24/24/4483
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
eu_rights_str_mv openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by-nc-sa/2.5/ar/
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Molecular Diversity Preservation International
publisher.none.fl_str_mv Molecular Diversity Preservation International
dc.source.none.fl_str_mv reponame:CONICET Digital (CONICET)
instname:Consejo Nacional de Investigaciones Científicas y Técnicas
reponame_str CONICET Digital (CONICET)
collection CONICET Digital (CONICET)
instname_str Consejo Nacional de Investigaciones Científicas y Técnicas
repository.name.fl_str_mv CONICET Digital (CONICET) - Consejo Nacional de Investigaciones Científicas y Técnicas
repository.mail.fl_str_mv dasensio@conicet.gov.ar; lcarlino@conicet.gov.ar
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score 13.22299

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